Efficient, continuous oxidation of durene to pyromellitic dianhydride mediated by a V-Ti-P ternary catalyst: The remarkable doping effect

doi:10.1016/j.cjche.2022.03.026

Chinese Journal of Chemical Engineering ›› 2023, Vol. 55 ›› Issue (3): 156-164.DOI: 10.1016/j.cjche.2022.03.026

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Efficient, continuous oxidation of durene to pyromellitic dianhydride mediated by a V-Ti-P ternary catalyst: The remarkable doping effect

Da Ke, Minjia Wang, Jiancheng Ruan, Xinzhi Chen, Shaodong Zhou

College of Chemical and Biological Engineering, Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, Zhejiang University, Hangzhou 310027, China;Institute of Zhejiang University – Quzhou, Quzhou 324000, China

Received:2022-02-18 Revised:2022-03-14 Online:2023-06-03 Published:2023-03-28
Contact: Shaodong Zhou,E-mail:szhou@zju.edu.cn
Supported by:
Generous financial support by the National Natural Science Foundation of China (21878265).

Efficient, continuous oxidation of durene to pyromellitic dianhydride mediated by a V-Ti-P ternary catalyst: The remarkable doping effect

Da Ke, Minjia Wang, Jiancheng Ruan, Xinzhi Chen, Shaodong Zhou

College of Chemical and Biological Engineering, Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, Zhejiang University, Hangzhou 310027, China;Institute of Zhejiang University – Quzhou, Quzhou 324000, China

通讯作者: Shaodong Zhou,E-mail:szhou@zju.edu.cn
基金资助:
Generous financial support by the National Natural Science Foundation of China (21878265).

Abstract

Abstract: Continuous preparation of pyromellitic dianhydride (PMDA) from durene has been studied using a fixed-bed reactor. The reaction was performed using a phosphorus-vanadium-titanium ternary catalyst. Relatively high selectivity and yield of PMDA was obtained. The in-situ characterization was combined with theoretical calculation to reveal the reaction mechanisms, and the remarkable doping effect was discussed.

Key words: Continuous oxidation, Anhydride, C-H activation, V-Ti-P ternary catalyst

摘要： Continuous preparation of pyromellitic dianhydride (PMDA) from durene has been studied using a fixed-bed reactor. The reaction was performed using a phosphorus-vanadium-titanium ternary catalyst. Relatively high selectivity and yield of PMDA was obtained. The in-situ characterization was combined with theoretical calculation to reveal the reaction mechanisms, and the remarkable doping effect was discussed.

关键词: Continuous oxidation, Anhydride, C-H activation, V-Ti-P ternary catalyst

Da Ke, Minjia Wang, Jiancheng Ruan, Xinzhi Chen, Shaodong Zhou. Efficient, continuous oxidation of durene to pyromellitic dianhydride mediated by a V-Ti-P ternary catalyst: The remarkable doping effect[J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 156-164.

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Efficient, continuous oxidation of durene to pyromellitic dianhydride mediated by a V-Ti-P ternary catalyst: The remarkable doping effect

Efficient, continuous oxidation of durene to pyromellitic dianhydride mediated by a V-Ti-P ternary catalyst: The remarkable doping effect

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