Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

doi:10.1016/j.cjche.2014.09.010

›› 2014, Vol. 22 ›› Issue (10): 1174-1177.DOI: 10.1016/j.cjche.2014.09.010

• RESEARCH NOTES • Previous Articles

Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

Hualing Yang^1,2, Ji Chen¹, WeiWang³, Hongmin Cui¹, Dongli Zhang¹, Yu Liu¹

1 State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2 School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China;
3 Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, China Academy of Geological Sciences, Zhengzhou 450006, China

Received:2013-08-02 Revised:2013-12-18 Online:2014-12-01 Published:2014-10-28
Supported by:
Supported by the National Natural Science Foundation of China (51174184), the National Basic Research Program of China (2012CBA01202), the Key Research Program of the Chinese Academy of Sciences (KGZD-EW-201-1), the Science and Technology Plan of Nantong City (BK2013030), the University Science Research Project of Jiangsu Province (14KJB150019), Open Subject of Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (RERU2014016).

Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

Hualing Yang^1,2, Ji Chen¹, WeiWang³, Hongmin Cui¹, Dongli Zhang¹, Yu Liu¹

1 State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2 School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China;
3 Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, China Academy of Geological Sciences, Zhengzhou 450006, China

通讯作者: Ji Chen
基金资助:
Supported by the National Natural Science Foundation of China (51174184), the National Basic Research Program of China (2012CBA01202), the Key Research Program of the Chinese Academy of Sciences (KGZD-EW-201-1), the Science and Technology Plan of Nantong City (BK2013030), the University Science Research Project of Jiangsu Province (14KJB150019), Open Subject of Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (RERU2014016).

Abstract

Abstract: The extraction kinetics of La(Ⅲ) from aqueous chloride solutions into n-heptane solutions of bifunctional ionic liquid extractant [A336][CA-12] (tricaprylmethylammonium sec-octylphenoxy acetic acid) was investigated using a constant interfacial cell with laminar flow. The effects of stirring speed, temperature and specific interfacial area on the extraction rate were examined. The results indicate that mass transfer kinetics of La(Ⅲ) is a mixed-controlled process influenced by interfacial reaction. On the basis ofmass transfer kinetic results in the extraction of La(Ⅲ) by [A336][CA-12], the extraction rate equation of La(Ⅲ) is proposed in terms of pseudo-firstorder constants, which is supported by the measured thermodynamic equations. The mass-transfer kinetic model deduced from the rate controlling step is adequate to interpret the experimental data qualitatively.

Key words: Extraction kinetics, Bifunctional ionic liquid, Constant interfacial cell with laminar flow

摘要： The extraction kinetics of La(Ⅲ) from aqueous chloride solutions into n-heptane solutions of bifunctional ionic liquid extractant [A336][CA-12] (tricaprylmethylammonium sec-octylphenoxy acetic acid) was investigated using a constant interfacial cell with laminar flow. The effects of stirring speed, temperature and specific interfacial area on the extraction rate were examined. The results indicate that mass transfer kinetics of La(Ⅲ) is a mixed-controlled process influenced by interfacial reaction. On the basis ofmass transfer kinetic results in the extraction of La(Ⅲ) by [A336][CA-12], the extraction rate equation of La(Ⅲ) is proposed in terms of pseudo-firstorder constants, which is supported by the measured thermodynamic equations. The mass-transfer kinetic model deduced from the rate controlling step is adequate to interpret the experimental data qualitatively.

关键词: Extraction kinetics, Bifunctional ionic liquid, Constant interfacial cell with laminar flow

Hualing Yang, Ji Chen, WeiWang, Hongmin Cui, Dongli Zhang, Yu Liu. Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow[J]. , 2014, 22(10): 1174-1177.

References

[1] J.G. Huddleston, H.D.Willauer, R.P.A.E. Swatloski, R.D. Rogers Visser, Room temperature ionic liquids as novel media for ‘clean' liquid-liquid extraction, Chem. Commun. 16 (1998) 1765-1766.
[2] J.H. Davis, Task-specific ionic liquids, Chem. Lett. 33 (2004) 1072-1077.
[3] V.M. Egorov, D.I. Djigailo, D.S. Momotenko, D.V. Chernyshov, I.I. Torocheshnikova, S.V. Smirnova, I.V. Pletnev, Task-specific ionic liquid trioctylmethylammonium salicylate as extraction solvent for transition metal ions, Talanta 80 (3) (2010) 1177-1182.
[4] D. Kogelnig, A. Stojanovic, M. Galanski, M. Groessl, F. Jirsa, R. Krachler, B.K. Keppler, Greener synthesis of new ammonium ionic liquids and their potential as extracting agents, Tetrahedron Lett. 49 (17) (2008) 2782-2785.
[5] Y.H. Liu, L.L. Zhu, X.Q. Sun, J. Chen, Toward greener separations of rare earths: bifunctional ionic liquid extractants in biodiesel, AICHE J. 56 (9) (2010) 2338-2346.
[6] H.M. Luo, S. Dai, P.V. Bonnesen, Solvent extraction of Sr²⁺ and Cs⁺ based on roomtemperature ionic liquids containing monoa-za-substituted crown ethers, Anal. Chem. 76 (10) (2004) 2773-2779.
[7] W. Wang, Y. Liu, A.M. Xu, H.L. Yang, H.M. Cui, J. Chen, Solvent extraction of yttrium by task-specific ionic liquids bearing carboxylic group, Chin. J. Chem. Eng. 20 (1) (2012) 40-46.
[8] A. Ouadi, B. Gadenne, P. Hesemann, J.J.E. Moreau, I. Billard, C. Gaillard, S. Mekki, G. Moutiers, Task-specific ionic liquids bearing 2-hydroxybenzylamine units: synthesis and americium-extraction studies, Chem. Eur. J. 12 (11) (2006) 3074-3081.
[9] A. Ouadi, O. Klimchuk, C. Gaillard, I. Billard, Solvent extraction of U(VI) by task specific ionic liquids bearing phosphoryl groups, Green Chem. 9 (11) (2007) 1160-1162.
[10] X.Q. Sun, Y. Ji, F. Hu, B. He, J. Chen, D.Q. Li, The inner synergistic effect of bifunctional ionic liquid extractant for solvent extraction, Talanta 81 (4-5) (2010) 1877-1883.
[11] J.P. Mikkola, P. Virtanena, R. Sjöholm, Aliquat 336((R))—a versatile and affordable cation source for an entirely new family of hydrophobic ionic liquids, Green Chem. 8 (3) (2006) 250-255.
[12] X.Q. Sun, Y. Ji, Y. Liu, J. Chen, D.Q. Li, An engineering-purpose preparation strategy for ammonium-type ionic liquid with high purity, AICHE J. 56 (4) (2010) 989-996.
[13] W. Wang, H.L. Yang, H.M. Cui, D.L. Zhang, Y. Liu, J. Chen, Application of bifunctional ionic liquid extractants [A336][CA-12] and [A336][CA-100] to the lanthanumextraction and separation from rare earths in the chloride medium, Ind. Eng. Chem. Res. 50 (12) (2011) 7534-7541.
[14] D.L. Zhang, W.Wang, Y.F. Deng, J.P. Zhang, H. Zhao, J. Chen, Extraction and recovery of Cerium(IV) and Fluorine(I) from sulfuric solutions using bifunctional ionic liquid extractants, Chem. Eng. J. 179 (2012) 19-25.
[15] H.L. Yang,W.Wang, H.M. Cui, J. Chen, Extraction mechanism of rare earths with bifunctional ionic liquids [A336][CA-12]/[A336][CA-100] in nitrate medium, Chin. J. Anal. Chem. 39 (10) (2011) 1561-1566.
[16] W. Li, X.L. Wang, S.L. Meng, D.Q. Li, Y. Xiong, Extraction and separation of yttrium from the rare earths with sec-octylphenoxy acetic acid in chloride media, Sep. Purif. Technol. 54 (2) (2007) 164-169.
[17] G.X. Xu, Rare Earths, Metallurgical Industry Press, Beijing, 1995. 471-500.
[18] X.L. Wang, S.L. Meng, D.Q. Li, Extraction kinetics of ytterbium (Ⅲ) by 2- ethylhexylphosphonic acidmono-(2-ethylhexyl) ester in the presence of isooctanol using a constant interfacial cell with laminar flow, Sep. Purif. Technol. 71 (1) (2010) 50-55.
[19] J.H. Lü, J.D. Liu, Y.J. Sun, C.L. Li, Kinetics of forward extraction of boric acid from salt lake brine by 2-ethyl-1,3-hexanediol in toluene using single drop technique, Chin. J. Chem. Eng. 22 (5) (2014) 496-502.
[20] X.Q. He, K. Huang, P.H. Yu, C. Zhang, K. Xie, P.F. Li, J.Wang, Z.T. An, H.Z. Liu, Liquid- liquid-liquid three phase extraction apparatus: operation strategy and influences on mass transfer efficiency, Chin. J. Chem. Eng. 20 (1) (2012) 27-35.
[21] Z. Zheng, J. Lu, D.Q. Li, G.X. Ma, The kinetics study in liquid-liquid systems with constant interfacial area cell with laminar flow, Chem. Eng. Sci. 53 (13) (1998) 2327-2333.
[22] D.B. Wu, X.L. Wang, D.Q. Li, Extraction kinetics of Sc(Ⅲ), Y(Ⅲ), La(Ⅲ) and Gd(Ⅲ) from chloride medium by Cyanex 302 in heptane using the constant interfacial cell with laminar flow, Chem. Eng. Process. 46 (1) (2007) 17-24.
[23] J.M. Zhao, W. Li, D.Q. Li, Y. Xiong, Kinetics of cerium(IV) extraction with DEHEHP from HNO3-HF medium using a constant interfacial cell with laminar flow, Ion Exch. Solvent Extr. 24 (2) (2006) 165-176.
[24] Y. Xiong, Z.N. Lou, S. Yue, J.J. Song, W.J. Shan, G.X. Han, Kinetics and mechanism of Re(VII) extraction with mixtures of tri-alkylamine and tri-n-butylphosphate, Hydrometallurgy 100 (3-4) (2010) 110-115.
[25] D.B. Wu, Y. Xiong, D.Q. Li, Mass transfer kinetics of yttrium(Ⅲ) using a constant interfacial cell with laminar flow. Part I. extraction with cyanex 302, Hydrometallurgy 82 (3-4) (2006) 176-183.
[26] J.J. Liu, Y.L. Wang, D.Q. Li, Extraction kinetics of thorium(IV) with primary amine N1923 in sulfate media using a constant interfacial cell with laminar flow, Sep. Sci. Technol. 43 (2) (2008) 431-445.
[27] J.J. Liu, Y.L. Wang, D.Q. Li, Extraction kinetics of cerium(IV) from sulfuric acid medium by the primary amine N1923 using a constant interfacial area cell with laminar flow, J. Chem. Technol. Biotechnol. 82 (10) (2007) 949-955.
[28] W.P. Liao, G.H. Yu, S.T. Yue, D.Q. Li, Kinetics of cerium(IV) extraction from H2SO4-HF medium with cyanex 923, Talanta 56 (4) (2002) 613-618.
[29] P.R. Danesi, G.F. Vandegrift, Kinetics and mechanism of the interfacial mass transfer of europium(3+) and americium(3+) in the system bis(2-ethylhexyl)-phosphaten- dodecane-sodium chloride-hydro chloric acid-water, J. Phys. Chem. 85 (24) (1981) 3646-3651.

Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

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