SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2023, Vol. 59 ›› Issue (7): 193-199.DOI: 10.1016/j.cjche.2023.01.017

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Nitrogen and phosphorus co-doped activated carbon induces high density Cu+ active center for acetylene hydrochlorination

Fei Li1, Xuemei Wang2, Pengze Zhang1, Qinqin Wang2, Mingyuan Zhu1, Bin Dai2   

  1. 1. College of Chemistry and Chemical Engineering, Yantai University, Yantai 264004, China;
    2. School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000, China
  • Received:2022-11-03 Revised:2022-12-30 Online:2023-10-14 Published:2023-07-28
  • Contact: Mingyuan Zhu,E-mail:zhuminyuan@shzu.edu.cn
  • Supported by:
    This work was supported by the Taishan Scholars Program of Shandong Province (tsqn202103051), the Project of Scientific Research in Shihezi University (CXFZ202205).

Nitrogen and phosphorus co-doped activated carbon induces high density Cu+ active center for acetylene hydrochlorination

Fei Li1, Xuemei Wang2, Pengze Zhang1, Qinqin Wang2, Mingyuan Zhu1, Bin Dai2   

  1. 1. College of Chemistry and Chemical Engineering, Yantai University, Yantai 264004, China;
    2. School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000, China
  • 通讯作者: Mingyuan Zhu,E-mail:zhuminyuan@shzu.edu.cn
  • 基金资助:
    This work was supported by the Taishan Scholars Program of Shandong Province (tsqn202103051), the Project of Scientific Research in Shihezi University (CXFZ202205).

Abstract: This work aims to solve the problems of low reaction activity of Cu-based catalysts and agglomeration of active centers in acetylene hydrochlorination. Cu-based catalysts supported by NP co-doped activated carbon (AC) with different content (mCu-xNP/AC) were manufactured and applied in the acetylene hydrochlorination reaction. It was found that the doping of carriers N and P induced the transformation of Cu2+ to Cu+, and the catalytic activity was markedly improved. Under the optimal reaction temperature of 220 ℃, the gas hourly space velocity (GHSV) of C2H2 was 90 h-1 and VHCL : VC2H2 was 1.15. The initial activity of the 5%Cu-30NP/AC catalyst reached 95.59%. Through some characterization methods showed the addition of N and P improved the dispersion of Cu in carbon, which increased the ratio of Cu+/Cu2+. The measurement results confirmed that the chemisorption capacity of mCu-xNP/AC for C2H2 decreased slightly, and the chemisorption capacity for HCl increased significantly, which was the reason for the increased activity of the catalyst. The conclusion provides a reference for the development of acetylene hydrochlorination Cu catalyst.

Key words: Acetylene hydrochlorination, Cu-based catalysts, Catalytic activity, Heterogeneous catalysis, N and P co-doped

摘要: This work aims to solve the problems of low reaction activity of Cu-based catalysts and agglomeration of active centers in acetylene hydrochlorination. Cu-based catalysts supported by NP co-doped activated carbon (AC) with different content (mCu-xNP/AC) were manufactured and applied in the acetylene hydrochlorination reaction. It was found that the doping of carriers N and P induced the transformation of Cu2+ to Cu+, and the catalytic activity was markedly improved. Under the optimal reaction temperature of 220 ℃, the gas hourly space velocity (GHSV) of C2H2 was 90 h-1 and VHCL : VC2H2 was 1.15. The initial activity of the 5%Cu-30NP/AC catalyst reached 95.59%. Through some characterization methods showed the addition of N and P improved the dispersion of Cu in carbon, which increased the ratio of Cu+/Cu2+. The measurement results confirmed that the chemisorption capacity of mCu-xNP/AC for C2H2 decreased slightly, and the chemisorption capacity for HCl increased significantly, which was the reason for the increased activity of the catalyst. The conclusion provides a reference for the development of acetylene hydrochlorination Cu catalyst.

关键词: Acetylene hydrochlorination, Cu-based catalysts, Catalytic activity, Heterogeneous catalysis, N and P co-doped