SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (5): 665-670.DOI: 10.1016/j.cjche.2016.10.017

• Energy, Resources and Environmental Technology • Previous Articles     Next Articles

Catalytic ozonation of thymol in reverse osmosis concentrate with core/shell Fe3O4@SiO2@Yb2O3 catalyst: Parameter optimization and degradation pathway

Liang Wang1, Anqi Liu2, Zhaohui Zhang1,2, Bin Zhao1,2, Yingming Xia2, Yun Tan2   

  1. 1 State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China;
    2 Department of Environmental Engineering, Tianjin Polytechnic University, Tianjin 300387, China
  • Received:2016-06-01 Revised:2016-10-30 Online:2017-07-06 Published:2017-05-28
  • Supported by:
    Supported by the National Natural Science Foundation of China (51138008,51478314,51308391),the Key Project for Research and Development (2016YFC0400503),the Tianjin Science and Technology Program (14ZCDGSF00128),and the Natural Science Foundation of Tianjin (14JCQNJC09000).

Catalytic ozonation of thymol in reverse osmosis concentrate with core/shell Fe3O4@SiO2@Yb2O3 catalyst: Parameter optimization and degradation pathway

Liang Wang1, Anqi Liu2, Zhaohui Zhang1,2, Bin Zhao1,2, Yingming Xia2, Yun Tan2   

  1. 1 State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China;
    2 Department of Environmental Engineering, Tianjin Polytechnic University, Tianjin 300387, China
  • 通讯作者: Zhaohui Zhang,E-mail address:zzh7448@126.com
  • 基金资助:
    Supported by the National Natural Science Foundation of China (51138008,51478314,51308391),the Key Project for Research and Development (2016YFC0400503),the Tianjin Science and Technology Program (14ZCDGSF00128),and the Natural Science Foundation of Tianjin (14JCQNJC09000).

Abstract: In this work, a novel catalyst of Fe3O4@SiO2@Yb2O3 was prepared and the degradation of thymol in reverse osmosis concentrate using ozonation was explored. The operational parameters, such as ozone dosage (8-48 mg·min-1), initial thymol concentration (20-100 mg·L-1), initial pH value (3-11), and catalyst Fe3O4@SiO2@Yb2O3 dosage (0.2-1.0 g), were studied focusing on the thymol degradation and COD removal. The results indicated that the increase in ozone dosage, initial pH value, and Fe3O4@SiO2@Yb2O3 dosage accelerated the thymol degradation and COD removal, while the increase in initial thymol concentration hampered the effect of ozonation. A pathway of thymol degradation by catalytic ozonation was proposed based on the intermediates detected by gas chromatography-mass spectrometer and ion chromatography. This paper can provide basic data and technical alternative for pollutant removal from reverse osmosis concentrate by ozonation.

Key words: Catalysis, Ozonation, Wastewater, Thymol, Degradation pathway

摘要: In this work, a novel catalyst of Fe3O4@SiO2@Yb2O3 was prepared and the degradation of thymol in reverse osmosis concentrate using ozonation was explored. The operational parameters, such as ozone dosage (8-48 mg·min-1), initial thymol concentration (20-100 mg·L-1), initial pH value (3-11), and catalyst Fe3O4@SiO2@Yb2O3 dosage (0.2-1.0 g), were studied focusing on the thymol degradation and COD removal. The results indicated that the increase in ozone dosage, initial pH value, and Fe3O4@SiO2@Yb2O3 dosage accelerated the thymol degradation and COD removal, while the increase in initial thymol concentration hampered the effect of ozonation. A pathway of thymol degradation by catalytic ozonation was proposed based on the intermediates detected by gas chromatography-mass spectrometer and ion chromatography. This paper can provide basic data and technical alternative for pollutant removal from reverse osmosis concentrate by ozonation.

关键词: Catalysis, Ozonation, Wastewater, Thymol, Degradation pathway