Adsorption Refrigeration Performance of Shaped MIL-101-Water Working Pair

doi:10.1016/S1004-9541(14)60076-8

Abstract

Abstract: A new metal-organic framework of MIL-101 was synthesized by hydrothermal method and the powder prepared was pressed into a desired shape. The effects of molding on specific surface area and pore structure were investigated using a nitrogen adsorption method. The water adsorption isotherms were obtained by high vacuum gravimetric method, the desorption temperature of water on shaped MIL-101 was measured by thermo gravimetric analyzer, and the adsorption refrigeration performance of shaped MIL-101-water working pair was studied on the simulation device of adsorption refrigeration cycle system. The results indicate that an apparent hysteresis loop appears in the nitrogen adsorption/desorption isotherms when the forming pressure is 10 MPa. The equilibrium adsorption capacity of water is up to 0.95 kg·kg^-1 at the forming pressure of 3 MPa (MIL-101-3). The desorption peak temperature of water on MIL-101-3 is 82℃, which is 7℃ lower than that of silica gel, and the desorption temperature is no more than 100℃. At the evaporation temperature of 10℃, the refrigeration capacity of MIL-101-3-water is 1059 kJ·kg^-1, which is 2.24 times higher than that of silica gel-water working pair. Thus MIL-101-water working pair presents an excellent adsorption refrigeration performance.

Key words: adsorption refrigeration, MIL-101, forming, adsorption capacity, refrigeration capacity

摘要： A new metal-organic framework of MIL-101 was synthesized by hydrothermal method and the powder prepared was pressed into a desired shape. The effects of molding on specific surface area and pore structure were investigated using a nitrogen adsorption method. The water adsorption isotherms were obtained by high vacuum gravimetric method, the desorption temperature of water on shaped MIL-101 was measured by thermo gravimetric analyzer, and the adsorption refrigeration performance of shaped MIL-101-water working pair was studied on the simulation device of adsorption refrigeration cycle system. The results indicate that an apparent hysteresis loop appears in the nitrogen adsorption/desorption isotherms when the forming pressure is 10 MPa. The equilibrium adsorption capacity of water is up to 0.95 kg·kg^-1 at the forming pressure of 3 MPa (MIL-101-3). The desorption peak temperature of water on MIL-101-3 is 82℃, which is 7℃ lower than that of silica gel, and the desorption temperature is no more than 100℃. At the evaporation temperature of 10℃, the refrigeration capacity of MIL-101-3-water is 1059 kJ·kg^-1, which is 2.24 times higher than that of silica gel-water working pair. Thus MIL-101-water working pair presents an excellent adsorption refrigeration performance.

关键词: adsorption refrigeration, MIL-101, forming, adsorption capacity, refrigeration capacity

RUI Zhengqiu, LI Quanguo, CUI Qun, WANG Haiyan, CHEN Haijun, YAO Huqing. Adsorption Refrigeration Performance of Shaped MIL-101-Water Working Pair[J]. Chin.J.Chem.Eng., 2014, 22(5): 570-575.

芮征球, 李全国, 崔群, 王海燕, 陈海军, 姚虎卿. Adsorption Refrigeration Performance of Shaped MIL-101-Water Working Pair[J]. Chinese Journal of Chemical Engineering, 2014, 22(5): 570-575.

References

1 Wang, R.Z., Oliveira, R.G., "Adsorption refrigeration-An efficient way to make good use of waste heat and solar Energy", Prog. Energy Combust. Sci., 32 (24), 424-458 (2006).

2 Saha, B.B., Koyama, S., Lee, J.B., Kuwahara, K., Alam, K.C.A., "Performance evaluation of a low-temperature waste heat driven multi-bed adsorption chiller", Int. J. Multiphase Flow, 29 (8), 1249-1263 (2003).

3 Saha, B.B., Koyama, S., Kashiwagi, T., Akisawa, A., Ng, K.C., Chua, H.T., "Waste heat driven dual-mode, multi-stage, multi-bed regenerative adsorption system", Int. J. Refriger., 26 (7), 749-757 (2003).

4 Boubakri, A., Guillemiont, J.J., Meunier, F., "Adsorptive solar powered ice-maker: Experiments and model", Solar Energ, 69 (3), 249-263 (2000).

5 Henninger, S.K., Schicktanz, M., Hugenell, P.P.C., Sievers, H., Henning, H.M., "Evaluation of methanol adsorption on activated carbons for thermally driven chillers part I: Thermophysical characterization", Int. J. Refriger., 35 (3), 543-553 (2012).

6 Henninger, S.K., Schmidt, F.P., Henning, H.M., "Water adsorption characteristics of novel materials for heat transformation applications", Appl. Thermal Eng., 30 (13), 1692-1702 (2010).

7 Zhong, Y., Critoph, R.E., Thorpe, R., "Evaluation of the performance of solid sorption refrigeration systems using carbon dioxide as refrigerant", Appl. Thermal Eng., 26 (16), 1807-1811 (2006).

8 Ferey, G., "Hybrid porous solids: past, present, future", Chemical Society Reviews, 37 (1), 191-214 (2008).

9 Chae, H.K., Siberio-Perez, D.Y., Jaheon, K., Go, Y.B., Eddaoudi, M., Matzger, A.J., Okeeffe, M., Yaghi, O.M., "A route to high surface area, porosity and inclusion of large molecules in crystals", Nature, 427 (6974), 523-527 (2004).

10 Zhao, X.B., Xiao, B., Fletcher, A.J., Thomas, K.M., Bradshaw, D., Rosseinsky, M.J., "Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks", Science, 306 (5698), 1012-1015 (2004).

11 Kitagawa, S., Kitaura, R., Noro, S., "Functional porous coordination polymers", Angewandet Chemie International Edition, 43 (18), 2234-2375 (2004).

12 Ferey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surble, S., Margiolaki, I., "Achromium terephthalate-based solid with unusually large pore volumes and surface area", Science, 309 (5743), 2040-2043 (2005).

13 Latroche, M., Surble, S., Serre, C., Mellot-Draznieks, C., Llewellyn, P.L., Lee, J., Chang, J., Jhung, S.H., Ferey, G., "Hydrogen storage in the giant-pore metal-organic frameworks MIL-100 and MIL-101", Angewandet Chemie International Edition, 45 (48), 8227-8231 (2006).

14 Khan, N.A., Kang, I.J., Seok, H.Y., Jhung, S.H., "Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101", Chem. Eng. J., 166 (3), 1152-1157 (2011).

15 Jhung, S.H., Lee, J.H., Yoon, J.W., Serre, C., Ferey, G., Chang, J.S., "Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption bbility", Adv. Mater., 19 (1), 121-124 (2007).

16 Henninger, S.K., Hesham, A.H., Christoph, J., "MOFs as adsorbents for low temperature heating and cooling applications", JACS, 131 (8), 2776-2777 (2009).

17 Ehrenmann, J., Henninger, S.K., Janiak, C., "Water adsorption characteristics of MIL-101 for heat transformation applications of MOFs", Eur. J. Inorg. Chem., 2011 (4), 471-474 (2011).

18 Pradip, C., Chaitanya, B., Sasidhar, G., "Gas adsorption properties of the chromium-based metal organic framework MIL-101", American Chemical Society, 113 (16), 6616-6621 (2009).

19 Chen, H.J., Cui, Q., Tang, Y., Chen, X.J., Yao, H.Q., "Attapulgite based LiCl composite adsorbents for cooling and air conditioning applications", Appl. Thermal Eng., 28 (17/18), 2187-2193 (2008).

20 Cui, Q., Tao, G., Chen, H.J., Guo, X.Y., Yao, H.Q., "Environmentally benign working pairs for adsorption refrigeration", Energy, 30 (2-4), 261-271 (2005).

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