Ionic liquids for CO2 electrochemical reduction

doi:10.1016/j.cjche.2020.10.029

Chinese Journal of Chemical Engineering ›› 2021, Vol. 29 ›› Issue (3): 75-93.DOI: 10.1016/j.cjche.2020.10.029

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Ionic liquids for CO₂ electrochemical reduction

Fangfang Li¹, Francesca Mocci², Xiangping Zhang³, Xiaoyan Ji¹, Aatto Laaksonen^1,4,5,6

1 Energy Engineering, Division of Energy Science, Luleå University of Technology, Luleå 97187, Sweden;
2 Department of Chemical and Geological Sciences, University of Cagliari, Monserrato 09042, Italy;
3 CAS Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
4 Division of Physical Chemistry, Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm 10691, Sweden;
5 Center of Advanced Research in Bionanocojugates and Biopolymers, "Petru Poni" Institute of Macromolecular Chemistry, Iasi 700469, Romania;
6 State Key Laboratory of Materials-Oriented and Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

Received:2020-09-01 Revised:2020-10-26 Online:2021-05-13 Published:2021-03-28
Contact: Xiaoyan Ji, Aatto Laaksonen
Supported by:
F. Li and X. Ji thank the financial support from the Swedish Energy Agency (P47500-1). A. Laaksonen acknowledges the Swedish Research Council for financial support (2019-03865), and partial support from a grant from Ministry of Research and Innovation of Romania (CNCS - UEFISCDI, project number PN-IIIP4-ID-PCCF-2016-0050, within PNCDI III). F. Mocci thanks the Fondazione di Sardegna, Project: “Precious metal-free complexes for catalytic CO₂ reduction” (CUP: F71I17000170002) for the financial support.

Ionic liquids for CO₂ electrochemical reduction

Fangfang Li¹, Francesca Mocci², Xiangping Zhang³, Xiaoyan Ji¹, Aatto Laaksonen^1,4,5,6

1 Energy Engineering, Division of Energy Science, Luleå University of Technology, Luleå 97187, Sweden;
2 Department of Chemical and Geological Sciences, University of Cagliari, Monserrato 09042, Italy;
3 CAS Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
4 Division of Physical Chemistry, Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm 10691, Sweden;
5 Center of Advanced Research in Bionanocojugates and Biopolymers, "Petru Poni" Institute of Macromolecular Chemistry, Iasi 700469, Romania;
6 State Key Laboratory of Materials-Oriented and Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

通讯作者: Xiaoyan Ji, Aatto Laaksonen
基金资助:
F. Li and X. Ji thank the financial support from the Swedish Energy Agency (P47500-1). A. Laaksonen acknowledges the Swedish Research Council for financial support (2019-03865), and partial support from a grant from Ministry of Research and Innovation of Romania (CNCS - UEFISCDI, project number PN-IIIP4-ID-PCCF-2016-0050, within PNCDI III). F. Mocci thanks the Fondazione di Sardegna, Project: “Precious metal-free complexes for catalytic CO₂ reduction” (CUP: F71I17000170002) for the financial support.

Abstract

Abstract: Electrochemical reduction of CO₂ is a novel research field towards a CO₂-neutral global economy and combating fast accelerating and disastrous climate changes while finding new solutions to store renewable energy in value-added chemicals and fuels. Ionic liquids (ILs), as medium and catalysts (or supporting part of catalysts) have been given wide attention in the electrochemical CO₂ reduction reaction (CO₂RR) due to their unique advantages in lowering overpotential and improving the product selectivity, as well as their designable and tunable properties. In this review, we have summarized the recent progress of CO₂ electro-reduction in IL-based electrolytes to produce higher-value chemicals. We then have highlighted the unique enhancing effect of ILs on CO₂RR as templates, precursors, and surface functional moieties of electrocatalytic materials. Finally, computational chemistry tools utilized to understand how the ILs facilitate the CO₂RR or to propose the reaction mechanisms, generated intermediates and products have been discussed.

Key words: Carbon dioxide, Ionic liquids, Electro-reduction, Electrolyte, Electrocatalytic material, Computer simulation

摘要： Electrochemical reduction of CO₂ is a novel research field towards a CO₂-neutral global economy and combating fast accelerating and disastrous climate changes while finding new solutions to store renewable energy in value-added chemicals and fuels. Ionic liquids (ILs), as medium and catalysts (or supporting part of catalysts) have been given wide attention in the electrochemical CO₂ reduction reaction (CO₂RR) due to their unique advantages in lowering overpotential and improving the product selectivity, as well as their designable and tunable properties. In this review, we have summarized the recent progress of CO₂ electro-reduction in IL-based electrolytes to produce higher-value chemicals. We then have highlighted the unique enhancing effect of ILs on CO₂RR as templates, precursors, and surface functional moieties of electrocatalytic materials. Finally, computational chemistry tools utilized to understand how the ILs facilitate the CO₂RR or to propose the reaction mechanisms, generated intermediates and products have been discussed.

关键词: Carbon dioxide, Ionic liquids, Electro-reduction, Electrolyte, Electrocatalytic material, Computer simulation

Fangfang Li, Francesca Mocci, Xiangping Zhang, Xiaoyan Ji, Aatto Laaksonen. Ionic liquids for CO₂ electrochemical reduction[J]. Chinese Journal of Chemical Engineering, 2021, 29(3): 75-93.

Fangfang Li, Francesca Mocci, Xiangping Zhang, Xiaoyan Ji, Aatto Laaksonen. Ionic liquids for CO₂ electrochemical reduction[J]. 中国化学工程学报, 2021, 29(3): 75-93.

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Ionic liquids for CO₂ electrochemical reduction

Ionic liquids for CO₂ electrochemical reduction

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