Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents

doi:10.1016/S1004-9541(14)60061-6

Abstract

Abstract: The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid + acetic acid (1:1), formic acid + propionic acid (1:1), formic acid + n-butyric acid (1:1), and formic acid + isobutyric acid (1:1) increases with temperature. The Apelblat equation, the λh model, and the ideal solution equation correlate the solubility data well.

Key words: solid-liquid equilibrium, solubility, D-xylose

摘要： The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid + acetic acid (1:1), formic acid + propionic acid (1:1), formic acid + n-butyric acid (1:1), and formic acid + isobutyric acid (1:1) increases with temperature. The Apelblat equation, the λh model, and the ideal solution equation correlate the solubility data well.

关键词: solid-liquid equilibrium, solubility, D-xylose

LI Tao, CHEN Feixiong, JIANG Zhenxi, REN Baozeng. Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents[J]. Chin.J.Chem.Eng., 2014, 22(4): 429-434.

李涛, 陈飞雄, 江振西, 任保增. Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents[J]. Chinese Journal of Chemical Engineering, 2014, 22(4): 429-434.

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