Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

›› 2008, Vol. 16 ›› Issue (3): 373-375.

• SPECIAL ISSUE OF THE FIRST INTERNATIONAL SYMPOSIUM ON SUSTAINABLE CHEMICAL PRODUCT AND PROCESS ENGINEERING • Previous Articles Next Articles

Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

WANG Jianying^1,2, ZHAO Hua², ZHANG Xiangjing², LIU Runjing², HU Yongqi^1,2

1. College of Chemical Engineering, Beijing Unversity of Chemical Technology, Beijing 100029, China;
2. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China

Received:2007-09-25 Revised:2008-03-17 Online:2008-06-28 Published:2008-06-28
Supported by:
Supported the National Natural Science Foundation of China (20776037)

Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

王建英^1,2, 赵华², 张向京², 刘润静², 胡永琪^1,2

1. College of Chemical Engineering, Beijing Unversity of Chemical Technology, Beijing 100029, China;
2. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China

通讯作者: HU Yongqi,E-mail:huyq2000@126.com;huyq@hebust.edu.cn
基金资助:
Supported the National Natural Science Foundation of China (20776037)

Abstract

Abstract: An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with Tert-butyl-hydroperoxide catalyzed by titanium silicalite 1(TS-1)in ambient-temperature ionic liquid [emim]BF₄.Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent.The research results showed 13.2% conversion of cyclohexane,97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.

Key words: ionic liquid, cyclohexane, TS-1, tert-butyl-hydroperoxide

摘要： An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with Tert-butyl-hydroperoxide catalyzed by titanium silicalite 1(TS-1)in ambient-temperature ionic liquid [emim]BF₄.Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent.The research results showed 13.2% conversion of cyclohexane,97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.

关键词: ionic liquid, cyclohexane, TS-1, tert-butyl-hydroperoxide

WANG Jianying, ZHAO Hua, ZHANG Xiangjing, LIU Runjing, HU Yongqi. Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide[J]. , 2008, 16(3): 373-375.

王建英, 赵华, 张向京, 刘润静, 胡永琪. Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide[J]. , 2008, 16(3): 373-375.

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Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

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