Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB

doi:10.1016/S1004-9541(13)60471-1

Chin.J.Chem.Eng. ›› 2013, Vol. 21 ›› Issue (4): 447-452.DOI: 10.1016/S1004-9541(13)60471-1

• MATERIALS AND PRODUCT ENGINEERING • Previous Articles Next Articles

Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB

ZHAO Linxiu^1,2, ZHANG Xin¹, LÜ Xingxin¹, YUAN Siguo¹, WU Xianli ¹

1 School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;
2 School of Chemical and Environment Engineering, North University of China, Taiyuan 030051, China

Received:2012-06-02 Revised:2012-11-27 Online:2013-04-26 Published:2013-04-28
Supported by:
Supported by the National Natural Science Foundation of China (21004055) and the Doctoral Discipline Foundation of Education Ministry (20104101110005).

Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB

赵林秀^1,2, 张鑫¹, 吕邢鑫¹, 原思国¹, 武现丽¹

1 School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;
2 School of Chemical and Environment Engineering, North University of China, Taiyuan 030051, China

通讯作者: YUAN Siguo
基金资助:
Supported by the National Natural Science Foundation of China (21004055) and the Doctoral Discipline Foundation of Education Ministry (20104101110005).

Abstract

Abstract: The suspension polymerization with two organic phases was adopted to prepare spherical hypercrosslinked resin by self-polycondensation of 4,4′-bis-(chloromethyl)-1,1′-biphenyl (CMB). The chemical structure, morphology and pore characteristics of the novel spherical resin were characterized with Fourier transform infrared spectroscopy (FTIR), micrograph and Brunauer-Emmett-Teller (BET). It is found that the suspension system and stirring speed impose a great influence upon the regularity and size distribution of hypercrosslinked beads. To prepare CMB resin beads with diameter of about 300 μm, the optimal condition is as follows: stirring speed 300 r·min^-1, and the volume ratio of the two organic phases (nitrobenzene/dimethyl silicon oil) 1:5. After the self-polycondensation and succedent post-crosslinking of CMB monomer, the spherical adsorbent presents high special surface area (1190 m²·g^-1) and abundant pore volume (0.714 cm³·g^-1), and could be potentially applied in the adsorption of various organic molecules and synthesis of porous ion exchanger.

Key words: two organic phase suspension polymerization, hypercrosslinked resin, bis chloromethyl monomer

摘要： The suspension polymerization with two organic phases was adopted to prepare spherical hypercrosslinked resin by self-polycondensation of 4,4′-bis-(chloromethyl)-1,1′-biphenyl (CMB). The chemical structure, morphology and pore characteristics of the novel spherical resin were characterized with Fourier transform infrared spectroscopy (FTIR), micrograph and Brunauer-Emmett-Teller (BET). It is found that the suspension system and stirring speed impose a great influence upon the regularity and size distribution of hypercrosslinked beads. To prepare CMB resin beads with diameter of about 300 μm, the optimal condition is as follows: stirring speed 300 r·min^-1, and the volume ratio of the two organic phases (nitrobenzene/dimethyl silicon oil) 1:5. After the self-polycondensation and succedent post-crosslinking of CMB monomer, the spherical adsorbent presents high special surface area (1190 m²·g^-1) and abundant pore volume (0.714 cm³·g^-1), and could be potentially applied in the adsorption of various organic molecules and synthesis of porous ion exchanger.

关键词: two organic phase suspension polymerization, hypercrosslinked resin, bis chloromethyl monomer

ZHAO Linxiu, ZHANG Xin, LÜ Xingxin, YUAN Siguo, WU Xianli . Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB[J]. Chin.J.Chem.Eng., 2013, 21(4): 447-452.

赵林秀, 张鑫, 吕邢鑫, 原思国, 武现丽. Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB[J]. Chinese Journal of Chemical Engineering, 2013, 21(4): 447-452.

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Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB

Two Organic Phase Suspension Polymerization for Novel Hypercrosslinked Resin Bead by Polycondensation of CMB

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