Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

doi:10.1016/j.cjche.2020.09.052

Chinese Journal of Chemical Engineering ›› 2021, Vol. 32 ›› Issue (4): 341-352.DOI: 10.1016/j.cjche.2020.09.052

• Energy, Resources and Environmental Technology • Previous Articles Next Articles

Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

Mohammad Saood Manzar¹, Shamsuddeen A. Haladu², Mukarram Zubair¹, Nuhu Dalhat Mu'azu¹, Aleem Qureshi¹, Nawaf I. Blaisi¹, Thomas F. Garrison³, Othman Charles S. Al Hamouz³

1 Department of Environmental Engineering, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia;
2 Department of Basic Engineering Sciences, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia;
3 Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Received:2019-12-22 Revised:2020-09-12 Online:2021-06-19 Published:2021-04-28
Contact: Shamsuddeen A. Haladu, Othman Charles S. Al Hamouz
Supported by:
The authors thank Imam Abdulrahman Bin Faisal University (IAU), Dammam for providing research facilities.

Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

Mohammad Saood Manzar¹, Shamsuddeen A. Haladu², Mukarram Zubair¹, Nuhu Dalhat Mu'azu¹, Aleem Qureshi¹, Nawaf I. Blaisi¹, Thomas F. Garrison³, Othman Charles S. Al Hamouz³

1 Department of Environmental Engineering, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia;
2 Department of Basic Engineering Sciences, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia;
3 Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

通讯作者: Shamsuddeen A. Haladu, Othman Charles S. Al Hamouz
基金资助:
The authors thank Imam Abdulrahman Bin Faisal University (IAU), Dammam for providing research facilities.

Abstract

Abstract: A new series of polymers comprising four terpolymers was synthesized via Mannich polycondensation of benzene-1,4-diamine, formaldehyde and piperazine by varying the benzene-1,4-diamine and piperazine ratio. The new polyamines (labeled Dipip) were characterized using ¹³C solid-state NMR, FT-IR, TGA, DSC, XRD, SEM and EDX. The adsorptive performances of the synthesized polymers for Erichrome Black T (EBT) uptake from aqueous solution were investigated under batch process. Equilibrium, kinetic, and thermodynamic studies were conducted to determine the influence of different operational parameters of the adsorption process. The two most promising polymers among the series show an excellent EBT removal efficiency of ~100% and ~95% with high adsorption capacities of 775 mg·g^-1 and 917 mg·g^-1, respectively at a meager dosage of 5 mg. The sorption of EBT on the polymers was well described by Redlich-Peterson & Langmuir model while the kinetic studies indicate that pseudo-second order model was followed. For the thermodynamic studies, the negative DG and positive DH values obtained suggest a spontaneity of the sorption process which was endothermic in nature. The results of reusability test of the resins were promising even at the fourth cycle, showcasing the potentials of the new polymers in dyes contaminated water treatment.

Key words: Erichrome Black T dye, Cross-linked polymer, Adsorption, Regeneration, Langmuir, Thermodynamics

摘要： A new series of polymers comprising four terpolymers was synthesized via Mannich polycondensation of benzene-1,4-diamine, formaldehyde and piperazine by varying the benzene-1,4-diamine and piperazine ratio. The new polyamines (labeled Dipip) were characterized using ¹³C solid-state NMR, FT-IR, TGA, DSC, XRD, SEM and EDX. The adsorptive performances of the synthesized polymers for Erichrome Black T (EBT) uptake from aqueous solution were investigated under batch process. Equilibrium, kinetic, and thermodynamic studies were conducted to determine the influence of different operational parameters of the adsorption process. The two most promising polymers among the series show an excellent EBT removal efficiency of ~100% and ~95% with high adsorption capacities of 775 mg·g^-1 and 917 mg·g^-1, respectively at a meager dosage of 5 mg. The sorption of EBT on the polymers was well described by Redlich-Peterson & Langmuir model while the kinetic studies indicate that pseudo-second order model was followed. For the thermodynamic studies, the negative DG and positive DH values obtained suggest a spontaneity of the sorption process which was endothermic in nature. The results of reusability test of the resins were promising even at the fourth cycle, showcasing the potentials of the new polymers in dyes contaminated water treatment.

关键词: Erichrome Black T dye, Cross-linked polymer, Adsorption, Regeneration, Langmuir, Thermodynamics

Mohammad Saood Manzar, Shamsuddeen A. Haladu, Mukarram Zubair, Nuhu Dalhat Mu'azu, Aleem Qureshi, Nawaf I. Blaisi, Thomas F. Garrison, Othman Charles S. Al Hamouz. Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 341-352.

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Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

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