Abstract: Metal ion contamination of drinking water and waste water, especially with heavy metal ion such as lead, is a serious and ongoing problem. In this work, activated carbon prepared from peanut shell (PAC) was used for the removal of Pb²⁺ from aqueous solution. The impacts of the Pb²⁺ adsorption capacities of the acid-modified carbons oxidized with HNO₃ were also investigated. The surface functional groups of PAC were confirmed by Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Boehm titration. The textural properties (surface area, total pore volume) were evaluated from the nitrogen adsorption isotherm at 77 K. The experimental results presented indicated that the adsorption data fitted better with the Langmuir adsorption model. A comparative study with a commercial granular activated carbon (GAC) showed that PAC was 10.3 times more efficient compared to GAC based on Langmuir maximum adsorption capacity. Further analysis results by the Langmuir equation showed that HNO₃ [20% (by mass)] modified PAC has larger adsorption capacity of Pb²⁺ from aqueous solution (as much as 35.5 mg·g^-1). The adsorption capacity enhancement ascribed to pore widening, increased cation-exchange capacity by oxygen groups, and the promoted hydrophilicity of the carbon surface.

Key words: activated carbon, phosphoric acid, adsorption, wastewater treatment, surface modification

摘要： Metal ion contamination of drinking water and waste water, especially with heavy metal ion such as lead, is a serious and ongoing problem. In this work, activated carbon prepared from peanut shell (PAC) was used for the removal of Pb²⁺ from aqueous solution. The impacts of the Pb²⁺ adsorption capacities of the acid-modified carbons oxidized with HNO₃ were also investigated. The surface functional groups of PAC were confirmed by Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Boehm titration. The textural properties (surface area, total pore volume) were evaluated from the nitrogen adsorption isotherm at 77 K. The experimental results presented indicated that the adsorption data fitted better with the Langmuir adsorption model. A comparative study with a commercial granular activated carbon (GAC) showed that PAC was 10.3 times more efficient compared to GAC based on Langmuir maximum adsorption capacity. Further analysis results by the Langmuir equation showed that HNO₃ [20% (by mass)] modified PAC has larger adsorption capacity of Pb²⁺ from aqueous solution (as much as 35.5 mg·g^-1). The adsorption capacity enhancement ascribed to pore widening, increased cation-exchange capacity by oxygen groups, and the promoted hydrophilicity of the carbon surface.

关键词: activated carbon, phosphoric acid, adsorption, wastewater treatment, surface modification