SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2021, Vol. 33 ›› Issue (5): 256-267.DOI: 10.1016/j.cjche.2020.07.061

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Microwave energy inductive fluidized metal particles discharge behavior and its potential utilization in reaction intensification

Xingang Li, Chuanrui Pang, Hong Li, Xin Gao   

  1. School of Chemical Engineering and Technology, National Engineering Research Center of Distillation Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),;
    Tianjin University, Tianjin 300072, China
  • Received:2020-06-19 Revised:2020-07-14 Online:2021-08-19 Published:2021-05-28
  • Contact: Xin Gao
  • Supported by:
    The authors are grateful for financial support from the National Natural Science Foundation of China (21878219) and the National Key R&D Program of China (2018YFB0604900).

Microwave energy inductive fluidized metal particles discharge behavior and its potential utilization in reaction intensification

Xingang Li, Chuanrui Pang, Hong Li, Xin Gao   

  1. School of Chemical Engineering and Technology, National Engineering Research Center of Distillation Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),;
    Tianjin University, Tianjin 300072, China
  • 通讯作者: Xin Gao
  • 基金资助:
    The authors are grateful for financial support from the National Natural Science Foundation of China (21878219) and the National Key R&D Program of China (2018YFB0604900).

Abstract: Microwave-induced metal discharge (MMD) technology offers a novel methodology for efficient gas-phase catalytic reaction due to its unique heating effect, plasma effect and discharge effect. Herein, we successfully used a special kind of uniformly distributed particles with synergistic microwave-induced fluidized-metal discharge (MFD) effect. A lab-scale atmospheric quartz tube fluidized bed reactor was designed. Apparatus like highspeed camera, fiber spectrometer and infrared thermometer were used to record the discharge phenomena. The effects of operating conditions such as gas velocity, microwave power, carrier gas type, and metal type on the discharge behavior were investigated in detail. Subsequently, the MFD was applied into the methane dry reform reaction (MDR) with excellent conversion compared with the conventional heating conditions. Gratifyingly, the metal particles can both be the converter of microwave and the catalyst of the reaction. The reported conclusion provides a novel way to intensification the reaction process and utilize microwave energy.

Key words: MDR, Non-equilibrium plasma, Microwave-induced discharge, Fluidized metal

摘要: Microwave-induced metal discharge (MMD) technology offers a novel methodology for efficient gas-phase catalytic reaction due to its unique heating effect, plasma effect and discharge effect. Herein, we successfully used a special kind of uniformly distributed particles with synergistic microwave-induced fluidized-metal discharge (MFD) effect. A lab-scale atmospheric quartz tube fluidized bed reactor was designed. Apparatus like highspeed camera, fiber spectrometer and infrared thermometer were used to record the discharge phenomena. The effects of operating conditions such as gas velocity, microwave power, carrier gas type, and metal type on the discharge behavior were investigated in detail. Subsequently, the MFD was applied into the methane dry reform reaction (MDR) with excellent conversion compared with the conventional heating conditions. Gratifyingly, the metal particles can both be the converter of microwave and the catalyst of the reaction. The reported conclusion provides a novel way to intensification the reaction process and utilize microwave energy.

关键词: MDR, Non-equilibrium plasma, Microwave-induced discharge, Fluidized metal