Supported ionic liquid sorbents for CO2 capture from simulated flue-gas

doi:10.1016/j.cjche.2018.04.025

Abstract

Abstract: Supported ionic liquid (IL) sorbents for CO₂ capture were prepared by impregnating tetramethylammonium glycinate ([N₁₁₁₁] [Gly]) into four types of porous materials in this study. The CO₂ adsorption behavior was investigated in a thermogravimetric analyzer (TGA). Among them, poly(methyl methacrylate) (PMMA)-[N₁₁₁₁] [Gly] exhibits the best CO₂ adsorption properties in terms of adsorption capacity and rate. The CO₂ adsorption capacity reaches up to 2.14 mmol·g^-1 sorbent at 35℃. The fast CO₂ adsorption rate of PMMA-[N₁₁₁₁] [Gly] allows 60 min of adsorption equilibrium time at 35℃ and much shorter time of 4 min is achieved at 75℃. Further, Avrami's fractional-order kinetic model was used and fitted well with the experiment data, which shows good consistency between experimental results and theoretical model. In addition, PMMA-[N₁₁₁₁] [Gly] remained excellent durability in the continuous adsorption-desorption cycling test. Therefore, this stable PMMA-[N₁₁₁₁] [Gly] sorbent has great potential to be used for fast CO₂ adsorption from flue-gas.

Key words: CO₂ adsorption, Amino acid ionic liquid, Supported ionic liquid sorbent, Adsorption kinetics

摘要： Supported ionic liquid (IL) sorbents for CO₂ capture were prepared by impregnating tetramethylammonium glycinate ([N₁₁₁₁] [Gly]) into four types of porous materials in this study. The CO₂ adsorption behavior was investigated in a thermogravimetric analyzer (TGA). Among them, poly(methyl methacrylate) (PMMA)-[N₁₁₁₁] [Gly] exhibits the best CO₂ adsorption properties in terms of adsorption capacity and rate. The CO₂ adsorption capacity reaches up to 2.14 mmol·g^-1 sorbent at 35℃. The fast CO₂ adsorption rate of PMMA-[N₁₁₁₁] [Gly] allows 60 min of adsorption equilibrium time at 35℃ and much shorter time of 4 min is achieved at 75℃. Further, Avrami's fractional-order kinetic model was used and fitted well with the experiment data, which shows good consistency between experimental results and theoretical model. In addition, PMMA-[N₁₁₁₁] [Gly] remained excellent durability in the continuous adsorption-desorption cycling test. Therefore, this stable PMMA-[N₁₁₁₁] [Gly] sorbent has great potential to be used for fast CO₂ adsorption from flue-gas.

关键词: CO₂ adsorption, Amino acid ionic liquid, Supported ionic liquid sorbent, Adsorption kinetics

Jiajia Ren, Zheng Li, Yifeng Chen, Zhuhong Yang, Xiaohua Lu. Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas[J]. Chin.J.Chem.Eng., 2018, 26(11): 2377-2384.

Jiajia Ren, Zheng Li, Yifeng Chen, Zhuhong Yang, Xiaohua Lu. Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas[J]. Chinese Journal of Chemical Engineering, 2018, 26(11): 2377-2384.

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Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas

Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas

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