Preparation of hybridizing zeolitic imidazolate frameworks with carboxymethylcellulose for adsorption separation of n-hexane/3-methylpentane

doi:10.1016/j.cjche.2020.05.023

Chinese Journal of Chemical Engineering ›› 2021, Vol. 29 ›› Issue (1): 103-109.DOI: 10.1016/j.cjche.2020.05.023

• Separation Science and Engineering • Previous Articles Next Articles

Preparation of hybridizing zeolitic imidazolate frameworks with carboxymethylcellulose for adsorption separation of n-hexane/3-methylpentane

Xiujuan Li, Le Chen, Dandan Zhu, Song Yang, Zhong Wu, Mingyang He, Zhihui Zhang, Qun Chen

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, China

Received:2020-03-08 Revised:2020-05-10 Online:2021-04-02 Published:2021-01-28
Contact: Le Chen, Zhihui Zhang
Supported by:
This research was supported by the National Natural Science Foundation of China (Nos. 11775037 and 21676030), the Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology (BM212110), and The Postgraduate Innovation Project of Changzhou University (KYCX19_1782).

Preparation of hybridizing zeolitic imidazolate frameworks with carboxymethylcellulose for adsorption separation of n-hexane/3-methylpentane

Xiujuan Li, Le Chen, Dandan Zhu, Song Yang, Zhong Wu, Mingyang He, Zhihui Zhang, Qun Chen

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, China

通讯作者: Le Chen, Zhihui Zhang
基金资助:
This research was supported by the National Natural Science Foundation of China (Nos. 11775037 and 21676030), the Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology (BM212110), and The Postgraduate Innovation Project of Changzhou University (KYCX19_1782).

Abstract

Abstract: A novel ZIF-8-CMC hybrid material was fabricated from the hybridization of ZIF-8 and carboxymethylcellulose (CMC) by impregnation method for n-hexane/3-methylpentane separation. The surface properties of ZIF-8 were tailored by introducing CMC into ZIF-8 nanoparticles. In this work, adsorption separation of n-hexane (nHEX) and 3-methylpentane (3MP) on ZIF-8-CMC were investigated by batch vapor-phase adsorption and liquid-phase breakthrough adsorption. The adsorption selectivity of nHEX/3MP reversed from preferable adsorption of nHEX to preferable adsorption of 3MP upon the increasing of CMC containing in the hybrid materials. As the temperature increases, the adsorption amounts of nHEX and 3MP decrease. With the increasing of CMC contents, the nHEX uptake decreased, the uptake capacity of 3MP increased gradually. For liquid-phase breakthrough adsorption, the dynamic adsorption capacity of nHEX also decreased with the increasing of temperature.

Key words: Zeolitic imidazolate frameworks, Carboxymethylcellulose (CMC), n-Hexane, Adsorption separation

摘要： A novel ZIF-8-CMC hybrid material was fabricated from the hybridization of ZIF-8 and carboxymethylcellulose (CMC) by impregnation method for n-hexane/3-methylpentane separation. The surface properties of ZIF-8 were tailored by introducing CMC into ZIF-8 nanoparticles. In this work, adsorption separation of n-hexane (nHEX) and 3-methylpentane (3MP) on ZIF-8-CMC were investigated by batch vapor-phase adsorption and liquid-phase breakthrough adsorption. The adsorption selectivity of nHEX/3MP reversed from preferable adsorption of nHEX to preferable adsorption of 3MP upon the increasing of CMC containing in the hybrid materials. As the temperature increases, the adsorption amounts of nHEX and 3MP decrease. With the increasing of CMC contents, the nHEX uptake decreased, the uptake capacity of 3MP increased gradually. For liquid-phase breakthrough adsorption, the dynamic adsorption capacity of nHEX also decreased with the increasing of temperature.

关键词: Zeolitic imidazolate frameworks, Carboxymethylcellulose (CMC), n-Hexane, Adsorption separation

Xiujuan Li, Le Chen, Dandan Zhu, Song Yang, Zhong Wu, Mingyang He, Zhihui Zhang, Qun Chen. Preparation of hybridizing zeolitic imidazolate frameworks with carboxymethylcellulose for adsorption separation of n-hexane/3-methylpentane[J]. Chinese Journal of Chemical Engineering, 2021, 29(1): 103-109.

References

[1] T.V. Cheshkova, V.P. Sergun, E.Y. Kovalenko, N.N. Gerasimova, T.A. Sagachenko, R.S. Min, Resins and asphaltenes of light and heavy oils:their composition and structure, Energy Fuel 33(2019) 7971-7982.
[2] X. Cheng, H. Lu, Z. Lu, Enantioselective benzylic C-H arylation via photoredox and nickel dual catalysis, Nat. Commun. 10(2019) 3549.
[3] D. Niu, P.H. Willoughby, B.P. Woods, B. Baire, T.R. Hoye, Alkane desaturation by concerted double hydrogen atom transfer to benzyne, Nature 501(2013) 531-534.
[4] S. Sommer, T. Melin, J.L. Falconer, R.D. Noble, Transport of C₆ isomers through ZSM-5 zeolite membranes, J. Membr. Sci. 224(2003) 51-67.
[5] M.L. Maloncy, L. Gora, J.C. Jansen, T. Maschmeyer, Conceptual processes for zeolite membrane based hydroisomerization of light alkanes, Ars Separatoria Acta 2(2003) 18-28.
[6] R. Krishna, B. Smit, T.J.H. Vlugt, Sorption-induced diffusion-selective separation of hydrocarbon isomers using silicalite, J. Phys. Chem. A 102(1998) 7727-7730.
[7] P.S. Bárcia, J.A.C. Silva, A.E. Rodrigues, Separation by fixed-bed adsorption of hexane isomers in zeolite BETA pellets, Ind. Eng. Chem. Res. 45(2006) 4316-4328.
[8] P.S. Barcia, J.A.C. Silva, A.E. Rodrigues, Multicomponent sorption of hexane isomers in zeolite BETA, AIChE J. 53(2007) 1970-1981.
[9] P.S. Bárcia, F. Zapata, J.A.C. Silva, A.E. Rodrigues, B. Chen, Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework, J. Phys. Chem. B 111(2007) 6101-6103.
[10] K. Shams, S.J. Mirmohammadi, Preparation of 5A zeolite monolith granular extrudates using kaolin:Investigation of the effect of binder on sieving/adsorption properties using a mixture of linear and branched paraffin hydrocarbons, Microporous Mesoporous Mater. 106(2007) 268-277.
[11] P.S. Barcia, D. Guimaraes, P.A.P. Mendes, J.A.C. Silva, V. Guillerm, H. Chevreau, C. Serre, A.E. Rodrigues, Reverse shape selectivity in the adsorption of hexane and xylene isomers in MOF UiO-66, Microporous Mesoporous Mater. 139(2011) 67-73.
[12] D. Peralta, G. Chaplais, A. Simon-Masseron, K. Barthelet, G.D. Pirngruber, Separation of C₆ paraffins using zeolitic imidazolate frameworks:Comparison with zeolite 5A, Ind. Eng. Chem. Res. 51(2012) 4692-4702.
[13] Z.R. Herm, B.M. Wiers, J.A. Mason, J.M. van Baten, M.R. Hudson, P. Zajdel, C.M. Brown, N. Masciocchi, R. Krishna, J.R. Long, Separation of hexane isomers in a metal-organic framework with triangular channels, Science 340(2013) 960-964.
[14] T.B. Reed, D.W. Breck, Crystalline zeolites. Ⅱ. Crystal structure of synthetic zeolite, type A, J. Am. Chem. Soc. 78(1956) 5972-5977.
[15] P.A.P. Mendes, A.E. Rodrigues, P. Horcajada, C. Serre, J.A.C. Silva, Single and multicomponent adsorption of hexane isomers in the microporous ZIF-8, Microporous Mesoporous Mater. 194(2014) 146-156.
[16] T.C. Holcombe, Total isomerization process, US Pat., 4210771(1980).
[17] A. Minkkinen, L. Mank, S. Jullian, Process for the isomerization of C₅/C₆ normal paraffins with recycling of normal paraffins, US Pat., 5233120(1993).
[18] J.A.C. Silva, A.E. Rodrigues, Equilibrium and kinetics of n-hexane sorption in pellets of 5A zeolite, AIChE J. 43(1997) 2524-2534.
[19] D. O'Nolan, A. Kumar, M.J. Zaworotko, Water vapor sorption in hybrid pillared square grid materials, J. Am. Chem. Soc. 139(2017) 8508-8513.
[20] B. Li, Y. Zhang, D. Ma, Z. Shi, S. Ma, Mercury nano-trap for effective and efficient removal of mercury(Ⅱ) from aqueous solution, Nat. Commun. 5(2014) 5537.
[21] Q. Sun, H. He, W. Gao, B. Aguila, L. Wojtas, Z. Dai, J. Li, Y. Chen, F. Xiao, S. Ma, Imparting amphiphobicity on single-crystalline porous materials, Nat. Commun. 7(2016) 13300.
[22] J. Zhang, Y. Zhang, J. Lin, X. Chen, Metal azolate frameworks:from crystal engineering to functional materials, Chem. Rev. 112(2012) 1001-1033.
[23] J. Li, X. Yu, M. Xu, W. Liu, E. Sandraz, H. Lan, J. Wang, S.M. Cohen, Metal-organic frameworks as micromotors with tunable engines and brakes, J. Am. Chem. Soc. 139(2017) 611-614.
[24] K.S. Park, Z. Ni, A.P. Côté, J.Y. Choi, R. Huang, F.J. Uribe-Romo, H.K. Chae, M. O'Keeffe, O.M. Yaghi, Exceptional chemical and thermal stability of zeolitic imidazolate frameworks, Proc. Natl. Acad. Sci. 103(2006) 10186-10191.
[25] N. Chang, Z.-Y. Gu, X.-P. Yan, Zeolitic imidazolate framework-8 nanocrystal coated capillary for molecular sieving of branched alkanes from linear alkanes along with high-resolution chromatographic separation of linear alkanes, J. Am. Chem. Soc. 132(2010) 13645-13647.
[26] Y. Chen, X. Huang, S. Zhang, S. Li, S. Cao, X. Pei, J. Zhou, X. Feng, B. Wang, Shaping of metal-organic frameworks:from fluid to shaped bodies and robust foams, J. Am. Chem. Soc. 138(2016) 10810-10813.
[27] L. Chen, S. Yuan, J. Qian, W. Fan, M. He, Q. Chen, Z. Zhang, Effective adsorption separation of n-hexane/2-methylpentane in facilely synthesized zeolitic imidazolate frameworks ZIF-8 and ZIF-69, Ind. Eng. Chem. Res. 55(2016) 10751-10757.
[28] X. Cao, J. Liu, B. Shen, H. Sun, Adsorption of normal paraffins from naphtha using 5A molecular sieves in a double-column fixed-bed, Pet. Process. Petrochem. 44(2013) 45-50.
[29] D. Peralta, G. Chaplais, A. Simon-Masseron, K. Barthelet, G.D. Pirngruber, Separation of C-6 paraffins using zeolitic imidazolate frameworks:Comparison with zeolite 5A, Ind. Eng. Chem. Res. 51(2012) 4692-4702.
[30] P. Xu, L. Chen, J. Zhong, M. He, Q. Chen, C. Yao, Synthesis of concave soil base 5A molecular sieve and adsorption separation of normal alkanes, Petrochem. Technol. 46(2017) 1150-1155.
[31] H. Wang, J. Li, Microporous metal-organic frameworks for adsorptive separation of C5-C6 alkane isomers, Acc. Chem. Res. 52(2019) 1968-1978.
[32] A. Henrique, A.E. Rodrigues, J.A.C. Silva, Separation of hexane isomers in ZIF-8 by fixed bed adsorption, Ind. Eng. Chem. Res. 58(2019) 378-394.
[33] A.F.P. Ferreira, M.C. Mittelmeijer-Hazeleger, M.A. Granato, V.F.D. Martins, A.E. Rodrigues, G. Rothenberg, Sieving di-branched from mono-branched and linear alkanes using ZIF-8:Experimental proof and theoretical explanation, Phys. Chem. Chem. Phys. 15(2013) 8795-8804.

Preparation of hybridizing zeolitic imidazolate frameworks with carboxymethylcellulose for adsorption separation of n-hexane/3-methylpentane

Preparation of hybridizing zeolitic imidazolate frameworks with carboxymethylcellulose for adsorption separation of n-hexane/3-methylpentane

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