Interfacial Tension of CO2 and Organic Liquid under High Pressure and Temperature

doi:10.1016/j.cjche.2014.09.042

›› 2014, Vol. 22 ›› Issue (11/12): 1302-1306.DOI: 10.1016/j.cjche.2014.09.042

• CHEMICAL ENGINEERING THERMODYNAMICS • Previous Articles Next Articles

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

Zihao Yang^1,2, Mingyuan Li^1,3, Bo Peng^1,2, Meiqin Lin^1,2, Zhaoxia Dong^1,2, Yong Ling ¹

1 Enhanced Oil Recovery Research Institute, China University of Petroleum, Beijing 102249, China;
2 Key Laboratory of Enhanced Oil Recovery, China National Petroleum Corporation (CNPC), Beijing 102249, China;
3 State Key Laboratory of Heavy Oil Processing, Beijing 102249, China

Received:2013-01-28 Revised:2013-07-08 Online:2014-12-24 Published:2014-12-28
Supported by:
Supported by the National Basic Research Program of China (2011CB707305), the National Key Technologies R&D Program (2012BAC24B00), National Nature Science Foundation of China(51304222), the CNPC Innovation Foundation (2013D-5006-0204) and the Science Foundation of China University of Petroleum (YJRC-2013-20).

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

Zihao Yang^1,2, Mingyuan Li^1,3, Bo Peng^1,2, Meiqin Lin^1,2, Zhaoxia Dong^1,2, Yong Ling ¹

1 Enhanced Oil Recovery Research Institute, China University of Petroleum, Beijing 102249, China;
2 Key Laboratory of Enhanced Oil Recovery, China National Petroleum Corporation (CNPC), Beijing 102249, China;
3 State Key Laboratory of Heavy Oil Processing, Beijing 102249, China

通讯作者: Zihao Yang
基金资助:
Supported by the National Basic Research Program of China (2011CB707305), the National Key Technologies R&D Program (2012BAC24B00), National Nature Science Foundation of China(51304222), the CNPC Innovation Foundation (2013D-5006-0204) and the Science Foundation of China University of Petroleum (YJRC-2013-20).

Abstract

Abstract: In order to investigate the effect of organic liquidmolecular structure and the intermolecular force operatingwith CO₂ molecules and organic liquid molecules on interfacial tension (IFT) between CO₂ and organic liquid at the first contact, the interfacial tension between CO₂ and hexane, octane, ethanol and cyclohexane at different temperatures and pressures ismeasured by using the pendant drop method and the axisymmetric drop shape analysis (ADSA). The results show that the interfacial tension between CO₂ and organic liquids is affected by the polarity and the structure of the organic liquid molecule obviously. The intermolecular force operating within CO₂ molecules or organic liquid, and that between CO₂ and organic liquids molecules play a dominate role on the interfacial tension between CO₂ and the organic liquids.

Key words: Carbon dioxide, Organic liquids, Interfacial tension, ADSA

摘要： In order to investigate the effect of organic liquidmolecular structure and the intermolecular force operatingwith CO₂ molecules and organic liquid molecules on interfacial tension (IFT) between CO₂ and organic liquid at the first contact, the interfacial tension between CO₂ and hexane, octane, ethanol and cyclohexane at different temperatures and pressures ismeasured by using the pendant drop method and the axisymmetric drop shape analysis (ADSA). The results show that the interfacial tension between CO₂ and organic liquids is affected by the polarity and the structure of the organic liquid molecule obviously. The intermolecular force operating within CO₂ molecules or organic liquid, and that between CO₂ and organic liquids molecules play a dominate role on the interfacial tension between CO₂ and the organic liquids.

关键词: Carbon dioxide, Organic liquids, Interfacial tension, ADSA

Zihao Yang, Mingyuan Li, Bo Peng, Meiqin Lin, Zhaoxia Dong, Yong Ling . Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature[J]. , 2014, 22(11/12): 1302-1306.

References

[1] C.A. T Eckert, Debenedetti P.G., Supercritical fluid as solvents for chemical and materials processing, Knutson, B. L. 383 (1996) 313-318.
[2] M.A. McHugh, V.J. Krukonis, in: M.A. Stoneham (Ed.), “Supercritical Fluids Extraction”: Principles and Practice, Butterworth, Heinman, 1993.
[3] Yu. Jinglin,Wang Shujun, Tian Yiling, Experimental determination and calculation of thermodynamic properties of CO₂ + octane to high temperatures and high pressures, Fluid Phase Equilib. 246 (6-14) (2006).
[4] P. Chattopadhyay, R.B. Gupta, Production of antibiotic nanoparticles using supercritical CO₂ as antisolvent with enhanced mass transfer, Ind. Eng. Chem. Res. 40 (2001) 3530-3539.
[5] C.G. Kalogiannis, P. Eleni, C.G. Panayiotou, Production of amoxicillin microparticles by supercritical antisolvent precipitation, Ind. Eng. Chem. Res. 44 (2005) 9339-9346.
[6] I. Kikic,M. Lora, A. Bertucco, Thermodynamic analysis of three phase equilibria in binary and ternary systems for applications in rapid expansion of a supercritical solution (RESS), particles from gas saturated solutions (PGSS) and supercritical antisolvent crystallization (SAS), Ind. Eng. Chem. Res. 36 (1997) 5507-5515.
[7] D.W. Matson, J.L. Fulton, R.C. Petersen, R.D. Smith, Rapid expansion of supercritical fluid solutions: solute formation of powders, thin film and fibers, Ind. Eng. Chem. Res. 26 (1987) 2298-2306.
[8] D. Fu, Z. Yang, Y.Z. Wei, Progress in phase equilibria and interfacial tensions for supercritical carbon dioxide and alkanes binary mixtures, J. N. China Electr. Power Univ. 37 (4) (2010) 84-89.
[9] J.C. Xu, S.Wang,W. Yu, Q.Q. Xu,W.B.Wang, J.Z. Yin, Molecular dynamics simulation for the binary mixtures of high pressure carbon dioxide and ionic liquids, Chin. J. Chem. Eng. 22 (2) (2014) 53-163.
[10] D. Mohammad-Aghaie, M.M. Papari, A.R. Ebrahimi, Determination of transport properties of dilute binary mixtures containing carbon dioxide through isotropic pair potential energies, Chin. J. Chem. Eng. 22 (3) (2014) 274-286.
[11] S.N. Joung, C.W. Yoo, H.Y. Shin, S.Y. Kim, K.P. Yoo, C.S. Lee,W.S. Huh, Measurements and correlation of high-pressure VLE of binary CO₂-alcohol systems (methanol, ethanol, 2-methoxyethanol and 2-ethoxyethanol), Fluid Phase Equilib. 185 (1-2) (2001) 219-230.
[12] Z. Yang, M. Li, B. Peng, M. Lin, Z. Dong, Dispersion property of CO₂ in oil, Part 1: Volume sexpansion of CO₂ + alkane at near critical and supercritical condition of CO₂, J. Chem. Eng. Data 57 (2012) 882-889.
[13] Z. Yang, M. Li, B. Peng, M. Lin, Z. Dong, Dispersion property of CO₂ in oil Part 2: Volume expansion of CO₂ + organic liquid at near critical and supercritical condition of CO₂, J. Chem. Eng. Data 57 (2012) 1305-1311.
[14] A.D. Leu, D.B. Robinson, Equilibrium phase properties of selected carbon dioxide binary systems: n-Pentane-carbon dioxide and isopentane-carbon dioxide, J. Chem. Eng. Data 32 (4) (1987) 447-450.
[15] J.J.C. Hsu, N. Nagarajan, R.L. Robinson, Equilibrium phase compositions, phase densities, and interfacial tensions for carbon dioxide + hydrocarbon systems. 1. Carbon dioxide + n-butane, J. Chem. Eng. Data 30 (4) (1985) 485-491.
[16] N. Nagarajan, R.L. Robinson, Equilibrium phase compositions, phase densities, and interfacial tensions for carbon dioxide + hydrocarbon systems. 2. Carbon dioxide + n-decane, J. Chem. Eng. Data 31 (2) (1986) 168-171.
[17] N. Nagarajan, R.L. Robinson, Equilibrium phase compositions, phase densities, and interfacial tensions for carbon dioxide + hydrocarbon systems. 3. CO₂ + cyclohexane. 4. CO₂ + benzene, J. Chem. Eng. Data 32 (3) (1987) 369-371.
[18] K.A.M. Gasem, K.B. Dickson, P.B. Dulcamara, N. Nagarajan, R.L. Robinson, Equilibriumphase compositions, phase densities, and interfacial tensions for carbon dioxide + hydrocarbon systems. 5. Carbon dioxide + n-tetradecane, J. Chem. Eng. Data 34 (2) (1989) 191-195.
[19] N. Nagarajan, K.A.M. Gasem, R.L. Robinson, Equilibrium phase compositions, phase densities, and interfacial tensions for carbon dioxide + hydrocarbon systems. 6. Carbon dioxide + n-butane + n-decane, J. Chem. Eng. Data 35 (3) (1990) 228-231.
[20] Y. Rotenberg, L. Boruvka, A.W. Neumann, Determination of surface tension and contact angle from the shapes of axisymmetric fluid interfaces, J. Colloid Interface Sci. 93 (1) (1983) 169-183.
[21] P. Cheng, D. Li, L. Boruvka, Y. Rotenberg, A.W. Neumann, Automation of axisymmetric drop shape analysis for measurements of interfacial tensions and contact angles, Colloids Surf. 43 (2) (1990) 151-167.
[22] D.N. Rao, A new technique of vanishing interfacial tension formiscibility determination, Fluid Phase Equilib. 139 (1997) 311-324.
[23] D.N. Rao, J.I. Lee, Determination of gas-oil miscibility conditions by interfacial tension measurements, J. Colloid Interface Sci. 262 (2) (2003) 474-482.
[24] D.N. Rao, Fluid-fluid and solid-fluid interfacial interactions in petroleumreservoirs, J. Pet. Sci. Technol. 19 (1) (2001) 157-188.
[25] D.Y. Yang, Y.A. Gu, “Visualization of interfacial interactions of crude oil-CO₂ systems under reservoir conditions, presented at symposium on improved oil recovery”, 17-21 April, Tulsa, Oklahoma SPE 89366-MS, 2004.
[26] Z. Yang, Dispersion Property of Supercritical CO₂ in Organic Liquid(Ph.D. Thesis) China University of Petroleum (Beijing), China, 2012.
[27] P.C. Hiemenz, R. Rajagopalan, Principles of Colloid and Surface Chemistry, Marcel Dekker, Inc, New York, 1997.

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Chaojie Li, Xianxin Fang, Meiling Sun, Jihai Duan, Weiwen Wang. Study on two-phase cloud dispersion from liquefied CO₂ release [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 37-45.
[2]	Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 105-117.
[3]	Tatyana P. Adamova, Sergey S. Skiba, Andrey Yu. Manakov, Sergey Y. Misyura. Growth rate of CO₂ hydrate film on water–oil and water–gaseous CO₂ interface [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 266-272.
[4]	Bowen Jiang, Jia Liu, Guoqiang Yang, Zhibing Zhang. Efficient conversion of CO₂ into cyclic carbonates under atmospheric by halogen and metal-free poly(ionic liquid)s [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 202-211.
[5]	Mingdong Sun, Dongxin Pan, Tingting Ye, Jing Gu, Yu Zhou, Jun Wang. Ionic porous polyamide derived N-doped carbon towards highly selective electroreduction of CO₂ [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 212-221.
[6]	Mengge Shang, Jing Zhang, Jinqiang Sun, Shimo Yu, Feng Hua, Xiaoxu Xuan, Xun Sun, Serguei Filatov, Xibin Yi. Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 36-43.
[7]	Xianglin Liu, Minjie Xu, Chenxi Cao, Zixu Yang, Jing Xu. Effects of zinc on χ-Fe₅C₂ for carbon dioxide hydrogenation to olefins: Insights from experimental and density function theory calculations [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 206-214.
[8]	Zhongyao Zhang, Ming Gao, Xiaopeng Chen, Xiaojie Wei, Jiezhen Liang, Chenghong Wu, Linlin Wang. The Joule–Thomson effect of (CO₂ + H₂) binary system relevant to gas switching reforming with carbon capture and storage (CCS) [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 215-231.
[9]	Hao Zhang, Daiwei Liu, Jiangbo Wen, Guangyu Sun, Chuanxian Li, Xinya Chen, Huihui Zhang, Ze Duan. Co-adsorption behaviors of asphaltenes and different flow improvers and their impacts on the interfacial viscoelasticity [J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 149-157.
[10]	Vladimir S. Derevschikov, Janna V. Veselovskaya, Anton S. Shalygin, Dmitry A. Yatsenko, Andrey Z. Sheshkovas, Oleg N. Martyanov. Operating limits and features of direct air capture on K₂CO₃/ZrO₂ composite sorbent [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 11-20.
[11]	Jipeng Dong, Fei Wang, Guanghui Chen, Shougui Wang, Cailin Ji, Fei Gao. Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 207-213.
[12]	Youwei Yang, Jingyu Zhang, Yueqi Gao, Busha Assaba Fayisa, Antai Li, Shouying Huang, Jing Lv, Yue Wang, Xinbin Ma. Highly dispersed nickel boosts catalysis by Cu/SiO₂ in the hydrogenation of CO₂-derived ethylene carbonate to methanol and ethylene glycol [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 77-85.
[13]	Zhen Lu, Jie He, Bogeng Guo, Yulai Zhao, Jingyu Cai, Longqiang Xiao, Linxi Hou. Efficient homogenous catalysis of CO₂ to generate cyclic carbonates by heterogenous and recyclable polypyrazoles [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 110-115.
[14]	Xin Li, Song Hong, Leiduan Hao, Zhenyu Sun. Cadmium-based metal-organic frameworks for high-performance electrochemical CO₂ reduction to CO over wide potential range [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 143-151.
[15]	Yichao Wu, Zhiwei Xie, Xiaofeng Gao, Xian Zhou, Yangzhi Xu, Shurui Fan, Siyu Yao, Xiaonian Li, Lili Lin. The highly selective catalytic hydrogenation of CO₂ to CO over transition metal nitrides [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 248-254.