Abstract: Flow property of coal ash and slag is an important parameter for slag tapping of entrained flow gasifier. The viscosity of slag with high contents of calcium and iron exhibits the behavior of a crystalline slag, of which viscosity sharply increases when temperature is lowered than temperature of critical viscosity (T_CV). The fluctuation in temperature near the T_CV can cause an accumulation of slag inside the gasifier. In order to prevent slag blockage, it is necessary to adjust the ash composition by additive to modify the flow property of coal rich in calcium and iron. Main components of coal gangue are Al₂O₃ and SiO₂, which is a potential additive to modify the ash flow properties of these coals. In this work, we investigated the ash flow properties of a typical coal rich in calcium and iron by adding coal gangue with different SiO₂/Al₂O₃ ratio. The results showed that the ash fusion temperatures (AFTs) firstly decreased, and then increased with increasing amount of coal gangue addition. Chemical composition of coal ash rich in calcium and iron moved from gehlenite primary phase to anorthite, quartz and corundum primary phases. The slags with coal gangue addition behaved as a glassy slag, of which the viscosity gradually increased as temperature decreased. Besides, a high SiO₂/Al₂O₃ ratio of coal gangue was beneficial to modify the slag viscosity behavior. Addition of coal gangue with a high SiO₂/Al₂O₃ ratio impeded formation of crystalline phases during cooling. This work demonstrated that coal gangue addition was an effective way to improve the ash flow properties of the coal rich in calcium and iron for the entrained flow gasifier.

Key words: Coal gangue, Coal rich in calcium and iron, Ash fusion temperatures, Viscosity-temperature characteristic, Phase transformation

摘要： Flow property of coal ash and slag is an important parameter for slag tapping of entrained flow gasifier. The viscosity of slag with high contents of calcium and iron exhibits the behavior of a crystalline slag, of which viscosity sharply increases when temperature is lowered than temperature of critical viscosity (T_CV). The fluctuation in temperature near the T_CV can cause an accumulation of slag inside the gasifier. In order to prevent slag blockage, it is necessary to adjust the ash composition by additive to modify the flow property of coal rich in calcium and iron. Main components of coal gangue are Al₂O₃ and SiO₂, which is a potential additive to modify the ash flow properties of these coals. In this work, we investigated the ash flow properties of a typical coal rich in calcium and iron by adding coal gangue with different SiO₂/Al₂O₃ ratio. The results showed that the ash fusion temperatures (AFTs) firstly decreased, and then increased with increasing amount of coal gangue addition. Chemical composition of coal ash rich in calcium and iron moved from gehlenite primary phase to anorthite, quartz and corundum primary phases. The slags with coal gangue addition behaved as a glassy slag, of which the viscosity gradually increased as temperature decreased. Besides, a high SiO₂/Al₂O₃ ratio of coal gangue was beneficial to modify the slag viscosity behavior. Addition of coal gangue with a high SiO₂/Al₂O₃ ratio impeded formation of crystalline phases during cooling. This work demonstrated that coal gangue addition was an effective way to improve the ash flow properties of the coal rich in calcium and iron for the entrained flow gasifier.

关键词: Coal gangue, Coal rich in calcium and iron, Ash fusion temperatures, Viscosity-temperature characteristic, Phase transformation