Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation

doi:10.1016/j.cjche.2015.07.008

Chin.J.Chem.Eng. ›› 2016, Vol. 24 ›› Issue (1): 175-179.DOI: 10.1016/j.cjche.2015.07.008

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Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation

Wei Ma, Mei Meng, Shumin Yan, Shufen Zhang

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China

Received:2014-10-14 Revised:2015-05-20 Online:2016-02-23 Published:2016-01-28
Contact: Wei Ma
Supported by:
Supported by the National Natural Science Foundation of China (21376042, 21421005), the National Key Technology R&D Program (2013BAF08B06) and Innovative Research Team of Ministry of Education of the People's Republic of China (IRT-13R06) and Dalian University of Technology (DUT2013TB07).

Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation

Wei Ma, Mei Meng, Shumin Yan, Shufen Zhang

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China

通讯作者: Wei Ma
基金资助:
Supported by the National Natural Science Foundation of China (21376042, 21421005), the National Key Technology R&D Program (2013BAF08B06) and Innovative Research Team of Ministry of Education of the People's Republic of China (IRT-13R06) and Dalian University of Technology (DUT2013TB07).

Abstract

Abstract: Novel cationic cotton fabricswere prepared by an efficient and simple one-step pad-dry-bake pretreatment processwith betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection (FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction (XRD), tensile strength and whiteness and yellowness index, were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyeswere tested, and the results presented that dye fixation on the cationic fabrics in the absence of saltwas improved with satisfactory light fastness property and applicable wash and rub fastnesses.

Key words: Salt-free dyeing, Betaine, Cationic cotton, Reactive dyes

摘要： Novel cationic cotton fabricswere prepared by an efficient and simple one-step pad-dry-bake pretreatment processwith betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection (FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction (XRD), tensile strength and whiteness and yellowness index, were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyeswere tested, and the results presented that dye fixation on the cationic fabrics in the absence of saltwas improved with satisfactory light fastness property and applicable wash and rub fastnesses.

关键词: Salt-free dyeing, Betaine, Cationic cotton, Reactive dyes

Wei Ma, Mei Meng, Shumin Yan, Shufen Zhang. Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation[J]. Chin.J.Chem.Eng., 2016, 24(1): 175-179.

Wei Ma, Mei Meng, Shumin Yan, Shufen Zhang. Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation[J]. Chinese Journal of Chemical Engineering, 2016, 24(1): 175-179.

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Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation

Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation

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