Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling

doi:10.1016/j.cjche.2016.05.035

›› 2017, Vol. 25 ›› Issue (1): 37-44.DOI: 10.1016/j.cjche.2016.05.035

• Separation Science and Engineering • Previous Articles Next Articles

Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling

Lucie Bartoňová^1,2,3, Lucie Ruppenthalová^1,4, Michal Ritz^1,3

1 VŠB-Technical University of Ostrava, Faculty of Metallurgy and Material Engineering, Department of Chemistry, Tř. 17. listopadu 15, 708 33 Ostrava, Poruba, Czech Republic;
2 VŠB-Technical University of Ostrava, Sustainable Development of Centre ENET, Tř. 17. listopadu 15, 708 33 Ostrava, Poruba, Czech Republic;
3 VŠB-Technical University of Ostrava, Regional Materials Science and Technology Centre, Tř. 17. listopadu 15, 708 33 Ostrava, Poruba, Czech Republic;
4 Institute of Geonics of the CAS, Studentská 1768, 708 00 Ostrava, Poruba, Czech Republic

Received:2016-03-24 Revised:2016-05-26 Online:2017-02-15 Published:2017-01-28
Supported by:
Supported by the project No. LO1404 (Sustainable Development of Center ENET-Energy Units for the Utilization of Non-Traditional Energy Sources), project No. LO 1203 (Regional Materials Science and Technology Centre-Feasibility Program) and the project No. LO1406 (Institute of Clean Technologies for Mining and Utilization of Raw Materials for Energy Use-Sustainability Program, supported by the National Programme for Sustainability I 2013-2020).

Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling

Lucie Bartoňová^1,2,3, Lucie Ruppenthalová^1,4, Michal Ritz^1,3

1 VŠB-Technical University of Ostrava, Faculty of Metallurgy and Material Engineering, Department of Chemistry, Tř. 17. listopadu 15, 708 33 Ostrava, Poruba, Czech Republic;
2 VŠB-Technical University of Ostrava, Sustainable Development of Centre ENET, Tř. 17. listopadu 15, 708 33 Ostrava, Poruba, Czech Republic;
3 VŠB-Technical University of Ostrava, Regional Materials Science and Technology Centre, Tř. 17. listopadu 15, 708 33 Ostrava, Poruba, Czech Republic;
4 Institute of Geonics of the CAS, Studentská 1768, 708 00 Ostrava, Poruba, Czech Republic

通讯作者: Lucie Bartoňová,E-mail address:lucie.bartonova@vsb.cz
基金资助:
Supported by the project No. LO1404 (Sustainable Development of Center ENET-Energy Units for the Utilization of Non-Traditional Energy Sources), project No. LO 1203 (Regional Materials Science and Technology Centre-Feasibility Program) and the project No. LO1406 (Institute of Clean Technologies for Mining and Utilization of Raw Materials for Energy Use-Sustainability Program, supported by the National Programme for Sustainability I 2013-2020).

Abstract

Abstract: The study deals with adsorption of Naphthol Green B on two unburned carbons and the parent coal, from which the UCs have been created in a fluidised-bed power station. Particular attention has been paid to the adsorption equilibrium modelling:experimental data has been analysed using 2-parameter (Langmuir, Freundlich) and 3-parameter (Redlich-Peterson) isotherms-both linear and non-linear regressions have been used for the estimation of the isotherm parameters. In the case of both UCs, the Langmuir isotherm model provides the worst fit, whereas 2-parameter Freundlich and 3-parameter Redlich-Peterson models are both good, from which 3-parameter Redlich-Peterson isotherm provides slightly better results (despite the penalty used for the higher number of parameters). In the case of both UCs, the linear regression of Freundlich and Redlich-Peterson models provides good results (comparable with non-linear regressions). Unlike both UCs, the best fit of the experimental data from the adsorption on the coal has been achieved by the Langmuir isotherm model. The results based on the Freundlich or Redlich-Peterson model were (in this case) somewhat worse.

Key words: Adsorption, Unburned carbon, Naphthol Green B, Isotherms, Non-linear modelling, Redlich-Peterson model

摘要： The study deals with adsorption of Naphthol Green B on two unburned carbons and the parent coal, from which the UCs have been created in a fluidised-bed power station. Particular attention has been paid to the adsorption equilibrium modelling:experimental data has been analysed using 2-parameter (Langmuir, Freundlich) and 3-parameter (Redlich-Peterson) isotherms-both linear and non-linear regressions have been used for the estimation of the isotherm parameters. In the case of both UCs, the Langmuir isotherm model provides the worst fit, whereas 2-parameter Freundlich and 3-parameter Redlich-Peterson models are both good, from which 3-parameter Redlich-Peterson isotherm provides slightly better results (despite the penalty used for the higher number of parameters). In the case of both UCs, the linear regression of Freundlich and Redlich-Peterson models provides good results (comparable with non-linear regressions). Unlike both UCs, the best fit of the experimental data from the adsorption on the coal has been achieved by the Langmuir isotherm model. The results based on the Freundlich or Redlich-Peterson model were (in this case) somewhat worse.

关键词: Adsorption, Unburned carbon, Naphthol Green B, Isotherms, Non-linear modelling, Redlich-Peterson model

Lucie Bartoňová, Lucie Ruppenthalová, Michal Ritz. Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling[J]. , 2017, 25(1): 37-44.

References

[1] C. Fernández, M.S. Larrechi, M.P. Callao, An analytical overview of processes for removing organic dyes from wastewater effluents, Trac Trends Anal. Chem. 29(10) (2010) 1202-2011.
[2] T. Robinson, G. McMullan, R. Marchant, P. Nigam, Remediation of dyes in textile effluent:A critical review on current treatment technologies with a proposed alternative, Bioresour. Technol. 77(3) (2001) 247-255.
[3] E. Forgacs, T. Cserháti, R. Oros, Removal of synthetic dyes from wastewaters:A review, Environ. Int. 30(7) (2004) 953-971.
[4] R.M. Gong, Y.Z. Sun, J. Chen, H.J. Liu, C. Yang, Effect of chemical modification on dye adsorption capacity of peanut hull, Dyes Pigments 67(3) (2005) 175-181.
[5] Y.S. Ho, G. McKay, Kinetic models for the sorption of dye from aqueous solution by wood, Process Saf. Environ. 76(B2) (1998) 183-191.
[6] C. Palma, L. Lloret, A. Puen, M. Tobar, E. Contreras, Production of carbonaceous material from avocado peel for its application as alternative adsorbent for dyes removal, Chin. J. Chem. Eng. 24(4) (2016) 521-528.
[7] Y.S. Ho, T.H. Chiang, Y.M. Hsueh, Removal of basic dye from aqueous solution using tree fern as a biosorbent, Process Biochem. 40(1) (2005) 119-124.
[8] N. Sivarajasekar, R. Baskar, Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds:Batch and fixed-bed column studies, Chin. J. Chem. Eng. 23(10) (2015) 1614-1619.
[9] Y.S. Ho, G. McKay, Sorption of dye from aqueous solution by peat, Chem. Eng. J. 70(2) (1998) 115-124.
[10] A. Hassani, L. Alidokht, A.R. Khatae, S. Karaca, Optimization of comparative removal of two structurally different basic dyes using coal as a low-cost and available adsorbent, J. Taiwan Inst. Chem. E 45(4) (2014) 1597-1607.
[11] A. Hassani, F. Vafaei, S. Karaca, A.R. Khataee, Adsorption of cationic dye from aqueous solution using Turkish lignite:Kinetic, isotherm, thermodynamic studies and neural network, J. Ind. Eng. Chem. 20(4) (2014) 2615-2624.
[12] N. Mirzaei, M. Hadi, M. Gholami, R.F. Fard, M.S. Aminabad, Sorption of acid dye by surfactant modificated natural zeolites, J. Taiwan Inst. Chem. E 59(2016) 186-194.
[13] D. Plachá, G.S. Martynková, J. Kukutschova, Sorpce par naftalenu na organicky modifikovaný vermikulit, Chem. List. 105(3) (2011) 186-192.
[14] P. Janoš, H. Buchtová, M. Rýznarová, Sorption of dyes from aqueous solutions onto fly ash, Water Res. 37(20) (2003) 4938-4944.
[15] S. Wang, Q. Ma, Z.H. Zhu, Characteristic of coal fly ash and adsorption application, Fuel 87(15-16) (2008) 3469-3473.
[16] Z. Liu, Y. Liu, Structure and properties of forming adsorbents prepared from different particle sizes of coal fly ash, Chin. J. Chem. Eng. 23(1) (2015) 290-295.
[17] Y. Gao, S. Xu, Q. Yue, Y. Wu, B. Gao, Chemical preparation of crab shell-based activated carbon with superior adsorption performance for dye removal from wastewater, J. Taiwan Inst. Chem. E 61(2016) 327-335.
[18] D.A. Giannakoudakis, G.Z. Kyzas, A. Avranas, N.K. Lazaridis, Multi-parametric adsorption effects of the reactive dye removal with commercial activated carbons, J. Mol. Liq. 213(2016) 381-389.
[19] R. Baccar, P. Blánquez, J. Bouzid, M. Feki, H. Attiya, M. Sarra, Modeling of adsorption isotherms and kinetics of a tannery dye onto an activated carbon prepared from an agricultural by-product, Fuel Process. Technol. 106(2013) 408-415.
[20] F. Scala, R. Chirone, A. Lancia, In-duct removal of mercury from coal-fired power plant flue gas by activated carbon:Assessment of entrained flow versus wall surface contributions, Environ. Eng. Sci. 25(10) (2008) 1423-1428.
[21] C. Senior, M. Denison, M. Bockelie, A. Sarofim, J. Siperstein, Q. He, Modelling of thermal desorption of Hg from activated carbon, Fuel Process. Technol. 91(10) (2010) 1282-1287.
[22] F. Scala, R. Chirone, A. Lancia, Elemental mercury vapor capture by powdered activated carbon in a fluidized bed reactor, Fuel 90(6) (2011) 2077-2082.
[23] M. Cabielles, M.A. Montes-Motán, A.B. Garcia, Structural study of graphite materials prepared by HTT of unburned carbon concentrates from coal combustion fly ashes, Energy Fuel 22(2) (2008) 1239-1243.
[24] T. Navrátil, Z. Šenholdová, K. Shanmugam, J. Barek, Voltametric determination of phenylglyoxylic acid in urine using graphite composite electrode, Electroanalysis 18(2) (2006) 201-206.
[25] M. Cabielles, J.-N. Rouzaud, A.B. Garcia, High-resolution transmission electron microscopy studies of graphite materials prepared by high-temperature treatment of unburned carbon concentrates from combustion fly ashes, Energy Fuel 23(2) (2009) 942-950.
[26] L. Bartoňová, Unburned carbon from coal combustion ash:An overview, Fuel Process. Technol. 134(2015) 136-158.
[27] N.J. Wagner, R.H. Matjie, J.H. Slaghuis, J.H.P. van Heerden, Characterization of unburned carbon present in coarse gasification ash, Fuel 87(6) (2008) 683-691.
[28] N. Malumbazo, N.J. Wagner, J.R. Bunt, D. van Niekerk, H. Assumption, Structural analysis of chars generated from South African inertinite coals in a pipe-reactor combustion unit, Fuel Process. Technol. 92(4) (2011) 743-749.
[29] V.P. Chabalala, N.J. Wagner, S. Potgieter-Vermaak, Investigation into the evolution of char structure using Raman spectroscopy in conjunction with coal petrography:Part 1, Fuel Process. Technol. 92(4) (2011) 750-756.
[30] L. Bartoňová, Z. Klika, D.A. Spears, Characterization of unburned carbon from ash after bituminous coal and lignite combustion in CFBs, Fuel 86(3) (2007) 455-463.
[31] J.C. Hower, C.L. Senior, E.M. Suuberg, R.H. Hurt, J.L. Wilcox, E.S. Olson, Mercury capture by native fly ash carbons in coal-fired power plants, Prog. Energy Combust. 36(4) (2010) 510-529.
[32] L. Bartoňová, B. Čech, L. Ruppenthalová, V. Majvelderová, D. Juchelková, Z. Klika, Effect of unburned carbon content in fly ash on the retention of 12 elements out of coal-combustion flue gas, J. Environ. Sci. 24(9) (2012) 1624-1629.
[33] S. Wang, L. Li, H. Wu, Z.H. Zhu, Unburned carbon as a low-cost adsorbent for treatment of methylene blue-containing wastewater, J. Colloid Interface Sci. 292(2) (2005) 336-343.
[34] S. Wang, H. Li, Dye adsorption on unburned carbon:Kinetics and equilibrium, J. Hazard. Mater. 126(1-3) (2005) 71-77.
[35] F. Montagnaro, L. Santoro, Reuse of coal combustion ashes as dyes and heavy metal adsorbents:Effect of sieving and demineralization on waste properties and adsorption capacity, Chem. Eng. J. 150(1) (2009) 174-180.
[36] F.C. Wu, P.H. Wu, R.L. Tseng, R.S. Juang, Preparation of activated carbons from unburnt coal in bottom ash with KOH activation for liquid-phase adsorption, J. Environ. Manag. 91(5) (2010) 1097-1102.
[37] S. Wang, H. Li, Kinetic modelling and mechanism of dye adsorption on unburned carbon, Dyes Pigments 72(3) (2007) 308-314.
[38] J.C. Hower, J.D. Robertson, Chemistry and petrology of fly ash derived from the co-combustion of western United States coal and tire-derived fuel, Fuel Process. Technol. 85(5) (2004) 359-377.
[39] H. Raclavská, D. Juchelková, V. Roubíček, D. Matysek, Energy utilization of biowaste-Sunflower-seed hulls for co-firing with coal, Fuel Process. Technol. 92(1) (2011) 13-20.
[40] D.O. Glushkov, N.E. Schlegel, P.A. Strizhak, K.Y. Vershinina, Heat transfer under ignition of droplet of composite liquid fuel made of coal, water and oil in an oxidant flow, Adv. Appl. Fluid Mech. 19(1) (2016) 157-168.
[41] F. Scala, R. Chirone, Fluidised bed combustion of alternative solid fuels, Exp. Thermal Fluid Sci. 28(7) (2004) 691-699.
[42] H. Raclavská, D. Juchelková, H. Škrobánková, T. Wiltowski, A. Campen, Conditions for energy generation as an alternative approach to compost utilization, Environ. Technol. 32(4) (2011) 407-417.
[43] D.O. Glushkov, P.A. Strizhak, K.Y. Vershinina, Minimum temperatures for sustainable ignition of coal water slurry containing petrochemicals, Appl. Therm. Eng. 96(2016) 534-546.
[44] D. Juchelková, A. Corsaro, A. Hlavsová, H. Raclavská, Effect of composting on the production of syngas during pyrolysis of perennial grasses, Fuel 154(2015) 380-390.
[45] K.V. Kumar, Optimum sorption isotherm by linear and non-linear methods for malachite green lemon peel, Dyes Pigments 74(3) (2007) 595-597.
[46] M.I. El-Khaiary, Least-squares regression of adsorption equilibrium data:Comparing the options, J. Hazard. Mater. 158(1) (2008) 73-87.
[47] Y.S. Ho, Selection of optimum sorption isotherm, Carbon 42(10) (2004) 2115-2116.
[48] K.V. Kumar, S. Sivanesan, Prediction of optimum sorption isotherm:Comparison of linear and non-linear method, J. Hazard. Mater. B126(2005) 198-201.
[49] K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J. 156(1) (2010) 2-10.
[50] I. Langmuir, The adsorption of gases on plane surface of glass, mica and platinum, J. Am. Chem. Soc. 40(1916) 1361-1368.
[51] Y.S. Ho, J.F. Porter, G. McKay, Equilibrium isotherm studies for the sorption of divalent metal ions onto peat:Copper, nickel and lead single component systems, Water Air Soil Pollut. 141(1-4) (2002) 1-33.
[52] H.M.F. Freundlich, Over the adsorption in solution, J. Phys. Chem. 57(1906) 385-470.
[53] O. Redlich, D.L. Peterson, A useful adsorption isotherm, J. Phys. Chem. 63(1959) 1024-1026.
[54] G. McKay, S.J. Allen, I.F. McConvey, The adsorption of dyes from solution-Equilibrium and column studies, Water Air Soil Pollut. 21(1-4) (1984) 127-129.
[55] M.I. El-Khaiary, G.F. Malash, Common data analysis errors in batch adsorption studies, Hydrometallurgy 105(2011) 314-320.57.
[56] F.-C. Wu, B.-L. Liu, K.-T. Wu, R.-L. Tseng, A new linear form analysis of Redlich-Peterson isotherm equation for the adsorptions of dyes, Chem. Eng. J. 162(2010) 21-27.
[57] M.F. Attallah, I.M. Ahmed, M.M. Hamed, Treatment of industrial wastewater containing Congo Red and Naphthol Green B using low-cost adsorbent, Environ. Sci. Pollut. Res. 20(2013) 1106-1116.
[58] Y. Cheng, Q. Feng, X. Ren, M. Yin, Y. Zhou, Z. Xue, Adsorption and removal of sulfonic dyes from aqueous solution onto a coordination polymeric xerogel with amino groups, Colloids Surf. A Physicochem. Eng. Asp. 485(2015) 125-135.
[59] E. Bezak-Mazur, D. Adamczyk, Changes in the chemistry of wd-extra activated carbon surface after Fenton's reagent regeneration used for adsorption of Naphthol Green B, Rocz. Ochrona Srodowiska 15(1) (2013) 966-980.

Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling

Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 26-36.
[2]	Jing Huang, Honghui Cai, Qian Zhao, Yunpeng Zhou, Haibo Liu, Jing Wang. Dual-functional pyrene implemented mesoporous silicon material used for the detection and adsorption of metal ions [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 108-117.
[3]	Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 212-227.
[4]	Alexander Nti Kani, Evans Dovi, Aaron Albert Aryee, Runping Han, Zhaohui Li, Lingbo Qu. Mechanisms and reusability potentials of zirconium-polyaziridine-engineered tiger nut residue towards anionic pollutants [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 275-292.
[5]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 9-15.
[6]	Hui Jiang, Zijian Zhao, Ning Yu, Yi Qin, Zhengwei Luo, Wenhua Geng, Jianliang Zhu. Synthesis, characterization, and performance comparison of boron using adsorbents based on N-methyl-D-glucosamine [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 16-31.
[7]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 262-269.
[8]	Shanghong Ma, Haitao Zhang, Jianbo Qu, Xiuzhong Zhu, Qingfei Hu, Jianyong Wang, Peng Ye, Futao Sai, Shiwei Chen. Preparation of waterborne polyurethane/β-cyclodextrin composite nanosponge by ion condensation method and its application in removing of dyes from wastewater [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 124-136.
[9]	Yueting Shi, Junhai Zhao, Lingli Chen, Hongru Li, Shengtao Zhang, Fang Gao. Double open mouse-like terpyridine parts based amphiphilic ionic molecules displaying strengthened chemical adsorption for anticorrosion of copper in sulfuric acid solution [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 233-246.
[10]	Jian Wang, Yuanhui Shen, Donghui Zhang, Zhongli Tang, Wenbin Li. Integrated vacuum pressure swing adsorption and Rectisol process for CO₂ capture from underground coal gasification syngas [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 265-279.
[11]	Yujia Cui, Zhiqiang Tan, Yanan Wang, Shuxian Shi, Xiaonong Chen. One-step crosslinking preparation of tannic acid particles for the adsorption and separation of cationic dyes [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 309-318.
[12]	Shanshan Mao, Tao Shen, Qing Zhao, Tong Han, Fan Ding, Xin Jin, Manglai Gao. Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 319-328.
[13]	Hany M. Abd El-Lateef, Mai M. Khalaf, K. Shalabi, Antar A. Abdelhamid. Multicomponent synthesis and designing of tetrasubstituted imidazole compounds catalyzed via ionic-liquid for acid steel corrosion protection: Experimental exploration and theoretical calculations [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 304-319.
[14]	Zhongqi Ren, Jie Wang, Hewei Zhang, Fan Zhang, Shichao Tian, Zhiyong Zhou. Adsorption of rubidium ion from aqueous solution by surface ion imprinted materials [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 1-10.
[15]	Mengge Shang, Jing Zhang, Jinqiang Sun, Shimo Yu, Feng Hua, Xiaoxu Xuan, Xun Sun, Serguei Filatov, Xibin Yi. Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 36-43.