SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2021, Vol. 29 ›› Issue (1): 354-364.DOI: 10.1016/j.cjche.2020.09.019

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Design and analysis of dual mixed refrigerant processes for high-ethane content natural gas liquefaction

Ting He, Wensheng Lin   

  1. Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2020-06-09 Revised:2020-07-19 Online:2021-04-02 Published:2021-01-28
  • Contact: Wensheng Lin

Design and analysis of dual mixed refrigerant processes for high-ethane content natural gas liquefaction

Ting He, Wensheng Lin   

  1. Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai 200240, China
  • 通讯作者: Wensheng Lin

Abstract: Recovery and purification of ethane has a significant impact on economic benefit improvement of the high-ethane content natural gas. However, current LNG-NGL integrated processes mainly focus on conventional natural gas, which are not applicable to natural gas with high ethane content. To fill this gap, three dual mixed refrigerant processes are proposed for simulation study of high-ethane content natural gas liquefaction. The proposed processes are optimized by a combination method of sequence optimization and genetic algorithm. Comparatively analysis is conducted to evaluate the three processes from the energetic and exergetic points of view. The results show that the power consumption of Process 3 which compressing natural gas after distillation is the lowest. For safety or other considerations, some common compositions of the mixed refrigerant may need to be removed under certain circumstances. Considering this, case studies of mixed refrigerant involving six composition combinations are carried out to investigate the effects of refrigerant selection on the process performance.

Key words: Natural gas liquefaction, Ethane, Dual mixed refrigerant cycle, Cryogenic distillation, Refrigerant selection

摘要: Recovery and purification of ethane has a significant impact on economic benefit improvement of the high-ethane content natural gas. However, current LNG-NGL integrated processes mainly focus on conventional natural gas, which are not applicable to natural gas with high ethane content. To fill this gap, three dual mixed refrigerant processes are proposed for simulation study of high-ethane content natural gas liquefaction. The proposed processes are optimized by a combination method of sequence optimization and genetic algorithm. Comparatively analysis is conducted to evaluate the three processes from the energetic and exergetic points of view. The results show that the power consumption of Process 3 which compressing natural gas after distillation is the lowest. For safety or other considerations, some common compositions of the mixed refrigerant may need to be removed under certain circumstances. Considering this, case studies of mixed refrigerant involving six composition combinations are carried out to investigate the effects of refrigerant selection on the process performance.

关键词: Natural gas liquefaction, Ethane, Dual mixed refrigerant cycle, Cryogenic distillation, Refrigerant selection