SCI和EI收录∣中国化工学会会刊

›› 2010, Vol. 18 ›› Issue (6): 1008-1012.

• THERMODYNAMICS AND CHEMICAL ENGINEERING DATA • Previous Articles     Next Articles

Solubilities of 1-Methyl-3-(3-sulfopropyl)-imidazolium Hydrogen Sulfate in Selected Solvents

CAI Shuangfei, WANG Lisheng, YAN Guoqing, LI Yi   

  1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China
  • Received:2010-06-11 Revised:2010-10-23 Online:2010-12-28 Published:2010-12-28

Solubilities of 1-Methyl-3-(3-sulfopropyl)-imidazolium Hydrogen Sulfate in Selected Solvents

蔡双飞, 王利生, 闫国庆, 李毅   

  1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China
  • 通讯作者: WANG Lisheng, E-mail: lishengwang@bit.edu.cn

Abstract: Ionic liquid 1-methyl-3-(3-sulfopropyl)-imidazolium hydrogen sulfate([C3SO3HMIM][HSO4]) was synthesized and characterized by infrared spectroscopy(IR),nuclear magnetic resonance(1H and 13C NMR) and ultraviolet-visible(UV-Vis) spectra. Its thermal stability was also examined by thermogravimetric analysis(TGA) and a differential scanning calorimeter(DSC). The mole fraction solubilities of [C3SO3HMIM][HSO4]) in 12 selected solvents(n-pentane,n-hexane,n-heptane,benzene,toluene,ethylbenzene,acetone,2-butanone,3-methyl-2-butanone,tetrahydrofuran,ethyl acetate and dichloromethane) in the temperature range from 289.15 to 363.15 K were measured using a static analytical method and correlated with an empirical equation.

Key words: Brφnsted acidic ionic liquid, solubility, organic solvent, static analytical method

摘要: Ionic liquid 1-methyl-3-(3-sulfopropyl)-imidazolium hydrogen sulfate([C3SO3HMIM][HSO4]) was synthesized and characterized by infrared spectroscopy(IR),nuclear magnetic resonance(1H and 13C NMR) and ultraviolet-visible(UV-Vis) spectra. Its thermal stability was also examined by thermogravimetric analysis(TGA) and a differential scanning calorimeter(DSC). The mole fraction solubilities of [C3SO3HMIM][HSO4]) in 12 selected solvents(n-pentane,n-hexane,n-heptane,benzene,toluene,ethylbenzene,acetone,2-butanone,3-methyl-2-butanone,tetrahydrofuran,ethyl acetate and dichloromethane) in the temperature range from 289.15 to 363.15 K were measured using a static analytical method and correlated with an empirical equation.

关键词: Brφnsted acidic ionic liquid, solubility, organic solvent, static analytical method