Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers

doi:10.1016/j.cjche.2013.08.004

Chin.J.Chem.Eng. ›› 2015, Vol. 23 ›› Issue (6): 919-923.DOI: 10.1016/j.cjche.2013.08.004

• SEPARATION SCIENCE AND ENGINEERING • Previous Articles Next Articles

Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers

Ya Fu¹, JiaanWu¹, Hongan Zhou¹, Guanping Jin^1,2

1 Department of Application Chemistry of School of Chemical Engineering, Hefei University of Technology, Hefei 230009, PR China;
2 Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, Hefei 230009, PR China

Received:2013-04-28 Revised:2013-08-18 Online:2015-07-09 Published:2015-06-28
Contact: Guanping Jin
Supported by:
Supported by the National Natural Science Foundation of China (21076054 and U140710231), the Natural Science Important Foundation of Educational Commission of Anhui Province (2010AJZR-85, 2011AJZR-87), Study Foundation of New Product and Technology of Anhui Economic and Information Technology Commission (2012AHST0797, 2013CXSY327 and 2013CXSY366), and National College Student Innovation Fund (2014CXCY321 and 2014CXCY349).

Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers

Ya Fu¹, JiaanWu¹, Hongan Zhou¹, Guanping Jin^1,2

1 Department of Application Chemistry of School of Chemical Engineering, Hefei University of Technology, Hefei 230009, PR China;
2 Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, Hefei 230009, PR China

通讯作者: Guanping Jin
基金资助:
Supported by the National Natural Science Foundation of China (21076054 and U140710231), the Natural Science Important Foundation of Educational Commission of Anhui Province (2010AJZR-85, 2011AJZR-87), Study Foundation of New Product and Technology of Anhui Economic and Information Technology Commission (2012AHST0797, 2013CXSY327 and 2013CXSY366), and National College Student Innovation Fund (2014CXCY321 and 2014CXCY349).

Abstract

Abstract: Iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers (PGMA-IDA/CFs) were prepared for Ni(II) removal from aqueous solutions. The effects of solution pH value, temperature and adsorption time were investigated. The maximum adsorption capacity of Ni(II) on PGMA-IDA/CFs is 0.923 mmol·L^-1 · g^-1 at pH 5.2 and 50 ℃. Kinetic data indicate that the adsorption process matches the pseudo-second-order model and Elovich kinetic model. Thermodynamic data suggest that the adsorption process is endothermic spontaneous reaction.

Key words: Iminodiacetic acid, Glycidyl methacrylate, Carbon fiber, Adsorption, Nickel(II)

摘要： Iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers (PGMA-IDA/CFs) were prepared for Ni(II) removal from aqueous solutions. The effects of solution pH value, temperature and adsorption time were investigated. The maximum adsorption capacity of Ni(II) on PGMA-IDA/CFs is 0.923 mmol·L^-1 · g^-1 at pH 5.2 and 50 ℃. Kinetic data indicate that the adsorption process matches the pseudo-second-order model and Elovich kinetic model. Thermodynamic data suggest that the adsorption process is endothermic spontaneous reaction.

关键词: Iminodiacetic acid, Glycidyl methacrylate, Carbon fiber, Adsorption, Nickel(II)

Ya Fu, JiaanWu, Hongan Zhou, Guanping Jin. Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers[J]. Chin.J.Chem.Eng., 2015, 23(6): 919-923.

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Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers

Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers

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