Abstract: Achieving high fouling resistance and permeability using membrane separation technology in water treatment processes remains a challenge. In this work, a novel mixed-matrix membrane (MMM) (poly(arylene ether ketone) [PAEK]-containing carboxyl groups [PAEK-COOH]/UiO-66-NH₂@graphene oxide [GO]) with superb fouling resistance and high permeability was prepared by the nonsolvent-induced phase separation method, by in-situ growth of UiO-66-NH₂ on the GO layer, and by preparing hydrophilic PAEK-COOH. On the basis of the structure and performance analysis of the MMM, the maximum water flux reached 591.25 L·m^-2·h^-1 for PAEK-COOH/UiO-66-NH₂@GO, whereas the retention rate for bovine serum albumin increased from 85.40% to 94.87%. As the loading gradually increased, the hydrophilicity of the MMMs increased, significantly enhancing their fouling resistance. The strongest anti-fouling ability observed was 94.74%, which was 2.02 times greater than that of the pure membrane. At the same time, the MMMs contained internal amide and hydrogen bonds during the preparation process, forming a cross-linked structure, which further enhanced the mechanical strength and chemical stability. In summary, the MMMs with high retention rate, strong permeability, and anti-fouling ability were successfully prepared.

Key words: Poly(arylene ether ketone)-containing Carboxyl groups (PAEK-COOH), UiO-66-NH₂@graphene oxide, Hydrophilic modification, Ultra-high selectivity, Strong anti-fouling

摘要： Achieving high fouling resistance and permeability using membrane separation technology in water treatment processes remains a challenge. In this work, a novel mixed-matrix membrane (MMM) (poly(arylene ether ketone) [PAEK]-containing carboxyl groups [PAEK-COOH]/UiO-66-NH₂@graphene oxide [GO]) with superb fouling resistance and high permeability was prepared by the nonsolvent-induced phase separation method, by in-situ growth of UiO-66-NH₂ on the GO layer, and by preparing hydrophilic PAEK-COOH. On the basis of the structure and performance analysis of the MMM, the maximum water flux reached 591.25 L·m^-2·h^-1 for PAEK-COOH/UiO-66-NH₂@GO, whereas the retention rate for bovine serum albumin increased from 85.40% to 94.87%. As the loading gradually increased, the hydrophilicity of the MMMs increased, significantly enhancing their fouling resistance. The strongest anti-fouling ability observed was 94.74%, which was 2.02 times greater than that of the pure membrane. At the same time, the MMMs contained internal amide and hydrogen bonds during the preparation process, forming a cross-linked structure, which further enhanced the mechanical strength and chemical stability. In summary, the MMMs with high retention rate, strong permeability, and anti-fouling ability were successfully prepared.

关键词: Poly(arylene ether ketone)-containing Carboxyl groups (PAEK-COOH), UiO-66-NH₂@graphene oxide, Hydrophilic modification, Ultra-high selectivity, Strong anti-fouling