High-temperature CO2 sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

doi:10.1016/j.cjche.2022.09.005

Abstract

Abstract: CO₂, one of the main components of greenhouse gases, increased rapidly because of the growing use of fossil fuels. And CaO sorbents possess the capability to be used in capture of CO₂ at high temperature. In the work, Ca—Al complex oxides derived from citrate and stearate intercalated layered double hydroxides were fabricated and their CO₂ adsorption capacity was compared with that from CO₃^2- intercalated layered double hydroxides. The results presented that the sorbents (Ca/Al = 5) with Ca—Al—citrate layered double hydroxides as precursors performed best and displayed remarkable CO₂ capture capacity of 52.0% (mass) at the carbonization temperature of 600 ℃ without distinct recession during cycling adsorption/desorption tests. The excellent CO₂ adsorption capacity of the sorbent was ascribed to its smaller crystallite size of calcinated particles, optimized pore size distribution as well as homogeneous distributed Ca and Al in the sorbent.

Key words: Layered double hydroxides, CO₂ capture, CaO-based, Organic ions

摘要： CO₂, one of the main components of greenhouse gases, increased rapidly because of the growing use of fossil fuels. And CaO sorbents possess the capability to be used in capture of CO₂ at high temperature. In the work, Ca—Al complex oxides derived from citrate and stearate intercalated layered double hydroxides were fabricated and their CO₂ adsorption capacity was compared with that from CO₃^2- intercalated layered double hydroxides. The results presented that the sorbents (Ca/Al = 5) with Ca—Al—citrate layered double hydroxides as precursors performed best and displayed remarkable CO₂ capture capacity of 52.0% (mass) at the carbonization temperature of 600 ℃ without distinct recession during cycling adsorption/desorption tests. The excellent CO₂ adsorption capacity of the sorbent was ascribed to its smaller crystallite size of calcinated particles, optimized pore size distribution as well as homogeneous distributed Ca and Al in the sorbent.

关键词: Layered double hydroxides, CO₂ capture, CaO-based, Organic ions

Tao Jiang, Fei Xiao, Yujun Zhao, Shengping Wang, Xinbin Ma. High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor[J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 177-184.

Tao Jiang, Fei Xiao, Yujun Zhao, Shengping Wang, Xinbin Ma. High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor[J]. 中国化学工程学报, 2022, 50(10): 177-184.

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High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

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