Improving the biodecolorization of reactive blue 13 by sodium anthraquinone-2-sulfonate immobilized on modified polyvinyl alcohol beads

doi:10.1016/j.cjche.2015.04.007

Chin.J.Chem.Eng. ›› 2015, Vol. 23 ›› Issue (7): 1194-1199.DOI: 10.1016/j.cjche.2015.04.007

• ENERGY, RESOURCES AND ENVIRONMENTAL TECHNOLOGY • Previous Articles Next Articles

Improving the biodecolorization of reactive blue 13 by sodium anthraquinone-2-sulfonate immobilized on modified polyvinyl alcohol beads

Yongxing Qian, Bin Yang, Zhongjian Li, Lecheng Lei, Xingwang Zhang

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Received:2014-08-27 Revised:2015-01-23 Online:2015-08-21 Published:2015-07-28
Contact: Xingwang Zhang
Supported by:
Supported by the National Natural Science Foundation of China (21276231, 21476201, U1462201, and 21376216).

Improving the biodecolorization of reactive blue 13 by sodium anthraquinone-2-sulfonate immobilized on modified polyvinyl alcohol beads

Yongxing Qian, Bin Yang, Zhongjian Li, Lecheng Lei, Xingwang Zhang

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

通讯作者: Xingwang Zhang
基金资助:
Supported by the National Natural Science Foundation of China (21276231, 21476201, U1462201, and 21376216).

Abstract

Abstract: In order to enhance the biodecolorization rate and avoid the wash-out problems of redox mediators in continuous systems such as a fluidized bed reactor, polyvinyl alcohol (PVA) beads modified with Ncontaining function groups were investigated and employed as a new sodium anthraquinone-2-sulfonate (AQS) carrier material. Elementary and XPS analyses confirmthe existence of AQS on modified PVA bead. The modified PVA beads suit with immobilizing AQS better in adsorption capability and stability. AQS supported on modified PVA beads shows high catalytic activity for biodecolorization of reactive blue 13 in a long process (> 10 runs).

Key words: Redox mediator, Biodecolorization, Functional bio-carrier

摘要： In order to enhance the biodecolorization rate and avoid the wash-out problems of redox mediators in continuous systems such as a fluidized bed reactor, polyvinyl alcohol (PVA) beads modified with Ncontaining function groups were investigated and employed as a new sodium anthraquinone-2-sulfonate (AQS) carrier material. Elementary and XPS analyses confirmthe existence of AQS on modified PVA bead. The modified PVA beads suit with immobilizing AQS better in adsorption capability and stability. AQS supported on modified PVA beads shows high catalytic activity for biodecolorization of reactive blue 13 in a long process (> 10 runs).

关键词: Redox mediator, Biodecolorization, Functional bio-carrier

Yongxing Qian, Bin Yang, Zhongjian Li, Lecheng Lei, Xingwang Zhang. Improving the biodecolorization of reactive blue 13 by sodium anthraquinone-2-sulfonate immobilized on modified polyvinyl alcohol beads[J]. Chin.J.Chem.Eng., 2015, 23(7): 1194-1199.

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Improving the biodecolorization of reactive blue 13 by sodium anthraquinone-2-sulfonate immobilized on modified polyvinyl alcohol beads

Improving the biodecolorization of reactive blue 13 by sodium anthraquinone-2-sulfonate immobilized on modified polyvinyl alcohol beads

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