SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 47 ›› Issue (7): 193-205.DOI: 10.1016/j.cjche.2021.05.043

• Full Length Article • 上一篇    下一篇

Hydrothermal synthesis of zeolitic material from circulating fluidized bed combustion fly ash for the highly efficient removal of lead from aqueous solution

Zhibin Ma, Xueli Zhang, Guangjun Lu, Yanxia Guo, Huiping Song, Fangqin Cheng   

  1. State Environmental Protection Key Laboratory of Efficient Utilization Technology of Coal Waste Resources, Collaborative Innovation Center of High Value-added Utilization of Coal-related Wastes, Institute of Resources and Environmental Engineering, Shanxi University, Taiyuan 030006, China
  • 收稿日期:2021-01-18 修回日期:2021-04-11 出版日期:2022-07-28 发布日期:2022-08-19
  • 通讯作者: Fangqin Cheng,E-mail:cfangqin@sxu.edu.cn
  • 基金资助:
    This work was supported by National Natural Science Foundation of China (22078181, U1810205) and the Bidding Project of Shanxi Province (20191101007).

Hydrothermal synthesis of zeolitic material from circulating fluidized bed combustion fly ash for the highly efficient removal of lead from aqueous solution

Zhibin Ma, Xueli Zhang, Guangjun Lu, Yanxia Guo, Huiping Song, Fangqin Cheng   

  1. State Environmental Protection Key Laboratory of Efficient Utilization Technology of Coal Waste Resources, Collaborative Innovation Center of High Value-added Utilization of Coal-related Wastes, Institute of Resources and Environmental Engineering, Shanxi University, Taiyuan 030006, China
  • Received:2021-01-18 Revised:2021-04-11 Online:2022-07-28 Published:2022-08-19
  • Contact: Fangqin Cheng,E-mail:cfangqin@sxu.edu.cn
  • Supported by:
    This work was supported by National Natural Science Foundation of China (22078181, U1810205) and the Bidding Project of Shanxi Province (20191101007).

摘要: The utilization of coal fly ash derived from circulating fluidized bed combustion (CFBFA) still faces great challenges because of its unique characteristics. In this study, a zeolitic material with Na-P1 zeolite as the main phase was successfully synthesized via a hydrothermal method by using CFBFA as the raw material. The effects of hydrothermal temperature, time, and added CTAB amount on the characterizations of synthesized materials were investigated by XRD, SEM, and XPS. The properties of the optimal zeolitic material and its adsorption performance for Pb2+ in aqueous solution were evaluated. The influences of pH, initial concentration, dosage, and temperature on Pb2+ adsorption were also examined. Results revealed the following optimal parameters for the synthesis of zeolitic material:NaOH concentration of 2 mol·L-1, solid-to-liquid ratio of 1:10 g·ml-1, hydrothermal temperature of 110℃, hydrothermal time of 9 h, and CTAB amount of 1 g (per 100 ml solution). The adsorption capacities of the zeolitic material reached 329.67, 424.69, and 542.22 mg·g-1 when the pH values of aqueous solution were 5, 6, and 7, respectively. The Pb2+removal efficiency can reach more than 99% in aqueous solution with the initial concentrations of 100-300 mg·L-1 under pH 6 and suitable adsorbent dosage. The adsorption and kinetics of Pb2+ on the zeolitic material can be described by Langmuir isotherm and pseudo-second-order kinetic models, respectively. The ion exchange between Pb2+ and Na+ and chemisorption are the main adsorption mechanism. All these findings imply that the synthesis of low-cost adsorbent for Pb2+ removal from weak acid and neutral aqueous solution provides a highly effective method to utilize CFBFA.

关键词: Circulating fluidized bed (CFB) coal fly ash, Hydrothermal treatment, Zeolite, Pb2+, Adsorption, Waste treatment

Abstract: The utilization of coal fly ash derived from circulating fluidized bed combustion (CFBFA) still faces great challenges because of its unique characteristics. In this study, a zeolitic material with Na-P1 zeolite as the main phase was successfully synthesized via a hydrothermal method by using CFBFA as the raw material. The effects of hydrothermal temperature, time, and added CTAB amount on the characterizations of synthesized materials were investigated by XRD, SEM, and XPS. The properties of the optimal zeolitic material and its adsorption performance for Pb2+ in aqueous solution were evaluated. The influences of pH, initial concentration, dosage, and temperature on Pb2+ adsorption were also examined. Results revealed the following optimal parameters for the synthesis of zeolitic material:NaOH concentration of 2 mol·L-1, solid-to-liquid ratio of 1:10 g·ml-1, hydrothermal temperature of 110℃, hydrothermal time of 9 h, and CTAB amount of 1 g (per 100 ml solution). The adsorption capacities of the zeolitic material reached 329.67, 424.69, and 542.22 mg·g-1 when the pH values of aqueous solution were 5, 6, and 7, respectively. The Pb2+removal efficiency can reach more than 99% in aqueous solution with the initial concentrations of 100-300 mg·L-1 under pH 6 and suitable adsorbent dosage. The adsorption and kinetics of Pb2+ on the zeolitic material can be described by Langmuir isotherm and pseudo-second-order kinetic models, respectively. The ion exchange between Pb2+ and Na+ and chemisorption are the main adsorption mechanism. All these findings imply that the synthesis of low-cost adsorbent for Pb2+ removal from weak acid and neutral aqueous solution provides a highly effective method to utilize CFBFA.

Key words: Circulating fluidized bed (CFB) coal fly ash, Hydrothermal treatment, Zeolite, Pb2+, Adsorption, Waste treatment