Solubility and metastable zone width measurement of 3, 4-bis (3-nitrofurazan-4-yl) furoxan (DNTF) in ethanol+water

doi:10.1016/j.cjche.2016.08.015

Abstract

Abstract: The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan (DNTF) in ethanol+water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width (MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol+water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol+water was calculated by the relationship between the cooling rate and the MSZW.

Key words: 3,4-Bis (3-nitrofurazan-4-yl) furoxan, Solubility, Metastable zone width, Apparent nucleation order

摘要： The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan (DNTF) in ethanol+water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width (MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol+water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol+water was calculated by the relationship between the cooling rate and the MSZW.

关键词: 3,4-Bis (3-nitrofurazan-4-yl) furoxan, Solubility, Metastable zone width, Apparent nucleation order

Lizhen Chen, Liang Song, Guanchao Lan, Jianlong Wang. Solubility and metastable zone width measurement of 3, 4-bis (3-nitrofurazan-4-yl) furoxan (DNTF) in ethanol+water[J]. , 2017, 25(5): 646-651.

References

[1] H.X. Hu, G.M. Qin, Z.Z. Zhang, 3,4-Dinitrofurazanfuroxan explosive, CN Pat., 02101092, 2002.
[2] Y.S. Zhou, B.Z. Wang, J.K. Li, C. Zhou, L. Hu, Z.Q. Chen, Z.Z. Zhang, Study on synthesis, characterization and properties of 3,4-bis(4'-nitrofurazano-3'-yl)furoxan, Acta Chim. Sin. 69(2011) 1673-1680.
[3] J. Wang, H.S. Dong, Y.G. Huang, J.S. Li, Snythesis of 3,4-diaminofurazanfuroxan, Chin. J. Energy Mater. (Supplement) (2004) 91-93.
[4] Y.S. Zhou, Z.Z. Zhang, J.K. Li, X.R. Guan, X.P. Huang, C. Zhou, Crystal structure of 3, 4-dinitrofurazanofuroxan, Chin. J. Explos. Propellants 28(2005) 43-46.
[5] V.P. Sinditskii, A.V. Burzhava, A.B. Sheremetev, N.S. Aleksandrova, Thermal and combustion properties of 3,4-bis(3-nitrofurazan-4-yl)furoxan (DNTF), Propellants Explos. Pyrotech. 37(2012) 575-580.
[6] F.Q. Zhao, P. Chen, R.Z. Hu, et al., Thermochemical properties and non-isothermal decomposition reaction kinetics of 3,4-dinitrofurazanfuroxan (DNTF), J. Hazard. Mater. 113(2004) 67-71.
[7] H.X. Hu, Z.Z. Zhang, F.Q. Zhao, C. Xiao, Q.H. Wang, B.H. Yuan, A study on the properties and application of high energy density material DNTF, Acta Armamentarii 25(2004) 155-158.
[8] W. Zheng, J.N. Wang, Review on 3,4-bisnitrofurazanfuroxan (DNTF), Chin. J. Energy Mater. 14(2006) 463-466.
[9] M. Lenka, D. Sarkar, Determination of metastable zone width, induction period and primary nucleation kinetics for cooling crystallization of L-asparaginenohydrate, J. Cryst. Growth 408(2014) 85-90.
[10] X.H. Shi, C.R. Zhou, Y.G. Gao, X.Z. Chen, Measurement and correlation for solubility of (S)-(+)-2,2-dimethylcyclopropane carbox amide in different solvents, Chin. J. Chem. Eng. 14(2006) 547-550.
[11] L.Z. Chen, T.B. Zhang, M. Li, J. Li, D.L. Cao, Solubility of 2,2',4,4',6,6'-hexanitrostilbene in binary solvent of N,N-dimethylformamide and acetonitrile, J. Chem. Thermodyn. 95(2016) 99-104.
[12] J.Y. Peng, Y.P. Dong, Z. Nie, F.Z. Kong, Q.F. Meng, W. Li, Solubility and metastable zone width measurement of borax decahydrate in potassium chloride solution, J. Chem. Eng. Data 57(2012) 890-895.
[13] F.X. Zou, W. Zhuang, J.L. Wu, J.W. Zhou, P.P. Yang, Q.Y. Liu, Y. Chen, H.J. Ying, Determination of metastable zone widths and the primary nucleation and growth mechanisms for the crystallization of disodium guanosine 5'-monophosphate from a water-ethanol system, Ind. Eng. Chem. Res. 54(2015) 137-145.
[14] K.J. Cui, Z.B. Xu, L.R. Chen, M. Xue, Z.H. Meng, G.G. Xu, R. Wang, W.J. Liu, Z.H. Lin, Solubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan in common solvents at temperatures between 293.15 K and 313.15 K, J. Chem. Eng. Data 58(2013) 2677-2680.
[15] A. Apelblat, E. Manzurola, Solubilities of manganese, cadmium, mercury and lead acetates in water from T=278.15 K to T=340.15 K, J. Chem. Thermodyn. 33(2001) 147-153.
[16] L. Zhou, P.P. Zhang, G.D. Yang, R. Lin, W.R. Wang, T.T. Liu, L.Q. Zhang, J.Y. Zhang, Solubility of chrysin in ethanol and water mixtures, J. Chem. Eng. Data 59(2014) 2215-2220.
[17] J. Yu, T.L. Ma, A. Li, X.C. Chen, Y. Chen, J.J. Xie, J.L. Wu, H.J. Ying, Solubility of disodium cytidine 5'-monophosphate in different binary mixtures from 288.15 K to 313.15 K, Thermochim. Acta 565(2013) 1-7.
[18] Y.H. Hu, X. Liu, W.G. Yang, J.J. Yin, Y. Liu, M.M. Liang, Measurement and correlation of the solubility of 4-methylbenzoic acid in (methanol + acetic acid) binary solvent mixtures, J. Mol. Liq. 193(2014) 213-219.
[19] L.P. Wang, H.T. Feng, J.Y. Peng, N.J. Dong, W. Li, Y.P. Dong, Solubility, metastable zone width, and nucleation kinetics of sodium dichromate dehydrate, J. Chem. Eng. Data 60(2015) 185-191.
[20] Y.Y. Qian, G.M. Lu, Y.Z. Sun, X.F. Song, J.G. Yu, Metastable zone width of SrCl₂·6H₂O during cooling crystallization, Cryst. Res. Technol. 49(2014) 78-83.
[21] J.Y. Peng, Z. Nie, L.L. Li, L.P. Wang, Y.P. Dong, W. Li, Solubility and metastable zone width of sodium tetraborate decahydrate in a solution containing lithium chloride, J. Chem. Eng. Data 58(2013) 1288-1293.