The Joule–Thomson effect of (CO2 + H2) binary system relevant to gas switching reforming with carbon capture and storage (CCS)

doi:10.1016/j.cjche.2022.03.017

Abstract

Abstract: The Joule–Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage (CCS). In this work, a set of apparatus was set up to determine the Joule–Thomson effect of binary mixtures (CO₂ + H₂). The accuracy of the apparatus was verified by comparing with the experimental data of carbon dioxide. The Joule–Thomson coefficients (μ_JT) for (CO₂ + H₂) binary mixtures with mole fractions of carbon dioxide (χ_CO₂ = 0.1, 0.26, 0.5, 0.86, 0.94) along six isotherms at various pressures were measured. Five equations of state EOSs (PR, SRK, PR, BWR and GERG-2008 equation) were used to calculate the μ_JT for both pure systems and binary systems, among which the GERG-2008 predicted best with a wide range of pressure and temperature. Moreover, the Joule–Thomson inversion curves (JTIC) were calculated with five equations of state. A comparison was made between experimental data and predicted data for the inversion curve of CO₂. The investigated EOSs show a similar prediction of the low-temperature branch of the JTIC for both pure and binary systems, except for the BWRS equation of state. Among all the equations, SRK has the most similar result to GERG-2008 for predicting JTIC.

Key words: Carbon dioxide, Hydrogen, Joule–Thomson coefficient, Joule–Thomson inversion curve, Gas switching reforming (GSR), Carbon capture and storage (CCS)

摘要： The Joule–Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage (CCS). In this work, a set of apparatus was set up to determine the Joule–Thomson effect of binary mixtures (CO₂ + H₂). The accuracy of the apparatus was verified by comparing with the experimental data of carbon dioxide. The Joule–Thomson coefficients (μ_JT) for (CO₂ + H₂) binary mixtures with mole fractions of carbon dioxide (χ_CO₂ = 0.1, 0.26, 0.5, 0.86, 0.94) along six isotherms at various pressures were measured. Five equations of state EOSs (PR, SRK, PR, BWR and GERG-2008 equation) were used to calculate the μ_JT for both pure systems and binary systems, among which the GERG-2008 predicted best with a wide range of pressure and temperature. Moreover, the Joule–Thomson inversion curves (JTIC) were calculated with five equations of state. A comparison was made between experimental data and predicted data for the inversion curve of CO₂. The investigated EOSs show a similar prediction of the low-temperature branch of the JTIC for both pure and binary systems, except for the BWRS equation of state. Among all the equations, SRK has the most similar result to GERG-2008 for predicting JTIC.

关键词: Carbon dioxide, Hydrogen, Joule–Thomson coefficient, Joule–Thomson inversion curve, Gas switching reforming (GSR), Carbon capture and storage (CCS)

Zhongyao Zhang, Ming Gao, Xiaopeng Chen, Xiaojie Wei, Jiezhen Liang, Chenghong Wu, Linlin Wang. The Joule–Thomson effect of (CO₂ + H₂) binary system relevant to gas switching reforming with carbon capture and storage (CCS)[J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 215-231.

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The Joule–Thomson effect of (CO₂ + H₂) binary system relevant to gas switching reforming with carbon capture and storage (CCS)

The Joule–Thomson effect of (CO₂ + H₂) binary system relevant to gas switching reforming with carbon capture and storage (CCS)

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