SCI和EI收录∣中国化工学会会刊

›› 2008, Vol. 16 ›› Issue (3): 365-368.

• SPECIAL ISSUE OF THE FIRST INTERNATIONAL SYMPOSIUM ON SUSTAINABLE CHEMICAL PRODUCT AND PROCESS ENGINEERING • Previous Articles     Next Articles

Sonochemical Synthesis of Maleated Rosin

NIE Yuanmei, YAO Xingdong, LEI Fuhou   

  1. Key Laboratory of Development and Application of Forest Chemicals of Guangxi, Guangxi University of Nation-alities, Nanning 530006, China
  • Received:2007-09-25 Revised:2008-03-25 Online:2008-06-28 Published:2008-06-28
  • Supported by:
    Supported by the Natural Science Foundation of Guangxi Province (0448020);the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry (2005-383);the Guangxi Talent Highland Program

Sonochemical Synthesis of Maleated Rosin

聂园梅, 姚兴东, 雷福厚   

  1. Key Laboratory of Development and Application of Forest Chemicals of Guangxi, Guangxi University of Nation-alities, Nanning 530006, China
  • 通讯作者: YAO Xingdong,E-mail:13321716154@gx165.com
  • 基金资助:
    Supported by the Natural Science Foundation of Guangxi Province (0448020);the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry (2005-383);the Guangxi Talent Highland Program

Abstract: The cycloaddition reaction of rosin and maleic anhydride under ultrasonic irradiation has been investigated. The results show that both isomerization and Diels-Alder cycloaddition reactions were accelerated remarkably. The sonochemical reaction reached equilibrium in 5-10 min at 110℃, comparing with regular synthesis of 4-5 h over 180℃.

Key words: sonochemistry, Diels-Alder reaction, maleated rosin

摘要: The cycloaddition reaction of rosin and maleic anhydride under ultrasonic irradiation has been investigated. The results show that both isomerization and Diels-Alder cycloaddition reactions were accelerated remarkably. The sonochemical reaction reached equilibrium in 5-10 min at 110℃, comparing with regular synthesis of 4-5 h over 180℃.

关键词: sonochemistry, Diels-Alder reaction, maleated rosin