SCI和EI收录∣中国化工学会会刊

›› 2008, Vol. 16 ›› Issue (3): 461-464.

• SPECIAL ISSUE OF THE FIRST INTERNATIONAL SYMPOSIUM ON SUSTAINABLE CHEMICAL PRODUCT AND PROCESS ENGINEERING • Previous Articles     Next Articles

Recovery Technology of DMF from Wet Type Polyurethane Synthetic Leather Waste Gas

ZHAO Shunhua1, SONG Xijin2, PEI Ning2, ZHANG Jingzhu3, LIU Shuqing3   

  1. 1. Zhejiang Hexin Industry Group Co., Jiaxing 314003, China;
    2. Department of Chemical&Biochemical Engineering, Zhejiang University, Hangzhou 310027, China;
    3. Yantai Dongjie Environmental Protection Machine Engineering Co., Yantai 264002, China
  • Received:2007-09-22 Revised:2008-03-25 Online:2008-06-28 Published:2008-06-28
  • Supported by:
    the Science and Technology Fund of Zhejiang Province, China (2006C13072)

Recovery Technology of DMF from Wet Type Polyurethane Synthetic Leather Waste Gas

赵舜华1, 宋锡瑾2, 裴宁2, 张景铸3, 刘书庆3   

  1. 1. Zhejiang Hexin Industry Group Co., Jiaxing 314003, China;
    2. Department of Chemical&Biochemical Engineering, Zhejiang University, Hangzhou 310027, China;
    3. Yantai Dongjie Environmental Protection Machine Engineering Co., Yantai 264002, China
  • 通讯作者: SONG Xijin,E-mail:xjsong@zju.edu.cn
  • 基金资助:
    the Science and Technology Fund of Zhejiang Province, China (2006C13072)

Abstract: A new recovery technology is developed to recycle N,N-dimethyl formamide(DMF)in waste gas from wet type polyurethane synthetic leather industry.Given that the concentration of DMF in waste gas was as low as 325.6-688.3 mg·m-3,it was necessary to make sure two phases contact adequately and strengthen the mass transfer by increasing contact area and enhancing the turbulence.Therefore,two-stage countercurrent absorption and two-stage fog removing system were introduced into the technology.The top section of the absorption column was filled with structured wire-ripple stainless steel packing BX500,while the lower section with sting-ripple packing CB250Y.Total height of packing material was 6 m.In addition,there were both two-stage fog removing layer and high efficiency liquid distributor at the column top.All the operating parameters,including temperature,pressure, flow rate and liquid position,could be controlled by computers without manual operation,making sure the outlet gas achieved the national emission standard that the DMF concentration should be below 40 mg·m-3.The whole equipment could recover 237.6 t of DMF each year,with the profit up to CNY 521×103.

Key words: N,N-dimethylformamide, polyurethane synthetic leather, absorption, recovery

摘要: A new recovery technology is developed to recycle N,N-dimethyl formamide(DMF)in waste gas from wet type polyurethane synthetic leather industry.Given that the concentration of DMF in waste gas was as low as 325.6-688.3 mg·m-3,it was necessary to make sure two phases contact adequately and strengthen the mass transfer by increasing contact area and enhancing the turbulence.Therefore,two-stage countercurrent absorption and two-stage fog removing system were introduced into the technology.The top section of the absorption column was filled with structured wire-ripple stainless steel packing BX500,while the lower section with sting-ripple packing CB250Y.Total height of packing material was 6 m.In addition,there were both two-stage fog removing layer and high efficiency liquid distributor at the column top.All the operating parameters,including temperature,pressure, flow rate and liquid position,could be controlled by computers without manual operation,making sure the outlet gas achieved the national emission standard that the DMF concentration should be below 40 mg·m-3.The whole equipment could recover 237.6 t of DMF each year,with the profit up to CNY 521×103.

关键词: N,N-dimethylformamide, polyurethane synthetic leather, absorption, recovery