Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

›› 2010, Vol. 18 ›› Issue (2): 337-345.

• PRODUCT ENGINEERING AND CHEMICAL TECHNOLOGY • Previous Articles Next Articles

Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

PANG Xuehui^1,2, RAN Xiangbin³, KUANG Fei⁴, XIE Jiandong⁵, HOU Baorong²

1. School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
2. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China;
3. Research Center for Marine Ecology, First Institute of Oceanography, SOA, Qingdao 266061, China;
4. School fo Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 637001, China;
5. Shandong Jianzhu University, Jinan 250014, China

Received:2009-06-05 Revised:2009-11-02 Online:2010-04-28 Published:2010-04-28
Supported by:
Supported by the National Science & Technology Pillar Program(082603101c);China Postdoctoral Science Foundation (O92623101H);Shandong Postdoctoral Foundation(200902040);Open Project Program of Marine Corrosion and Protection Research Center of Institute of Oceanology,Chinese Academy of Science(200901005);Doctor Foundation of University of Jinan(XBS0899)

Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

庞雪辉^1,2, 冉祥滨³, 匡飞⁴, 解建东⁵, 侯保荣²

1. School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
2. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China;
3. Research Center for Marine Ecology, First Institute of Oceanography, SOA, Qingdao 266061, China;
4. School fo Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 637001, China;
5. Shandong Jianzhu University, Jinan 250014, China

通讯作者: PANG Xuehu,E-mail:pxh791118@163.com
基金资助:
Supported by the National Science & Technology Pillar Program(082603101c);China Postdoctoral Science Foundation (O92623101H);Shandong Postdoctoral Foundation(200902040);Open Project Program of Marine Corrosion and Protection Research Center of Institute of Oceanology,Chinese Academy of Science(200901005);Doctor Foundation of University of Jinan(XBS0899)

Abstract

Abstract: The inhibiting effect of ciprofloxacin,norfloxacin and ofloxacin on the corrosion of mild steel in 1 mol·L^-1 HCl and the mechanism were studied at different temperatures using mass loss measurement,electrochemical method,and X-ray photoelectron spectroscopy(XPS) .Effective inhibition was shown by mass loss,potentiodynamic polarization and impedance spectroscopy measurement.The corrosion rate of the metal in the mass loss measurement,and the corrosion reaction on cathode and anode in the electrochemical measurement were accelerated when temperature was increased.XPS results showed that the inhibitors adsorbed effectively on the metal surface.

Key words: corrosion, inhibition, electrochemical impedance spectroscopy, potentiodynamic polarization, X-ray photoelectron spectroscopy

摘要： The inhibiting effect of ciprofloxacin,norfloxacin and ofloxacin on the corrosion of mild steel in 1 mol·L^-1 HCl and the mechanism were studied at different temperatures using mass loss measurement,electrochemical method,and X-ray photoelectron spectroscopy(XPS) .Effective inhibition was shown by mass loss,potentiodynamic polarization and impedance spectroscopy measurement.The corrosion rate of the metal in the mass loss measurement,and the corrosion reaction on cathode and anode in the electrochemical measurement were accelerated when temperature was increased.XPS results showed that the inhibitors adsorbed effectively on the metal surface.

关键词: corrosion, inhibition, electrochemical impedance spectroscopy, potentiodynamic polarization, X-ray photoelectron spectroscopy

PANG Xuehui, RAN Xiangbin, KUANG Fei, XIE Jiandong, HOU Baorong. Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid[J]. , 2010, 18(2): 337-345.

庞雪辉, 冉祥滨, 匡飞, 解建东, 侯保荣. Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid[J]. , 2010, 18(2): 337-345.

References

1 Sanyal, B., “Organic compounds as corrosion inhibitors in different environments-A review”, Prog. Org. Coat., 9, 165-236 (1981).
2 Nathan, C.C., Corrosion Inhibitors, NACE, Houston (1973).
3 Ranney, M.W., Inhibitors-Manufacture and Technology, Noyes Data Corp, New Jersey (1976).
4 Putilova, N., Balezin, S.A., Barannik, V.P., Metallic Corrosion Inhibitors, Pergamon Press, London (1966).
5 Xiao, M.T., Huang, Y.Y., Meng, C., Guo, Y.H., “Kinetics of asymmetric reduction of phenylglyoxylic acid to R-(-)-mandelic acid by Saccharomyces cerevisiae FD11b”, Chin. J. Chem. Eng., 14 (1), 73-80 (2006).
6 Eldredge, G.G., Warner, J.C., The Corrosion Hand Book, Wiley, New York, 905 (1948).
7 Solmaz, R., Kardas, G., Yazici, B., Erbil, M., “Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-1,3,4-thiadiazole on mild steel in hydrochloric acid media”, Colloid. Surf. Physicochem. Eng. Aspect., 312, 7-17 (2008).
8 Negm, N.A., Zaki, M.F., “Corrosion inhibition efficiency of nonionic Schiff base amphiphiles of p-aminobenzoic acid for aluminum in 4N HCl”, Colloid Surface Physicochem Eng Aspect, 322, 97-102 (2008).
9 Machnikova1, E., Whitmire, K.H., Hackerman, N., “Corrosion inhibition of carbon steel in hydrochloric acid by furan derivatives”, Electrochimica Acta, 53, 6024-6032 (2008).
10 Avci, G., “Corrosion inhibition of indole-3-acetic acid on mild steel in 0.5M HCl”, Colloid. Surf. Physicochem. Eng. Aspect., 317, 730-736 (2008).
11 Satpati, A.K., Ravindran, P.V., “Electrochemical study of the inhibition of corrosion of stainless steel by 1,2,3-benzotriazole in acidic media”, Mater. Chem. Phys., 109, 352-359 (2008).
12 Lebrini, M., Traisnel, M., Lagrene'e, M., Mernari, B., Bentiss, F.I., “Inhibitive properties, adsorption and a theoretical study of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles as corrosion inhibitors for mild steel in perchloric acid”, Corros. Sci., 50, 473-479 (2008).
13 Solmaz, R., Kardas, G., Culha, M., Yazici, B., Erbil, M., “Investigation of adsorption and inhibitive effect of 2-mercaptothiazoline on corrosion of mild steel in hydrochloric acid media”, Electrochimica Acta, 53 , 5941-5952 (2008).
14 Ramesh, S.V., Adhikari, A.V., “Quinolin-5-ylmethylene-3-{[8(trifluoromethyl) quinolin-4-yl]thio}propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution”, Corros. Sci., 50, 55-61 (2008).
15 Achary, G., Sachin, H.P., Naik, Y.A., Venkatesha, T.V., “The corrosion inhibition of mild steel by 3-formyl-8-hydroxy quinoline in hydrochloric acid medium”, Mater. Chem. Phys., 107, 44-50 (2008).
16 Ergun, U., Yüzer, D., Emregül, K.C., “The inhibitory effect of bis-2,6-(3,5-dimethylpyrazolyl) pyridine on the corrosion behaviour of mild steel in HCl solution”, Mater. Chem. Phys., 109, 492-499 (2008).
17 Li, Y., Zhao, P., Hou, B.R., “Berberine as a natural source inhibitor for mild steel in 1 M H₂SO₄”, Appl. Surf. Sci., 252 (5), 1245-1253 (2005).
18 Matamala ,G., Smeltzerand, W., Droguett, G., “Comparison of steel anticorrosive protection formulated with natural tannins extracted from acacia and from pine bark”, Corros. Sci., 42 (8), 1351-1362 (2000).
19 Lin, X.Z., Gong, M., Wu, J.P., “Study about use of abstracted oil from plant scrapas corrosion inhibitor for hydrochloric acid cleaning”, Corro. Sci. Prot. Tech., 18 (3), 222-224 (2006). (in Chinese)
20 Arenas, A., Bethencourt, M., Botana, F.J., Damborenea, de. J., Marcos, M., “Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts”, Corros. Sci., 43 (1), 157-170 (2001).
21 Aballe, A., Bethencourt, M., Botana, F.J., Marcos, M.J., “CeCl₃ and LaCl₃ binary solutions as environment-friendly corrosion inhibitors of AA5083 Al-Mg alloy in NaCl solutions”, Alloys. Comp., 323/324, 855-858 (2001). (in Chinese)
22 El-Sawy, S.M., Abu-Ayana, Y.M., Abdel-Mohdy, F.A., “Some chitin/chitosan derivatives for corrosion protection and waste water treatments”, Anticorros. Meth. Mat., 48 (4), 227-235 (2001). (in Chinese)
23 Feng, Y.F., Li, K.X., Xie, F., Sun, C.H., “HPLC determination of active metabolite of prulifloxacin:NM394 in human plasma with fluorescence detection”, Chin. J. Pharm. Ana., 26 (6), 755-757 (2006). (in Chinese)
24 Shen, J.Z., Li, J.S., Liang, B., Zhong, Q.F., Xiao, X.L., Liu, J.F., “Study on the reproductive teratogenic toxicity of sarafloxacin to wistar rats”, Acta. Veter. Zoo. Sinica, 32 (4), 375-378 (2001). (in Chinese)
25 Lebrini, M., Lagrenée, M., Vezin, H., Gengembre, L., Bentiss, F., “Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium”, Corros. Sci., 47 (2), 485-505 (2005).
26 Pang, X.H., Guo, W.J., Li, W.H., Xie, J.D., Hou, B.R., “Electrochemical, quantum chemical and SEM investigation of the inhibiting effect and mechanism of ciprofloxacin, norfloxacin and ofloxacin on the corrosion for mild steel in hydrochloric acid”, Science in China Series B:Chemistry, 51 (10), 928-936 (2008).
27 Khaled, K.F., “Experimental and theoretical study for corrosion inhibition of mild steel in hydrochloric acid solution by some new hydrazine carbodithioic acid derivatives”, Appl. Surf. Sci., 252 (12), 4120-4128 (2006).
28 Wang, D.X., Li, S.Y., Ying, Y., Wang, M.G., Xiao, H.M., Chen, Z.X., “Theoretical and experimental studies of structure and inhibition efficiency of imidazoline derivatives”, Corros. Sci., 41, 1911-1919 (1999).
29 Chebabe, D., Chikh, Z.A., Dermaj, A., Rhattas, K., Jazouli, T., Hajjaji, N., Mdari, F.E., Srhiri, A., “Synthesis of bolaamphiphile surfactants and their inhibitive effect on carbon steel corrosion in hydrochloric acid medium”, Corros. Sci., 46, 2701-2713 (2004).
30 Bentiss, F., Traisnel, M., Chaibi, N., Mernari, B., Vezin, H., Lagrenée, M., “2,5-Bis(n-methoxyphenyl)-1,3,4-oxadiazoles used as corrosion inhibitors in acidic media, correlation between inhibition efficiency and chemical structure”, Corros. Sci., 44, 2271-2289 (2002).
31 Tebbji, K., Hammouti, B., Oudda, H., Ramdani, A., Benkadour, M., “The inhibitive effect of bipyrazolic derivatives on the corrosion of steel in hydrochloric acid solution”, Appl. Surf. Sci., 252, 1378-1385 (2005).
32 Hosseini, M., Mertens, S.F.L., Ghorbani, M., Arshadi, M.R., “Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media”, Mater. Chem. Phys., 78 (3), 800-808 (2003).
33 Cruz, J., Martínez, R., Genesca, J., Garc, E., “Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media”, J. Electroanal. Chem., 566 (1), 111-121 (2004).
34 McCafferty, E., Hackerman, N., “Double layer capacitance of iron and corrosion iInhibition with polymethylene diamines”, J. Electrochem. Soc., 119 (2), 146-154 (1972).
35 Liu, S.H., Wang, D.H., Pan, C.H., X-ray Photoelectron Spectroscopy Analysis, Science Press, Beijing (1988). (in Chinese)
36 Olivares, O., Likhanova, N.V., Gómez, B., Navarrete, J., Llanos-Serrano, M.E., Arce, E., Hallen, J.M., “Electrochemical and XPS studies of decylamides of a-amino acids adsorption on carbon steel in acidic environment”, Appl. Surf. Sci., 252, 2894-2909 (2006).
37 Bentiss, F., Traisnel, M., Gengembre, L., Lagrenee, M., “Inhibition of acidic corrosion of mild steel by 3,5-diphenyl-4H-1,2,4-triazole”, Appl. Surf. Sci., 161, 194-202 (2000).
38 Bommersbach, P., Alemany-Dumont, C., Millet, J.P., Normand, B., “Formation and behaviour study of an environment-friendly corrosion inhibitor by electrochemical methods”, Electrochim Acta., 51, 1076-1084 (2005).
39 Pang, X.H., Hou, B.R., Li, W.H., Liu, F.Q., Yu, Z.G., “2,3,5-Triphenyl2H-tetrazolium chloride and 2,4,6-tri(2-pyridyl)-striazine on the corrosion of mild steel in HCl”, Chin. J. Chem. Eng., 15, 909-915 (2007).
40 Yang, K., Chu, G., Shao, L., Xiang, Y., Zhang, L., Chen, J.F., “Micromixing efficiency of viscous media in micro-channel reactor”, Chin. J. Chem. Eng., 17, 546-551 (2009).

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Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

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