%0 Journal Article %A Syieluing Wong %A Yowjeng Lee %A Norzita Ngadi %A Ibrahim Mohammed Inuwa %A Nurul Balqis Mohamed %T Synthesis of activated carbon from spent tea leaves for aspirin removal %D 2018 %R 10.1016/j.cjche.2017.11.004 %J Chinese Journal of Chemical Engineering %P 1003-1011 %V 26 %N 5 %X Adsorption capacity of activated carbon prepared from spent tea leaves (STL-AC) for the removal of aspirin from aqueous solution was investigated in this study. Preliminary studies have shown that treatment with phosphoric acid (H3PO4) increased removal efficiency of STL-AC. Characterizations on STL-AC revealed excellent textural properties (1200 m2·g-1, 51% mesoporosity), as well as distinctive surface chemistry (1.08 mmol·g-1 and 0.54 mmol·g-1 for acidic and basic oxygenated groups, pHpzc=2.02). Maximum removal efficiency of aspirin observed was 94.28% after 60 min when the initial concentration was 100 mg·L-1, 0.5 g of adsorbent used, pH 3 and at a temperature of 30℃. The adsorption data were well fitted to the Freundlich isotherm model and obeyed the pseudo-second order kinetics model. The adsorption of aspirin onto STL-AC was exothermic in nature (ΔHΘ=-13.808 kJ·mol-1) and had a negative entropy change, ΔSΘ (-41.444 J·mol-1). A negative Gibbs free energy, ΔGΘ was obtained indicating feasibility and spontaneity of the adsorption process. The adsorption capacity of AC-STL (178.57 mg·g-1) is considerably high compared to most adsorbents synthesized from various sources, due to the well-defined textural properties coupled with surface chemistry of STL-AC which favors aspirin adsorption. The results demonstrate the potential of STL-AC as aspirin adsorbent. %U https://cjche.cip.com.cn/EN/10.1016/j.cjche.2017.11.004