SCI和EI收录∣中国化工学会会刊

›› 2011, Vol. 19 ›› Issue (4): 586-589.

• SEPARATION SCIENCE AND ENGINEERING • Previous Articles     Next Articles

Investigation of Mg2+/Li+Separation by Nanofiltration

YANG Gang, SHI Hong, LIU Wenqiang, XING Weihong, XU Nanping   

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
  • Received:2010-12-09 Revised:2011-04-15 Online:2011-08-28 Published:2011-08-28
  • Supported by:
    Supported by the National Natural Science Foundation of China(20576052)and the Joint Innovation Fund of Jiangsu Province(BY2009107).

Investigation of Mg2+/Li+Separation by Nanofiltration

杨刚, 史宏, 刘文强, 邢卫红, 徐南平   

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
  • 通讯作者: YANG Gang,E-mail:yanggang@njut.edu.cn
  • 基金资助:
    Supported by the National Natural Science Foundation of China(20576052)and the Joint Innovation Fund of Jiangsu Province(BY2009107).

Abstract: The Mg2+/Li+/Cl- solutions were filtrated with a commercially available DK nanofiltration membrane to investigate the possibility to enrich the lithium component.The investigation was significant as such an approach might be a competing substitute for the present lithium purification industry and the environmental protection purpose.The Donnan steric pore model(DSPM) was implemented for the prediction.The separation of Mg2+/Li+ was mainly affected by the working pressure(or the permeation flux) and a limiting separation factor was found around 0.31.The effective membrane charge density was evaluated and its dependence on the permeation flux as well as the ion pattern was discussed.For predicting an actual separation of electrolytes, the experimental investigation seems necessary for the reliability and efficiency.

Key words: nanofiltration, lithium recovery, DSPM model, separation factor

摘要: The Mg2+/Li+/Cl- solutions were filtrated with a commercially available DK nanofiltration membrane to investigate the possibility to enrich the lithium component.The investigation was significant as such an approach might be a competing substitute for the present lithium purification industry and the environmental protection purpose.The Donnan steric pore model(DSPM) was implemented for the prediction.The separation of Mg2+/Li+ was mainly affected by the working pressure(or the permeation flux) and a limiting separation factor was found around 0.31.The effective membrane charge density was evaluated and its dependence on the permeation flux as well as the ion pattern was discussed.For predicting an actual separation of electrolytes, the experimental investigation seems necessary for the reliability and efficiency.

关键词: nanofiltration, lithium recovery, DSPM model, separation factor