Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction

›› 2011, Vol. 19 ›› Issue (6): 926-930.

• SEPARATION SCIENCE AND ENGINEERING • Previous Articles Next Articles

Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction

LI Liqing^1,2, ZHONG Hong¹, CAO Zhanfang¹, YUAN Lu¹

1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2. School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 34100, China

Received:2010-11-19 Revised:2011-08-17 Online:2012-04-24 Published:2011-12-28
Supported by:
Supported by the National Key Technologies Research and Development Program of China during the 11th Five-Year Plan Period (2007BAB22B01);the Young Science Foundation of Jiangxi Province Education Office (GJJ11124)

Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction

李立清^1,2, 钟宏¹, 曹占芳¹, 袁露¹

1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2. School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 34100, China

通讯作者: ZHONG Hong, E-mail: zhonghongcsu@163.com
基金资助:
Supported by the National Key Technologies Research and Development Program of China during the 11th Five-Year Plan Period (2007BAB22B01);the Young Science Foundation of Jiangxi Province Education Office (GJJ11124)

Abstract

Abstract: The solvent extraction technology was applied to recover Cu²⁺ and Ni²⁺ from plating wastewater. Lix984N was chosen as the extractant due to its good extraction performance. The influence parameters were examined. The results show that the separation of Cu²⁺ and Ni²⁺ from sulphate medium can be realized by adjusting pH value with the help of Lix984N. For extracting Cu²⁺ and Ni²⁺, the optimal pH values are 4 and 10.5, and the maximal extraction percentages are 92.9% and 93.0%, respectively. With recovered Cu²⁺ and Ni²⁺ stripped in 170 g·L^-1 and 200 g·L^-1 H₂SO₄ medium, the stripping percentages of Cu²⁺ and Ni²⁺ are 92.9% and 93.0%, respectively. This method is simple and can be used to recover Cu²⁺ and Ni²⁺ from plating wastewater. And a flow sheet for separation of Cu²⁺ and Ni²⁺ is presented.

Key words: recovery, copper, nickel, solvent extraction, plating wastewater

摘要： The solvent extraction technology was applied to recover Cu²⁺ and Ni²⁺ from plating wastewater. Lix984N was chosen as the extractant due to its good extraction performance. The influence parameters were examined. The results show that the separation of Cu²⁺ and Ni²⁺ from sulphate medium can be realized by adjusting pH value with the help of Lix984N. For extracting Cu²⁺ and Ni²⁺, the optimal pH values are 4 and 10.5, and the maximal extraction percentages are 92.9% and 93.0%, respectively. With recovered Cu²⁺ and Ni²⁺ stripped in 170 g·L^-1 and 200 g·L^-1 H₂SO₄ medium, the stripping percentages of Cu²⁺ and Ni²⁺ are 92.9% and 93.0%, respectively. This method is simple and can be used to recover Cu²⁺ and Ni²⁺ from plating wastewater. And a flow sheet for separation of Cu²⁺ and Ni²⁺ is presented.

关键词: recovery, copper, nickel, solvent extraction, plating wastewater

LI Liqing, ZHONG Hong, CAO Zhanfang, YUAN Lu. Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction[J]. , 2011, 19(6): 926-930.

李立清, 钟宏, 曹占芳, 袁露. Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction[J]. , 2011, 19(6): 926-930.

References

1 Farrell, M., Perkins, W.T., Hobbs, P.J., Griffth, G.W., Jones, D.L., “Migration of heavy metals in soil as influenced by compost amendments”, Environ. Pollut., 158, 55-64(2010).
2 Jha, M.K., Van Nguyen, N., Lee, J.C., Jeong, J., Yoo, J.M., “Adsorption of copper from the sulphate solution of low copper contents using the cationic resin amberlite IR 120”, J. Hazard. Mater., 164, 948-953(2009).
3 Panigrahi, S., Parhi, P.K., Sarangi, K., Nathsarma, K.C., “A study on extraction of copper using LIX84-I and LIX622N”, Sep. Purif. Technol., 70, 58-62(2009).
4 Parija, C., Bhaskara Sarma, P.V.R., “Separation of nickel and copper from ammoniacal solutions through co-extraction and selective stripping using LIX84 as the extractant”, Hydrometallurgy, 54, 195-204(2000).
5 Agrawal, A., Manoj, M.K., Kumari, S., Bagchi, D., Kumar, V., Pandey, B.D., “Extractive separation of copper and nickel from copper bleed stream by solvent extraction route”, Minerals Engineering, 21, 1126-1130(2008).
6 Ritcey, G.M., Ashbrook, A.W., Solvent Extraction—Principles and Applications to Process Metallurgy, Part I, Elsevier, 21-26(1984).
7 Ritcey., G.M., Ashbrook, A.W., Solvent Extraction—Principles and Applications to Process Metallurgy, Part II, Elsevier, 78-99(1979).
8 Sastre, A.M., Alguacil, F.J., “Co-extraction and selective stripping of copper(II) and molybdenum(VI) using LIX 622”, Chem. Eng. J., 81, 109-112(2001).
9 Alguacil, F.J., “Recovery of copper from ammoniacal/ammonium carbonate medium by LIX 973N”, Hydrometallurgy, 52, 55-61(1999).
10 Pospiech, B., Walkowiak, W., “Separation of copper(II), cobalt(II) and nickel(II) from chloride solutions by polymer inclusion membranes”, Sep. Purif. Technol., 57, 461-467(2007).
11 Reddy, B.R., Park, K.H., Mohapatra, D., “Process development for the separation and recovery of copper from sulphate leach liquors of synthetic Cu-Ni-Co-Fe matte using LIX 84 and LIX 973N”, Hydrometallurgy, 87, 51-57(2007).
12 Lan, Z.Y., Hu, Y.H., Liu, J.S., Liu, J.S., Wang, J., “Solvent extraction of copper and zinc from bioleaching solutions with LIX984 and D2EHPA”, J. Cent. South Univ. Technol., 12(1), 46-52(2005).(in Chinese)
13 Liu, X.R., Qiu, G.Z., Hu, Y.H., Yang, J.H., Jin, M.L., “Effect of Lix984N content on phase disengagement dynamics in copper-SX”, Trans. Nonferrous Met. Soc. China, 13(4), 963-969(2003).(in Chinese)
14 Owusu, G., “Selective extraction of copper from acidic zinc sulfate leach solution using LIX 622”, Hydrometallurgy, 51, 1-7(1999).
15 Xie, F., Dreisinger, D., “Recovery of copper cyanide from waste cyanide solution by LIX 7950”, Minerals Engineering, 22, 190-195(2009).
16 Sayar, N.A., Filiz, M., Sayar, A.A., “Extraction of Co(II) and Ni(II) from concentrated HCl solution using Alamine 336”, Hydrometallurgy, 96, 148-153(2009).
17 Sayilgan, E., Kukrer, T., Civelekoglu, G., “A review of technologies for the recovery of metals from spent alkaline and zinc-carbon batteries”, Hydrometallurgy, 97, 158-166(2009).
18 Wu, F., Xu, S.M., Li, L.Y., “Recovery of valuable metals from anode material of hydrogen-nickel battery”, Trans. Nonferrous Met. Soc., 19, 468-473(2009).(in Chinese)
19 Alorro, R.D., Hiroyoshi, N., Ito, M., “Recovery of heavy metals from MSW molten fly ash by CIP method”, Hydrometallurgy, 97, 8-14(2009).
20 Gameiro, M.L.F., Ismael, M.R.C., “Recovery of copper from ammoniacal medium using liquid membranes with LIX 54”, Sep. Purif. Technol., 63, 287-296(2008).
21 Reddy, B.R., Priya, D.N., “Process development for the separation of copper(II), nickel(II) and zinc(II) from sulphate solutions by solvent extraction using LIX84-I”, Sep. Purif. Technol., 45, 163-167(2005).
22 Facon, S., Adekola, F., Cote, G., “Stripping of copper from CYANEX 301 extract with thiourea-hydrazine-sodium hydroxide solution”, Hydrometallurgy, 89, 297-304(2007).

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Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction

Recovery of Copper(II) and Nickel(II) from Plating Wastewater by Solvent Extraction

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