Abstract: As a potential solution to the crises of energy and resources, forward osmosis (FO) has been limited by the development of draw agents. An ideal draw agent should be able to generate high osmotic pressure and can be easily recovered. In this study, a thermo-sensitive polyelectrolyte of poly(N-isopropylacrylamide-co-acrylic acid) (PNA) is developed as an efficient drawagent, and two easy and simple methods are proposed to effectively recover the polyelectrolytes. After adjusting the pH value of polyelectrolyte solutions to around 6.0, the polyelectrolyte can generate relatively high osmotic pressure, and induce average water fluxes of 2.09 and 2.95 L·m^-2·h^-1 during 12 h FO processes when the polyelectrolyte concentrations are 0.20 and 0.38 g·ml^-1 respectively. After acidifying and heating to 70 ℃, the PNA-10 polyelectrolyte can aggregate together because of hydrophobic association and separate from water, so it can be easily recovered by either simple centrifugation or gravitational sedimentation. The recovery ratios of PNA-10 polyelectrolyte in both methods are as high as 89%, and the recovered polyelectrolytes can be reused with almost the same FO performance as fresh ones. The results in this study provide valuable guidance for designing efficient and easily recoverable draw agents for FO processes.

Key words: Forward osmosis, Draw agent, Thermo-sensitive polyelectrolyte, Recovery method, Poly(N-isopropylacrylamide-co-acrylic acid)

摘要： As a potential solution to the crises of energy and resources, forward osmosis (FO) has been limited by the development of draw agents. An ideal draw agent should be able to generate high osmotic pressure and can be easily recovered. In this study, a thermo-sensitive polyelectrolyte of poly(N-isopropylacrylamide-co-acrylic acid) (PNA) is developed as an efficient drawagent, and two easy and simple methods are proposed to effectively recover the polyelectrolytes. After adjusting the pH value of polyelectrolyte solutions to around 6.0, the polyelectrolyte can generate relatively high osmotic pressure, and induce average water fluxes of 2.09 and 2.95 L·m^-2·h^-1 during 12 h FO processes when the polyelectrolyte concentrations are 0.20 and 0.38 g·ml^-1 respectively. After acidifying and heating to 70 ℃, the PNA-10 polyelectrolyte can aggregate together because of hydrophobic association and separate from water, so it can be easily recovered by either simple centrifugation or gravitational sedimentation. The recovery ratios of PNA-10 polyelectrolyte in both methods are as high as 89%, and the recovered polyelectrolytes can be reused with almost the same FO performance as fresh ones. The results in this study provide valuable guidance for designing efficient and easily recoverable draw agents for FO processes.

关键词: Forward osmosis, Draw agent, Thermo-sensitive polyelectrolyte, Recovery method, Poly(N-isopropylacrylamide-co-acrylic acid)