Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

doi:10.1016/S1004-9541(13)60640-0

Abstract

Abstract: It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

Key words: ionic liquid, activity coefficients at infinite dilution, organic reactions

摘要： It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

关键词: ionic liquid, activity coefficients at infinite dilution, organic reactions

MA Zheng, DONG Xiaoxia, Hu Yufeng, ZHANG Bosong, XU Changying, LIU Yansheng. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. Chin.J.Chem.Eng., 2013, 21(12): 1370-1375.

马征, 董晓霞, 胡玉峰, 张柏松, 徐长英, 刘艳升. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. Chinese Journal of Chemical Engineering, 2013, 21(12): 1370-1375.

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