SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (8): 1846-1850.DOI: 10.1016/j.cjche.2018.10.013

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Dual-template synthesis of HZSM-5 zeolites with tailored activity in toluene methylation with CH3Br

Wuhui Wang1, Jun Xie1, Peng Wang1, Lang Chen1, Chaktong Au1,2, Shuangfeng Yin1   

  1. 1 State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan Provincial Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China;
    2 College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China
  • Received:2018-09-04 Revised:2018-10-12 Online:2019-11-16 Published:2019-08-28
  • Contact: Lang Chen, Shuangfeng Yin
  • Supported by:
    Supported by the National Natural Science Foundation of China (21273067, 21476065, 21671062, 21725602), Program for Changjiang Scholars and Innovative Research Team in University (IRT1238), and the Fundamental Research Funds for the Central Universities.

Dual-template synthesis of HZSM-5 zeolites with tailored activity in toluene methylation with CH3Br

Wuhui Wang1, Jun Xie1, Peng Wang1, Lang Chen1, Chaktong Au1,2, Shuangfeng Yin1   

  1. 1 State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan Provincial Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China;
    2 College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China
  • 通讯作者: Lang Chen, Shuangfeng Yin
  • 基金资助:
    Supported by the National Natural Science Foundation of China (21273067, 21476065, 21671062, 21725602), Program for Changjiang Scholars and Innovative Research Team in University (IRT1238), and the Fundamental Research Funds for the Central Universities.

Abstract: Shape-selective zeolites (HZ-x/y) were synthesized by a one-pot method using TPAOH (y) and/or MeEt3N+I- (x) as templates. The use of MeEt3N+I- affects the crystal growth and the distribution of acid sites on the external surface of the zeolites. The catalysts show excellent catalytic activity towards toluene alkylation with CH3Br. With toluene conversion of 36.3% and p-xylene selectivity of 66.2%, HZ-40/0 is the most effective among the prepared catalysts, showing a p-xylene yield of 21.2%. The improved para-selectivity is mainly due to the decrease of acid sites on the external surface of the catalysts.

Key words: HZSM-5, Dual-template, Alkylation, Shape-selective, p-Xylene

摘要: Shape-selective zeolites (HZ-x/y) were synthesized by a one-pot method using TPAOH (y) and/or MeEt3N+I- (x) as templates. The use of MeEt3N+I- affects the crystal growth and the distribution of acid sites on the external surface of the zeolites. The catalysts show excellent catalytic activity towards toluene alkylation with CH3Br. With toluene conversion of 36.3% and p-xylene selectivity of 66.2%, HZ-40/0 is the most effective among the prepared catalysts, showing a p-xylene yield of 21.2%. The improved para-selectivity is mainly due to the decrease of acid sites on the external surface of the catalysts.

关键词: HZSM-5, Dual-template, Alkylation, Shape-selective, p-Xylene