Recovery of nickel, cobalt, copper and zinc in sulphate and chloride solutions using synergistic solvent extraction

doi:10.1016/j.cjche.2015.06.002

Abstract

Abstract: A number of synergistic solvent extraction (SSX) systems have been developed to recover nickel, cobalt, zinc and copper from sulphuric and chloride leach solutions by the solvent extraction team of CSIRO, Australia. These include (1) Versatic 10/CLX50 system for the separation of Ni from Ca in sulphate solutions, (2) Versatic 10/4PC systemfor the separation of Ni and Co fromMn/Mg/Ca in sulphate solutions, (3) Cyanex 471X/HRJ-4277 system for the separation of Zn from Cd in sulphate solutions, (4) Versatic 10/LIX63 systemfor the separation of Co from Mn/Mg/Ca in sulphate solutions, (5) Versatic 10/LIX63/TBP systemfor separation of Ni and Co fromMn/Mg/Ca in sulphate solutions, (6) Versatic 10/LIX63 systemfor the separation of cobalt fromnickel in sulphate solutions by difference in kinetics, (7) Cyanex 272/LIX84 system for the separation of Cu/Fe/Zn from Ni/Co in sulphate solutions, (8) Versatic 10/LIX63/TBP system to recover Cu/Ni from strong chloride solutions, and (9) Versatic 10/LIX63 system to separate Cu from Fe in strong chloride solutions.
The synergistic effect on metal separation and efficiency is presented and possible industrial applications are demonstrated. The chemical stability of selected SSX systems is also reported.

Key words: Synergistic solvent extraction, Nickel, Cobalt, Copper, Zinc

Chu Yong Cheng, Keith R. Barnard, Wensheng Zhang, Zhaowu Zhu, Yoko Pranolo. Recovery of nickel, cobalt, copper and zinc in sulphate and chloride solutions using synergistic solvent extraction[J]. , 2016, 24(2): 237-248.

Chu Yong Cheng, Keith R. Barnard, Wensheng Zhang, Zhaowu Zhu, Yoko Pranolo. [J]. , 2016, 24(2): 237-248.

References

[1] C.Y. Cheng, K.R. Barnard, W. Zhang, D.J. Robinson, Synergistic solvent extraction of nickel and cobalt: a literature review of recent developments, Solvent Extr. Ion Exch. 29 (2011) 719-754.
[2] C.Y. Cheng, M.G. Davies, Separation of nickel from calcium using synergistic solvent extraction, Proceedings of International Symposium of Solvent Extraction, Bhubaneswar, India, September, 2002 2002, pp. 71-88.
[3] C.Y. Cheng,M.D. Urbani, Recovery of nickel and cobalt fromleach solutions by direct solvent extraction, ALTA Nickel/Cobalt-8, Perth, May, 20022002.
[4] C.Y. Cheng, M.D. Urbani, Purification of laterite leach solutions by direct solvent extraction, Yazawa International Symposium on Metallurgical and Materials Processing: Principals and Technologies, TMS Annual Meeting, San Diego, USA, vol. 3 March 2003, pp. 251-265.
[5] C.Y. Cheng, SX application for nickel and cobalt: pros and cons of existing processes and possible future development, Proceedings of ALTA SX/IX World Summit, ALTA Metallurgical Services, Perth, Australia, May, 2003.
[6] C.Y. Cheng,M.D. Urbani, M. Houchin, Synergistic solvent extraction and its potential application to nickel and cobalt recovery, Hydrometallurgy 2003-Fifth International Conference in Honour of Professor Ian Ritchie, Leaching and Solution Purification, Vancouver, Canada, vol. 1 August 2003, pp. 787-798.
[7] C.Y. Cheng, M.D. Urbani, The recovery of nickel and cobalt from leach solutions by solvent extraction: practice, research and development, International Conference on Hydrometallurgy (ICHM) October 16-19, 2004, Xian, China, Abstracts 2004, p. 20.
[8] C.Y. Cheng, M.D. Urbani, The recovery of nickel and cobalt from leach solutions by solvent extraction: process overview, recent research and development, Proceeding of ISEC 2005, Beijing, China September 2005, pp. 503-526.
[9] C.Y. Cheng, K.R. Barnard, M.D. Urbani, Application of synergistic solvent extraction for metal recovery, ALTA Ni/Co 2005, ALTA Metallurgical Services, Perth, Australia, May 2005.
[10] C.Y. Cheng, K.R. Barnard, M.D. Urbani, Improving plant operation using synergistic SX technology and organicmonitoring, The First ExtractiveMetallurgy Operators' Conference, Brisbane, Australia November 2005, pp. 59-66 (accepted for publication).
[11] K.R. Barnard, M.G. Davies, C.Y. Cheng, Stability of the Versatic 10-decyl-4-pyridinecarboxylate system under continuous SX conditions: chemical analysis and phase disengagement studies, Hydrometallurgy 74 (2004) 47-56.
[12] D. Dreisinger, C.Y. Cheng, W. Zhang, Y. Pranolo, Development of Boleo process flowsheet and its direct solvent extraction (DSX) circuit, Proceedings of the International Mineral Processing Conference, Brisbane Australia September 2010, pp. 309-317.
[13] C.Y. Cheng, M.D. Urbani, Solvent extraction process for separation cobalt and/or manganese from impurities in leach solutions. Patent Publication No. WO 2005/ 073415 A1 (2005).
[14] C.Y. Cheng, Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime, Hydrometallurgy 84 (2006) 109-107.
[15] C.Y. Cheng,W. Zhang, Y. Pranolo, Recovery of cobalt and zinc from Boleo leach solutions using the CSIRO DSX process, ALTA Ni/Co, PerthMay 2007.
[16] C.Y. Cheng,W. Zhang, Y. Pranolo, Recovery of cobalt and zinc from Boleo leach solutions using the CSIRO DSX process, Proceedings of ISEC 2008, Solvent Extraction: Fundamentals to Industrial Applications, Tucson, USA September, 2008, pp. 163-168.
[17] C.Y. Cheng, W. Zhang, Y. Pranolo, Separation of cobalt and zinc from manganese, magnesium and calcium using synergistic solvent extraction system consisting of Versatic 10 and LIX63, Solvent Extr. Ion Exch. 28 (2010) 604-624.
[18] Anon, Boleo Pilot Plant Program at SGS Lakefield Research Successfully Completed, News release of Baja Mining Corp., Toronto, December 2004.
[19] Anon, Baja Mining Phase 2 Pilot Plant Program Successfully Completed, News release of Baja Mining Corp., Toronto, July 2006.
[20] K.R. Barnard, LIX®63 stability in the presence of Versatic 10 under proposed commercial extract and strip conditions, part I: operation at high temperature, Hydrometallurgy 91 (2008) 1-10.
[21] K.R. Barnard, N.L. Turner, LIX®63 stability in the presence of Versatic 10 under proposed commercial extract and strip conditions, part II: oxime isomer inter-conversion and the effect of oxime degradation products on selected physical properties, Hydrometallurgy 91 (2008) 11-19.
[22] K.R. Barnard, N.L. Turner, D.W. Shiers, LIX®63 stability in the presence of Versatic 10 under proposed commercial extract and strip conditions, part III: effect of manganese and cobalt loading on oxime stability at 30 ℃, Hydrometallurgy 104 (2010) 268-277.
[23] K.R. Barnard, M.N. Tsuntsaeva, Identification of four additional hydroxyoxime degradation products formed in the LIX 63/Versatic 10 synergistic system and their effect on metal selectivity, Solvent Extr. Ion Exch. 31 (1) (2013) 79-94.
[24] K.R. Barnard, N.J. Kelly, D.W. Shiers, T.M. McCoy, D.L. Jones, K.E. Mayhew, The effect of LIX 63 hydroxyoxime degradation products on kinetics-based metal extraction, Solvent Extr. Ion Exch. 32 (1) (2013) 95-110.
[25] K.R. Barnard, Current understanding of LIX®63/Versatic 10 synergistic solvent extraction system chemistry, in: F. Valenzuela L., B.A. Moyer (Eds.), Gecamin Conference for Mining, Santiago, Chile, October 2011 Chapter 7, Paper 162.
[26] C.Y. Cheng, M.D. Urbani, Solvent extraction process for separation cobalt and/or nickel from impurities in leach solutions. Patent Publication No. WO 2005/073416 A1 (2005).
[27] K.R. Barnard, M.D. Urbani, The effect of organic acids on LIX®63 stability under harsh strip conditions and isolation of a diketone degradation product, Hydrometallurgy 89 (2007) 40-51.
[28] C.Y. Cheng, G. Boddy,W. Zhang, G. Godfrey, K.R. Barnard, D.J. Robinson, Y. Pranolo, Z. Zhu, W. Zhang, L. Zeng, N.L. Turner, T.N. Hill, Separation of nickel and cobalt from manganese, magnesium and calcium by synergistic solvent extraction-from batch tests to pilot plant operation, Proceedings of the International Mineral Processing Conference, Brisbane Australia September 2010, pp. 285-297.
[29] K.R. Barnard, N.L. Turner, Hydroxyoxime stability and unusual cobalt loading behaviour in the LIX 63-Versatic 10-tributyl phosphate synergistic system under synthetic laterite conditions, Hydrometallurgy 109 (2011) 29-36.
[30] K.R. Barnard, N.L. Turner, The effect of temperature on hydroxyoxime stability in the LIX 63-Versatic 10-tributyl phosphate synergistic solvent extraction system under synthetic nickel laterite conditions, Hydrometallurgy 109 (2011) 245-251.
[31] N.L. Turner, K.R. Barnard, The effect of individual complexed metals on hydroxyoxime stability in the LIX 63-Versatic 10-tributyl phosphate synergistic solvent extraction system under synthetic nickel laterite extract conditions, Hydrometallurgy 117-118 (2012) 79-85.
[32] C.Y. Cheng, G. Boddy,W. Zhang, M. Godfrey, D.J. Robinson, Y. Pranolo, Z. Zhu, L. Zeng, W. Wang, Direct solvent extraction for recovery of nickel and cobalt from Rio Tinto laterite leach solutions, Proceedings of International Symposium, Hydrometallurgy of Nickel and Cobalt 2009, Canada 2009, pp. 243-254.
[33] C.Y. Cheng, G. Boddy, W. Zhang, M. Godfrey, D.J. Robinson, Y. Pranolo, Z. Zhu, W. Wang, L. Zeng, A DSX process for Ni and Co recovery from Rio Tinto laterite leach solutions using SSX technology-from batch tests to pilot plant operation, ALTA Nickel/Cobalt, Perth AustraliaMay 2009.
[34] C.Y. Cheng, G. Boddy, W. Zhang, M. Godfrey, D.J. Robinson, Y. Pranolo, Z. Zhu, W. Wang, Recovery of nickel and cobalt from laterite leach solutions using direct solvent extraction: part 1-selection of a synergistic SX system, Hydrometallurgy 104 (2010) 45-52.
[35] C.Y. Cheng, G. Boddy,W. Zhang, M. Godfrey, D.J. Robinson, Y. Pranolo, Z. Zhu, L. Zeng, W. Wang, Recovery of nickel and cobalt from laterite leach solutions using direct solvent extraction: part 2-semi-and fully-continuous tests, Hydrometallurgy 104 (2010) 53-60.
[36] Anon, Cyanex 272 Extractant, Cytec Industries Inc., 2007
[37] K.E. Mayhew, T.M. McCoy, D.L. Jones, K.R. Barnard, C.Y. Cheng, W. Zhang, D.J. Robinson, Kinetic separation of Co from Ni, Mg, Mn and Ca via synergistic solvent extraction, Solvent Extr. Ion Exch. 29 (2010) 755-781.
[38] T.M. McCoy, K.E. Mayhew, D.L. Jones, K.R. Barnard, C.Y. Cheng, D.J. Robinson, W. Zhang, Separation of Co from Ni in an impure sulphate solution, part 1-extraction, in: F. Valenzuela L., B.A. Moyer (Eds.), Gecamin Conference for Mining, Santiago, Chile, October 2011 Chapter 2, Paper 56.
[39] T.M. McCoy, K.E. Mayhew, D.L. Jones, K.R. Barnard, C.Y. Cheng, D.J. Robinson, W. Zhang, Separation of Co from Ni in an impure sulphate solution, part 2-stripping, in: F. Valenzuela L., B.A. Moyer (Eds.), Gecamin Conference for Mining, Santiago, Chile, October 2011 Chapter 2, Paper 57.
[40] C.Y. Cheng, M. Rodriguez, Upgrading cobalt product using synergistic solvent extraction technology atMurrin Murrin Operation ofMinara Resources, ALTA Ni/Co, Perth, AustraliaMay 2006.
[41] C.Y. Cheng,W. Zhang,M. Rodriguez, Separation of Copper, Iron and Zinc fromCobalt and Nickel in Minara Process Liquor by Synergistic Solvent Extraction: Pilot Plant Operation, ALTA Ni/Co, Perth, May, 2007.
[42] C.Y. Cheng,W. Zhang, Purification, separation and recovery of metals by synergistic solvent extraction, Proceedings of EMC, Dusseldorf, Germany, June 11-14 2007.
[43] W. Zhang, C.Y. Cheng, M. Rodriguez, Y. Pranolo, Separation of copper, iron and zinc from cobalt and nickel with mixed Cyanex 272 and LIX84 extractants, Proceedings of ISEC 2008, Solvent Extraction: Fundamentals to Industrial Applications, Tucson, USA September 2008, pp. 177-182.
[44] D. Moradkhani, M.D. Urbani, C.Y. Cheng, The separation of cadmium from zinc with a novel synergistic mixture of nonylsalicylic acid and tri-isobutylphosphine sulphide, Hydrometallurgy 78 (2005) 129-136.
[45] C.Y. Cheng, D.Moradkhani,M.D. Urbani, M. Askari, D. Bastani, The separation of cadmium from zinc with a novel synergistic system and the synergistic mechanism interpreted by a new slope analysis method, Proceeding of ISEC 2005, Beijing, China September 2005, pp. 527-539.
[46] C.Y. Cheng, W. Zhang, D. Moradkhani, The recovery of metals from leach solutions by synergistic solvent extraction, HydroProcess Conference, Iquique, Chile October 2006, pp. 3-16.
[47] C.Y. Cheng, Z. Zhu, W. Zhang, A novel synergistic solvent extraction system for separating copper from iron in strong chloride solutions and transferring it into sulphate solutions for recovery, ALTA Ni/Co/Cu Conference, Perth, Australia, ALTA Metallurgical Service, May 28-30 2010.
[48] Z. Zhu, W. Zhang, C.Y. Cheng, A novel synergistic solvent extraction system for separating copper from iron in strong chloride solutions and transferring it into sulphate solutions for recovery, Hydrometallurgy 113-134 (2011) 155-159.
[49] C.Y. Cheng, Z. Zhu, W. Zhang, A DSX Process to Recover Copper, Nickel, Cobalt and Zinc from Chloride Solutions by Synergistic Solvent Extraction, ALTA Copper, Perth Australia, ALTA Metallurgical Service, May 2009.
[50] Z. Zhu, C.Y. Cheng, W. Zhang, A novel synergistic solvent extraction process for the recovery of copper, nickel, cobalt and zinc from chloride solutions, in: F. Valenzuela L., B.A. Moyer (Eds.),Gecamin Conference for Mining, Santiago, Chile, October 2011, Chapter 7, Paper 169, October 2011.
[51] Z. Zhu, W. Zhang, Y. Pranolo, C.Y. Cheng, Separation and recovery of copper, nickel, cobalt and zinc in chloride solutions by synergistic solvent extraction, Hydrometallurgy 127-128 (2012) 1-7.