SCI和EI收录∣中国化工学会会刊

›› 2008, Vol. 16 ›› Issue (2): 314-319.

• PROCESS AND PRODUCT TECHNOLOGY • Previous Articles     Next Articles

Effect of Strain and Chloride Concentration on Pitting Susceptibility for Type 304 Austenitic Stainless Steel

LÜ Guocheng1, CHENG Haidong1, XU Chunchun1, HE Zonghu2   

  1. 1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
    2. Department of Chemical, Biomedical, and Materials Engineering, Stevens Institute of Technology, Hoboken, New Jersey 07030, USA
  • Received:2007-10-19 Revised:2008-01-11 Online:2008-04-28 Published:2008-04-28
  • Supported by:
    China Petroleum & Chemical Corporation(306021)

Effect of Strain and Chloride Concentration on Pitting Susceptibility for Type 304 Austenitic Stainless Steel

吕国诚1, 程海东1, 许淳淳1, 何宗虎2   

  1. 1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
    2. Department of Chemical, Biomedical, and Materials Engineering, Stevens Institute of Technology, Hoboken, New Jersey 07030, USA
  • 通讯作者: XU Chunchun,E-mail:chunchunxu@263.net
  • 基金资助:
    China Petroleum & Chemical Corporation(306021)

Abstract: The effects of strain and chloride concentration on pitting susceptibility for type 304 stainless steel were studied in situ using the electrochemical technology under constant strain.The impact factor fε was brought forward to value the effect of strain on pitting.The pitting behaviors of type 304 stainless steel in various chloride concentrations under the strain levels 0%,10%,and 30%were investigated.Potentiostatic polarization technology was used to study how the chloride concentration affected corrosion current density.The results indicated that fε increased substantially and pitting potential varied remarkably when chloride concentration was over 90 mg·L-1. Un-der the three levels of strain mentioned above,when chloride concentration was below 463 mg·L-1,121 mg·L-1,and 98 mg·L-1,respectively,the pitting potential shifted towards positivity and,the passive film became more stable. When the strain was below 10%,the pitting susceptibility of type 304 stainless steel varied greatly as strain increased,whereas the susceptibility only changed a little when the strain was over 10%

Key words: 304 stainless steel, strain, pitting corrosion, chloride concentration

摘要: The effects of strain and chloride concentration on pitting susceptibility for type 304 stainless steel were studied in situ using the electrochemical technology under constant strain.The impact factor fε was brought forward to value the effect of strain on pitting.The pitting behaviors of type 304 stainless steel in various chloride concentrations under the strain levels 0%,10%,and 30%were investigated.Potentiostatic polarization technology was used to study how the chloride concentration affected corrosion current density.The results indicated that fε increased substantially and pitting potential varied remarkably when chloride concentration was over 90 mg·L-1. Un-der the three levels of strain mentioned above,when chloride concentration was below 463 mg·L-1,121 mg·L-1,and 98 mg·L-1,respectively,the pitting potential shifted towards positivity and,the passive film became more stable. When the strain was below 10%,the pitting susceptibility of type 304 stainless steel varied greatly as strain increased,whereas the susceptibility only changed a little when the strain was over 10%

关键词: 304 stainless steel, strain, pitting corrosion, chloride concentration