Hydrogenation of CO2 to formate catalyzed by SBA-15-supported cyclic (alkyl)(amino)carbene-iridium

doi:10.1016/j.cjche.2022.07.029

Abstract

Abstract: Recently, cyclic (alkyl)(amino)carbenes (CAACs) have been widely used as ligands to enhance the catalytic reactivity of center metal, but the problem of recycling this expensive ligand remains to be solved. In this work, the heterogeneous SBA-15-CAAC-Ir catalyst was prepared by a covalent attachment method, and using SBA-15 as the carrier. It shows high reactivity for the hydrogenation of CO₂ to formate. After immobilization, the ordered mesoporous structure and the overall rod-like morphology of the original SBA-15 have been preserved very well. Using SBA-15-CAAC-Ir as catalyst, up to 21050 TON can be obtained at 60 ℃. In addition, the catalyst can be separated easily by centrifugation, and the catalytic activity of SBA-15-CAAC-Ir can still remain very high after multiple cycles.

Key words: Cyclic (alkyl)(amino)carbenes, Carbon dioxide, Hydrogenation, SBA-15, Formate

摘要： Recently, cyclic (alkyl)(amino)carbenes (CAACs) have been widely used as ligands to enhance the catalytic reactivity of center metal, but the problem of recycling this expensive ligand remains to be solved. In this work, the heterogeneous SBA-15-CAAC-Ir catalyst was prepared by a covalent attachment method, and using SBA-15 as the carrier. It shows high reactivity for the hydrogenation of CO₂ to formate. After immobilization, the ordered mesoporous structure and the overall rod-like morphology of the original SBA-15 have been preserved very well. Using SBA-15-CAAC-Ir as catalyst, up to 21050 TON can be obtained at 60 ℃. In addition, the catalyst can be separated easily by centrifugation, and the catalytic activity of SBA-15-CAAC-Ir can still remain very high after multiple cycles.

关键词: Cyclic (alkyl)(amino)carbenes, Carbon dioxide, Hydrogenation, SBA-15, Formate

Lei Zhou, Lingling Peng, Xingbang Hu. Hydrogenation of CO₂ to formate catalyzed by SBA-15-supported cyclic (alkyl)(amino)carbene-iridium[J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 283-291.

Lei Zhou, Lingling Peng, Xingbang Hu. Hydrogenation of CO₂ to formate catalyzed by SBA-15-supported cyclic (alkyl)(amino)carbene-iridium[J]. 中国化学工程学报, 2022, 50(10): 283-291.

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Hydrogenation of CO₂ to formate catalyzed by SBA-15-supported cyclic (alkyl)(amino)carbene-iridium

Hydrogenation of CO₂ to formate catalyzed by SBA-15-supported cyclic (alkyl)(amino)carbene-iridium

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