Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

doi:10.1016/S1004-9541(13)60490-5

Chin.J.Chem.Eng. ›› 2013, Vol. 21 ›› Issue (4): 442-446.DOI: 10.1016/S1004-9541(13)60490-5

• ENERGY, RESOURCES AND ENVIRONMENTAL TECHNOLOGY • Previous Articles Next Articles

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

CHEN Chunguang^1,2, FENG Yaqing¹, NIU Weiwei³, CHEN Xuexi ⁴

1 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 Huangdao Entry-Exit Inspection and Quarantine Bureau, Qingdao 266555, China;
3 School of Polymer Science and Engineering, Qingdao University of Science & Technology, Qingdao 266042, China;
4 School of Chemical Engineering and Technology, Qingdao University of Science & Technology, Qingdao 266042, China

Received:2012-04-24 Revised:2012-11-12 Online:2013-04-26 Published:2013-04-28

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

陈春光^1,2, 冯亚青¹, 牛伟玮³, 陈学玺⁴

1 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 Huangdao Entry-Exit Inspection and Quarantine Bureau, Qingdao 266555, China;
3 School of Polymer Science and Engineering, Qingdao University of Science & Technology, Qingdao 266042, China;
4 School of Chemical Engineering and Technology, Qingdao University of Science & Technology, Qingdao 266042, China

通讯作者: CHEN Xuexi

Abstract

Abstract: The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing the decomposition of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level. Thus the zero release of nitrogen oxide waste gas can be achieved without using any absorption process.

Key words: nitrosation, nitrogen oxides, phase equilibrium

摘要： The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing the decomposition of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level. Thus the zero release of nitrogen oxide waste gas can be achieved without using any absorption process.

关键词: nitrosation, nitrogen oxides, phase equilibrium

CHEN Chunguang, FENG Yaqing, NIU Weiwei, CHEN Xuexi . Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice[J]. Chin.J.Chem.Eng., 2013, 21(4): 442-446.

陈春光, 冯亚青, 牛伟玮, 陈学玺. Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice[J]. Chinese Journal of Chemical Engineering, 2013, 21(4): 442-446.

References

1 Williams, D.L.H., Nitrosation Reactions and the Chemistry of Nitric Oxide, Elsevier, Netherlands (2004).

2 Bolzan, R., “Peroxynitrite-mediated oxidations: Nitration and nitrosation”, Ph. D. Thesis, Louisiana State University, USA (2002).

3 Czepiel, P., Douglas, E., Harriss, R., Crill, P., “Measurements of N₂O from composted organic wastes”, Environ. Sci. Technol, 30 (8), 2519-2525 (1996).

4 Barton, P.K., Atwater, J.W., “Nitrous oxide emissions and the anthropogenic nitrogen in wastewater and solid waste”, Journal of Environmental Engineering, 128 (2), 137-150 (2003).

5 Gong, Y.K., Wang, S.Y., Wang, S., Peng, Y.Z., “Nitrous oxide production from sequencing batch reactor sludge under nitrifying conditions: Effect of nitrite concentrations”, Environmental Technology, 33 (4), 401-408 (2012).

6 World Bank Group, “Nitrogen oxides: Pollution prevention and control”, In: Pollution Prevention and Abatement Handbook, World Bank Group, 245-249 (1998).

7 De Soete, G., “Nitrous oxide from combustion and industry: Chemistry, emissions, and control”, In: Proc. Int. IPCC Workshop on Methane and Nitrous Oxide: Methods in National Emissions Inventories and Options for Control, van Amstel, A.R., ed., The Netherlands, 287-337 (1993).

8 Braida, W., Ong, S.K., “Decomposition of nitrite under various pH and aeration conditions”, Water, Air, & Soil Pollution, 118 (1-2), 13-26 (2000).

9 Pires, M., Rossi, M.J., Ross, D.S., “Kinetic and mechanistic aspects of the NO oxidation by O₂ in aqueous phase”, International Journal of Chemical Kinetics, 26 (12), 1207-1227(1994).

10 Steinitz, K., “A combined potassium iodide-starch reagent”, Microchimica Acta, 35 (2-3), 176-177 (1950).

11 Board on Chemical Sciences and Technology, division of Earth and Life studies, Prudent Practices in the Laboratory: Handling and Management of Chemical Hazards, National Academy Press, Washington, D.C., 188-189 (2011).

12 Parker, W.L., “Methods for reducing the concentration of amines in process and hydrocarbon fluids”, US Pat., 5976359 (1999).

[1]	Tingting Jiao, Huiling Fan, Shoujun Liu, Song Yang, Wenguang Du, Pengzheng Shi, Chao Yang, Yeshuang Wang, Ju Shangguan. A review on nitrogen transformation and conversion during coal pyrolysis and combustion based on quantum chemical calculation and experimental study [J]. Chinese Journal of Chemical Engineering, 2021, 35(7): 107-123.
[2]	Chunyuan Wu, Youwei Cheng, Lijun Wang, Xi Li. Solid-liquid equilibrium of dimethyl terephthalate (DMT), dimethyl isophthalate (DMI) and dimethyl phthalate (DMP) in melt crystallization process [J]. Chin.J.Chem.Eng., 2017, 25(12): 1735-1739.
[3]	Mehdi Ardjmand, Mehrdad Mirzajanzadeh, Fatemeh Zabihi. Measurement and Correlation of Solid Drugs Solubility in Supercritical Systems [J]. Chin.J.Chem.Eng., 2014, 22(5): 549-558.
[4]	Cheng Lian, Dongyan Zhi, Shouhong Xu, Honglai Liu. A Molecular Thermodynamic Model for Restricted Swelling Behaviors of Thermo-sensitive Hydrogel [J]. , 2014, 22(11/12): 1307-1313.
[5]	ZHANG Zhenzhen, QIAN Zhi, XU Lianbin, WU Caiyan, GUO Kai . Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation [J]. Chin.J.Chem.Eng., 2013, 21(7): 770-775.
[6]	Daniel A. Beneke, Seon B. Kim, Andreas A. Linninger. Pinch Point Calculations and Its Implications on Robust Distillation Design [J]. , 2011, 19(6): 911-925.
[7]	HUANG Xueli, LI Songwan. Liquid-solid Equilibria in Quinary System Na⁺, K⁺, Mg²⁺//Cl^-, NO₃^--H₂O at 25℃ [J]. , 2011, 19(1): 101-107.
[8]	LI Yu, LIU Youzhi, ZHANG Luyao, SU Qiang, JIN Guoliang. Absorption of NO_x into Nitric Acid Solution in Rotating Packed Bed [J]. , 2010, 18(2): 244-248.
[9]	WANG Lin, HAO Xiaosong, ZHENG Lan, CHEN Kaixun. Phase Equilibrium of Isobutanol in Supercritical CO₂ [J]. , 2009, 17(4): 642-647.
[10]	JI Yuanhui, JI Xiaoyan, FENG Xin, LIU Chang, LÜ, Linghong, LU Xiaohua. Progress in the study on the phase equilibria of the CO₂-H₂O and CO₂-H₂O-NaCl systems [J]. , 2007, 15(3): 439-448.
[11]	JIWeirong. Modeling VLE and GLE of systems involving polymers by using SRK equation of state [J]. , 2007, 15(2): 221-227.
[12]	CHEN Jianmeng, CHEN Jun, Lance Hershman, WANG Jiade, Daniel P.Y.Chang. Autotrophic Biofilters for Oxidation of Nitric Oxide [J]. , 2004, 12(1): 113-117.
[13]	LIN Jinqing, LI Haoran, HAN Shijun. Elemental Composition Method in Thermodynamics of Multireaction Systems (Ⅱ) Residual Properties,Property Changes of Mixing and Excess Properties Relations [J]. , 2002, 10(4): 464-468.
[14]	ZHANG Jingchang, WU Xiangyang, CAOWeiliang. Study on Critical Properties for CO₂+Cosolvent Binary System and Ternary System [J]. , 2002, 10(2): 223-227.
[15]	ZHU Hugang, TIAN Yiling, CHEN Li, QIN Ying, FENG Jijun. High-pressure Phase Equilibria for Binary Ethanol System Containing Supercritical CO2 [J]. , 2001, 9(3): 322-325.

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments