Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride

›› 2011, Vol. 19 ›› Issue (2): 262-266.

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Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride

WANG Lihong¹, LI Deling¹, CHENG Lihua^2,3, ZHANG Lin^2,3, CHEN Huanlin^2,3

1. Department of Chemistry, Tangshan Normal College, Tangshan 063000, China;
2. Department of Chemical & Biological Engineering, Zhejiang University, Hangzhou 310027, China;
3. The Engineering Central of Membrane and Water Treatment, MOE, Hangzhou 310027, China

Received:2010-04-27 Revised:2010-11-18 Online:2011-04-28 Published:2011-04-28
Supported by:
Supported by the National Natural Science Foundation of China(21076176);the Research and Development Project of Tangshan(10140201C-3);the Research and Development Project of Hebei Province(07275113);the Research Fund of Tangshan Normal College

Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride

王丽红¹, 李德玲¹, 程丽华^2,3, 张林^2,3, 陈欢林^2,3

1. Department of Chemistry, Tangshan Normal College, Tangshan 063000, China;
2. Department of Chemical & Biological Engineering, Zhejiang University, Hangzhou 310027, China;
3. The Engineering Central of Membrane and Water Treatment, MOE, Hangzhou 310027, China

通讯作者: ZHANG Lin,E-mail:linzhang@zju.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(21076176);the Research and Development Project of Tangshan(10140201C-3);the Research and Development Project of Hebei Province(07275113);the Research Fund of Tangshan Normal College

Abstract

Abstract: A new aromatic diamine,3,5-diaminobenzoylpiperazine (3,5-DABP),was synthesized from 3,5-diaminobenzoic acid and 1-formyl piperazine.The structure of 3,5-DABP was identified by FT-IR spectra and 1H NMR spectra.With 3,5-DABP as aqueous monomer and trimesoyl chloride (TMC) as organic monomer,thin film composite (TFC) nanofiltration membranes were prepared by interfacial polymerization technology.The salt rejection order of these TFC membranes is Na₂SO₄>MgSO₄>MgCl₂>NaCl.This sequence indicates that the membranes are negatively charged.

Key words: thin film composite membrane, 3,5-diaminobenzoylpiperazine, trimesoyl chloride, interfacial polymerization

摘要： A new aromatic diamine,3,5-diaminobenzoylpiperazine (3,5-DABP),was synthesized from 3,5-diaminobenzoic acid and 1-formyl piperazine.The structure of 3,5-DABP was identified by FT-IR spectra and 1H NMR spectra.With 3,5-DABP as aqueous monomer and trimesoyl chloride (TMC) as organic monomer,thin film composite (TFC) nanofiltration membranes were prepared by interfacial polymerization technology.The salt rejection order of these TFC membranes is Na₂SO₄>MgSO₄>MgCl₂>NaCl.This sequence indicates that the membranes are negatively charged.

关键词: thin film composite membrane, 3,5-diaminobenzoylpiperazine, trimesoyl chloride, interfacial polymerization

WANG Lihong, LI Deling, CHENG Lihua, ZHANG Lin, CHEN Huanlin. Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride[J]. , 2011, 19(2): 262-266.

王丽红, 李德玲, 程丽华, 张林, 陈欢林. Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride[J]. , 2011, 19(2): 262-266.

References

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Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride

Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride

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