Measurement and correlation of the solubility of sodium acetate in eight pure and binary solvents

doi:10.1016/j.cjche.2021.06.029

Abstract

Abstract: The knowledge of solubility of a salt in either the pure solvent or blend solvent is of great importance for studying or operating the crystallization, extraction, and distillation processes. The solubility of sodium acetate (NaAc) in four pure solvents (water, ethanol, acetic acid and 2,2,2-trifluoroethanol) and four binary solvents (water–ethanol, water-acetic acid, acetic acid–ethanol, and acetic acid-ethyl acetate) were measured by using the laser dynamic method at temperatures from 288.15 K to 338.15 K at 0.1 MPa. The results showed that the solubility of NaAc was influenced by either the solution temperature or solvent composition. The aqueous sodium acetate solution possessed the maximal solubility under the experimental conditions. The solubility of NaAc in 2,2,2-trifluoroethanol was found to be decreased with the increase of the solution temperature. While, the solubilities of NaAc in other seven solvents increased as the solution temperature was elevated. Besides, five correlation models, including the van't Hoff model, modified Apelblat model, Yaws model, λh model, and modified Apelblat-Jouyban-Acree model were used to correlate the solubility data of those sodium acetate solutions with acceptable deviation, respectively. Finally, van't Hoff analysis method was selected to analyze the change law of thermodynamic properties of a salt during the dissolution process.

Key words: Solubility, Sodium acetate, Solution, Water, Solvent

摘要： The knowledge of solubility of a salt in either the pure solvent or blend solvent is of great importance for studying or operating the crystallization, extraction, and distillation processes. The solubility of sodium acetate (NaAc) in four pure solvents (water, ethanol, acetic acid and 2,2,2-trifluoroethanol) and four binary solvents (water–ethanol, water-acetic acid, acetic acid–ethanol, and acetic acid-ethyl acetate) were measured by using the laser dynamic method at temperatures from 288.15 K to 338.15 K at 0.1 MPa. The results showed that the solubility of NaAc was influenced by either the solution temperature or solvent composition. The aqueous sodium acetate solution possessed the maximal solubility under the experimental conditions. The solubility of NaAc in 2,2,2-trifluoroethanol was found to be decreased with the increase of the solution temperature. While, the solubilities of NaAc in other seven solvents increased as the solution temperature was elevated. Besides, five correlation models, including the van't Hoff model, modified Apelblat model, Yaws model, λh model, and modified Apelblat-Jouyban-Acree model were used to correlate the solubility data of those sodium acetate solutions with acceptable deviation, respectively. Finally, van't Hoff analysis method was selected to analyze the change law of thermodynamic properties of a salt during the dissolution process.

关键词: Solubility, Sodium acetate, Solution, Water, Solvent

Xi Wu, Shuaishuai Yang, Shiming Xu, Xinjie Zhang, Yujie Ren. Measurement and correlation of the solubility of sodium acetate in eight pure and binary solvents[J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 474-484.

Xi Wu, Shuaishuai Yang, Shiming Xu, Xinjie Zhang, Yujie Ren. Measurement and correlation of the solubility of sodium acetate in eight pure and binary solvents[J]. 中国化学工程学报, 2022, 44(4): 474-484.

References

[1] X. Zheng, K. Chen, Z. Lin, Synthesis and characterization of alginate-silica gel composites for adsorption dehumidification, Ind. Eng. Chem. Res. 59 (13) (2020) 5760-5767
[2] M.Y. Li, D. Constantinescu, L.S. Wang, A. Mohs, J. Gmehling, Solubilities of NaCl, KCl, LiCl, and LiBr in methanol, ethanol, acetone, and mixed solvents and correlation using the liquac model, Ind. Eng. Chem. Res. 49 (10) (2010) 4981-4988
[3] X. Wu, S.M. Xu, D.B. Wu, H. Liu, Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2, 2, 2-trifluoroethanol, 2-propanol and their binary blends, Chin. J. Chem. Eng. (2018) 26(12)2581-2591
[4] X. Wu, Y. Gong, S.M. Xu, Z.T. Yan, X.J. Zhang, S.S. Yang, Electrical conductivity of lithium chloride, lithium bromide, and lithium iodide electrolytes in methanol, water, and their binary mixtures, J. Chem. Eng. Data 64 (10) (2019) 4319-4329
[5] M. Micari, M. Bevacqua, A. Cipollina, A. Tamburini, W. van Baak, T. Putts, G. Micale, Effect of different aqueous solutions of pure salts and salt mixtures in reverse electrodialysis systems for closed-loop applications, J. Membr. Sci. 551 (2018) 315-325
[6] Y.D. Raka, H. Karoliussen, K.M. Lien, O.S. Burheim, Opportunities and challenges for thermally driven hydrogen production using reverse electrodialysis system, Int. J. Hydrog. Energy 45 (2) (2020) 1212-1225
[7] S.M. Xu, Z.Q. Liu, X. Wu, Y.W. Zhang, J.Y. Hu, D.B. Wu, Q. Leng, D.X. Jin, P. Wang, Experimental study on the hydrogen production with RED reactor powered by concentration gradient energy, CIESC Journal. 71 (2020) 2283-2291 (in Chinese)
[8] X. Luo, X.X. Cao, Y.H. Mo, K. Xiao, X.Y. Zhang, P. Liang, X. Huang, Power generation by coupling reverse electrodialysis and ammonium bicarbonate:Implication for recovery of waste heat, Electrochem. Commun. 19 (2012) 25-28
[9] R. Long, B. de Li, Z.C. Liu, W. Liu, Hybrid membrane distillation-reverse electrodialysis electricity generation system to harvest low-grade thermal energy, J. Membr. Sci. 525 (2017) 107-115
[10] F. Giacalone, C. Olkis, G. Santori, A. Cipollina, S. Brandani, G. Micale, Novel solutions for closed-loop reverse electrodialysis:Thermodynamic characterisation and perspective analysis, Energy 166 (2019) 674-689
[11] Wu X., Xu S.M., Wu D.B., Ternary working fluids for a heat-power conversion system with reverse electrodialysis method, CN Pat. CN105810985A (2016).
[12] X.P. Zhu, W.H. He, B.E. Logan, Influence of solution concentration and salt types on the performance of reverse electrodialysis cells, J. Membr. Sci. 494 (2015) 154-160
[13] A. Tamburini, M. Tedesco, A. Cipollina, G. Micale, M. Ciofalo, M. Papapetrou, W. van Baak, A. Piacentino, Reverse electrodialysis heat engine for sustainable power production, Appl. Energy 206 (2017) 1334-1353
[14] X. Wu, S.M. Xu, D.B. Wu, H. Liu, Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2, 2, 2-trifluoroethanol, 2-propanol and their binary blends, Chin. J. Chem. Eng. 26 (12) (2018) 2581-2591
[15] E.W. Lemmon, I.H. Bell., M.L. Huber, M.O. Lclinden, Reference Fluid Thermodynamic and Transport Properties (REFPROP). NIST Standard Reference Database 23, 2018.
[16] X. Wu, X.J. Zhang, S.M. Xu, Z.T. Yan, Y. Gong, Electrical conductivity of solutions consist of NaAc and organic solvents (methanol, ethylene glycol and 2,2,2-trifluoroethanl), Journal of Thermal Science and Technology. 18 (2019) 340-344. (in Chinese)
[17] J. Soleymani, E. Kenndler, W.E. Acree Jr, A. Jouyban, Solubility of sodium acetate in ternary mixtures of methanol, 1-propanol, acetonitrile, and water at 298.2 K, J. Chem. Eng. Data 59 (8) (2014) 2670-2676
[18] J. Soleymani, M. Zamani-Kalajahi, B. Ghasemi, E. Kenndler, A. Jouyban, Solubility of sodium acetate in binary mixtures of methanol, 1-propanol, acetonitrile, and water at 298.2 K, J. Chem. Eng. Data 58 (12) (2013) 3399-3404
[19] B.W. Long, D. Zhao, W. Liu, Thermodynamics studies on the solubility of inorganic salt in organic solvents:Application to KI in organic solvents and water-ethanol mixtures, Ind. Eng. Chem. Res. 51 (28) (2012) 9456-9467
[20] P.B. Lian, Q. Liu, L.Z. Chen, C. Cao, J.X. Zhao, J.L. Wang, Determination and correlation solubility of 4-nitroimidazole in twelve pure solvents from 278.15 K to 323.15 K, Chin. J. Chem. Eng. 28 (10) (2020) 2634-2639
[21] P.S. Zhang, C. Zhang, R. Zhao, Y.M. Wan, Z.K. Yang, R.Y. He, Q.L. Chen, T. Li, B.Z. Ren, Measurement and correlation of the solubility of florfenicol form A in several pure and binary solvents, J. Chem. Eng. Data. 63 (2018) 2046-2055
[22] G.T. Hefter, R.P.T. Tomkins, The Experimental determination of solubilities, in:Roger Cohen-Adad, Marie-Thérèse Cohen-Adad (Eds.), Solubility of Solids in Liquids (Chapter 4.1), John Wiley & Sons, Ltd., 2003, pp. 259-264.
[23] X.H. Chen, Z.X. Zeng, W.L. Xue, T. Pu, Solubility of 2, 6-diaminopyridine in toluene, o-xylene, ethylbenzene, methanol, ethanol, 2-propanol, and sodium hydroxide solutions, J. Chem. Eng. Data 52 (5) (2007) 1911-1915
[24] X.H. Chen, Z.X. Zeng, W.L. Xue, T. Pu, Solubility of 2, 6-diaminopyridine in toluene, o-xylene, ethylbenzene, methanol, ethanol, 2-propanol, and sodium hydroxide solutions, J. Chem. Eng. Data 52 (5) (2007) 1911-1915
[25] H. Stephen, T. Stephen, Solubilities of Inorganic and Organic Compounds, Pergamon Press, Oxford, England, 1979
[26] J. Dorn, M. Steiger, Measurement and calculation of solubilities in the ternary system NaCH₃COO + NaCl + H₂O from 278 K to 323 K, J. Chem. Eng. Data 52 (5) (2007) 1784-1790
[27] A. Apelblat, E. Manzurola, The vapour pressures over saturated aqueous solutions of sodium and potassium acetates, chlorates, and perchlorates, J. Chem. Thermodyn. 39 (8) (2007) 1176-1181
[28] J. Neuhaus, E. Von Harbou, H. Hasse, Physico-Chemical Properties of LiFSI Solutions I. LiFSI with Valeronitrile, Dichloromethane, 1,2-Dichloroethane, and 1,2-Dichlorobenzene, J. Chem. Eng. Data. 64 (2019) 868-877
[29] S. Wang, Y.Y. Zhang, J.D. Wang, Solubility measurement and modeling for betaine in different pure solvents, J. Chem. Eng. Data 59 (8) (2014) 2511-2516
[30] E. Manzurola, A. Apelblat, Solubilities of l-glutamic acid, 3-nitrobenzoic acid, p-toluic acid, calcium-l-lactate, calcium gluconate, magnesium-dl-aspartate, and magnesium-l-lactate in water, J. Chem. Thermodyn. 34 (7) (2002) 1127-1136
[31] A. Apelblat, E. Manzurola, Solubilities ofL-aspartic, DL-aspartic, DL-glutamic, p-hydroxybenzoic, o-anisic, p-anisic, and itaconic acids in water fromT=278 K toT=345 K, J. Chem. Thermodyn. 29 (12) (1997) 1527-1533
[32] X.H. Chen, Z.X. Zeng, W.L. Xue, T. Pu, Solubility of 2, 6-diaminopyridine in toluene, o-xylene, ethylbenzene, methanol, ethanol, 2-propanol, and sodium hydroxide solutions, J. Chem. Eng. Data 52 (5) (2007) 1911-1915
[33] P.S. Ma, M.M. Chen, Solid-liquid equilibrium of terephthalic acid in several solvents, Chin. J. Chem. Eng. 11 (2003) 334-337
[34] L.Z. Chen, L. Song, Y.P. Gao, A.P. Zhu, D.L. Cao, Experimental determination of solubilities and supersolubilities of 2, 2', 4, 4', 6, 6'-hexanitrostilbene in different organic solvents, Chin. J. Chem. Eng. 25 (6) (2017) 809-814
[35] J. Wang, A.L. Xu, R.J. Xu, Solubility of 2-nitro-p-phenylenediamine in nine pure solvents and mixture of (methanol + N-methyl-2-pyrrolidone) from T=(283.15 to 318.15) K:Determination and modelling, J. Chem. Thermodyn. 108 (2017) 45-58
[36] S.N. Mirheydari, M. Barzegar-Jalali, W.E. Acree, H. Shekaari, A. Shayanfar, A. Jouyban, Comparison of the models for correlation of drug solubility in Ethanol + Water binary mixtures, J. Solut. Chem. 48 (7) (2019) 1079-1104
[37] P.B. Lian, H.P. Zhao, J.L. Wang, L.Z. Chen, Y. Xiang, Q.H. Ren, Determination and correlation solubility of m-phenylenediamine in (methanol, ethanol, acetonitrile and water) and their binary solvents from 278.15 K to 313.15 K, Chin. J. Chem. Eng. 27 (5) (2019) 1149-1158
[38] R. S. Treptow, Le Châtelier's principle applied to the temperature dependence of solubility,J. Chem. Educ. 61 (1984) 499-502
[39] R.Y. Li, H. Yan, Z. Wang, J.B. Gong, Correlation of solubility and prediction of the mixing properties of ginsenoside compound K in various solvents, Ind. Eng. Chem. Res. 51 (23) (2012) 8141-8148
[40] C.H. Gu, H. Li, R.B. Gandhi, K. Raghavan, Grouping solvents by statistical analysis of solvent property parameters:Implication to polymorph screening, Int J Pharm 283 (1-2) (2004) 117-125
[41] P. Winget, D.M. Dolney, D.J. Giesen, C.J. Cramer, D.G. Truhlar, Minnesota solvent descriptor database, Dept. of Chemistry and Supercomputer Inst., University of Minnesota, Minneapolis, MN 55455-0431, 1999
[42] R. Chitra, P.E. Smith, Properties of 2, 2, 2-trifluoroethanol and water mixtures, J. Chem. Phys. 114 (1) (2001) 426
[43] I.M. Smallwood, Handbook of Organic Solvent Properties, Butterworth-Heinemann Elsevier Ltd, Oxford, United Kingdom, 1996
[44] R.F. Fedors, A method for estimating both the solubility parameters and molar volumes of liquids, Polym. Eng. Sci. 14 (2) (1974) 147-154
[45] K.S. Kim, H. Lee, Densities, viscosities, and surface tensions of the trifluoroethanol + quinoline system, J. Chem. Eng. Data 47 (2) (2002) 216-218
[46] H. Li, F. Guo, G.Q. Hu, L. Zhao, Y.D. Zhang, Solubilities and enthalpies of solution for thiourea in ethanol or methanol + water, J. Chem. Eng. Data 54 (11) (2009) 2986-2990
[47] N. Seedher, S. Bhatia, Solubility enhancement of cox-2 inhibitors using various solvent systems, AAPS Pharmscitech 4 (3) (2003) 36-44
[48] A.P. Gowardhane, N.V. Kadam, S. Dutta, Review on enhancement of solubilization process, Am. J. Drug Discov. Dev. 4 (2) (2014) 134-152
[49] J.H. Hildebrand, J.M. Prausnitz, R.L. Scott, Regular and related solutions:The solubility of gases, liquids and solids, Van Nostrand Reinhold Co., New York, 1970
[50] J.M. Prausnitz, R.N. Lichtenthaler, E.G. De Azevedo, Molecular thermodynamics of fluid-phase equilibria, in:Solubility of solids in liquids (Chapter 11), Pearson Education, New York,USA(1998) 653
[51] H.Y. Yang, T. Zhang, S.J. Xu, D.D. Han, S.Y. Liu, Y. Yang, S.C. Du, M.C. Li, J.B. Gong, Measurement and correlation of the solubility of azoxystrobin in seven monosolvents and two different binary mixed solvents, J. Chem. Eng. Data 62 (11) (2017) 3967-3980
[52] U. Domańska, Solubility of acetyl-substituted naphthols in binary solvent mixtures, Fluid Phase Equilibria 55 (1-2) (1990) 125-145
[53] A. Patel, A. Vaghasiya, R. Gajera, S. Baluja, Solubility of 5-amino salicylic acid in different solvents at various temperatures, J. Chem. Eng. Data 55 (3) (2010) 1453-1455
[54] A. Ahad, F. Shakeel, O.A. Alfaifi, M. Raish, A. Ahmad, F.I. Al-Jenoobi, A.M. Al-Mohizea, Solubility determination of raloxifene hydrochloride in ten pure solvents at various temperatures:Thermodynamics-based analysis and solute-solvent interactions, Int J Pharm 544 (1) (2018) 165-171
[55] F. Shakeel, N. Haq, F.K. Alanazi, I.A. Alsarra, Solubility and thermodynamics of apremilast in different mono solvents:Determination, correlation and molecular interactions, Int J Pharm 523 (1) (2017) 410-417