%0 Journal Article
%A Hongxia Li
%A Tao Zhang
%A Shaojun Yuan
%A Shengwei Tang
%T MCM-36 zeolites tailored with acidic ionic liquid to regulate adsorption properties of isobutane and 1-butene
%D 2016
%R 10.1016/j.cjche.2016.05.033
%J Chinese Journal of Chemical Engineering
%P 1703-1711
%V 24
%N 12
%X Adsorption properties of an adsorbent or a catalyst towards adsorbates are crucial in the process of adsorption separation or catalytic reaction. Surface morphology and structure of adsorbents have a significant impact on the adsorption properties. In this study, a novel acidic ionic liquid, 1-butyl-3-(triethoxysilylpropyl)imidazolium hydrogen sulfate (i.e.,[BTPIm] [HSO4]), was synthesized and subsequently grafted onto the MCM-36 zeolite for the regulation of its adsorption properties towards isobutane and 1-butene. The resultant[BTPIm] [HSO4]-immobilized MCM-36 (i.e., MCM-36-IL) was characterized by FT-IR, XPS, XRD, SEM, TG/DTG and N2 adsorption-desorption measurement. It was found that the specific surface area, micropore volume and mesopore volume of the MCM-36 support underwent a reduction upon the immobilization of ionic liquid, while the surface density of acid increased from 0.0014 to 0.0035 mmol·m-2. The adsorption capacity of isobutane and 1-butene on the MCM-36-IL was determined by a static volumetric method. Results demonstrated that the interaction between isobutane and MCM-36-IL was enhanced and the interaction between 1-butene and MCM-36-IL was reduced. As a result, a tunable adsorption ratio of isobutane/1-butene on MCM-36 was achieved. With the increase in surface density of acid and the tunable adsorption ratio of isobutane and 1-butene on the functionalized MCM-36, the acidic ionic liquid-immobilized zeolites are beneficial to obtain an improved reaction yield and a prolonged catalyst life in the reactions catalyzed by solid acid.
%U https://cjche.cip.com.cn/EN/10.1016/j.cjche.2016.05.033