Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide

Chin.J.Chem.Eng. ›› 2012, Vol. 20 ›› Issue (4): 760-767.

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Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide

LU Yiyu^1,2, LIU Yong^1,2,3, XIA Binwei^1,2, ZUO Weiqin^1,2,3

1. State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing 400044, China;
2. State and Local Joint Engineering Laboratory of Methane Drainage in Complex Coal Gas Seam, Chongqing Uni-versity, Chongqing 400044, China;
3. College of Safety Science and Technology, Henan Polytechnic University, Jiaozuo 454000, China

Received:2011-06-22 Revised:2011-11-22 Online:2012-09-15 Published:2012-08-28
Supported by:
Supported by the National Natural Science Foundation of China (50921063,51104191);the Natural Science Foundationof Chongqing (2009BA6047)

Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide

卢义玉^1,2, 刘勇^1,2,3, 夏彬伟^1,2, 左伟芹^1,2,3

1. State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing 400044, China;
2. State and Local Joint Engineering Laboratory of Methane Drainage in Complex Coal Gas Seam, Chongqing Uni-versity, Chongqing 400044, China;
3. College of Safety Science and Technology, Henan Polytechnic University, Jiaozuo 454000, China

通讯作者: LIU Yong, E-mail:luyiyu@cqu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (50921063,51104191);the Natural Science Foundationof Chongqing (2009BA6047)

Abstract

Abstract: The paper presents results of phenol oxidized under the conditions of high temperature created during collapse of cavitation bubbles.The degradation efficiency has been greatly improved by using cavitation water jets combined with H₂O₂ as demonstrated in laboratory tests.Various factors affecting phenol removal ratio were examined and the degradation mechanism was revealed by high performance liquid chromatography(HPLC).The results showed that 99.85% of phenol was mineralized when phenol concentration was 100 mg·L^-1 with pH value of 3.0,H₂O₂ concentration of 300 mg·L^-1,confining pressure of 0.5 MPa,and pumping pressure of 20 MPa.The intermediate products after phenol oxidation were composed of catechol,hydroquinone and p-benzoquinone.Finally,phenol was degraded into maleic acid and acetic acid.Furthermore,a dynamic model of phenol oxidation via cavitation water jets combined with H₂O₂ has been developed.

Key words: phenol oxidation, cavitation water jet, hydrogen peroxide, wastewater treatment, correlation coefficient, removal ratio

摘要： The paper presents results of phenol oxidized under the conditions of high temperature created during collapse of cavitation bubbles.The degradation efficiency has been greatly improved by using cavitation water jets combined with H₂O₂ as demonstrated in laboratory tests.Various factors affecting phenol removal ratio were examined and the degradation mechanism was revealed by high performance liquid chromatography(HPLC).The results showed that 99.85% of phenol was mineralized when phenol concentration was 100 mg·L^-1 with pH value of 3.0,H₂O₂ concentration of 300 mg·L^-1,confining pressure of 0.5 MPa,and pumping pressure of 20 MPa.The intermediate products after phenol oxidation were composed of catechol,hydroquinone and p-benzoquinone.Finally,phenol was degraded into maleic acid and acetic acid.Furthermore,a dynamic model of phenol oxidation via cavitation water jets combined with H₂O₂ has been developed.

关键词: phenol oxidation, cavitation water jet, hydrogen peroxide, wastewater treatment, correlation coefficient, removal ratio

LU Yiyu, LIU Yong, XIA Binwei, ZUO Weiqin. Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide[J]. Chin.J.Chem.Eng., 2012, 20(4): 760-767.

卢义玉, 刘勇, 夏彬伟, 左伟芹. Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 760-767.

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Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide

Phenol Oxidation by Combined Cavitation Water Jet and Hydrogen Peroxide

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