Preparation of an adsorptive membrane of polyvinylidene fluoride incorporated functionalized boron nitride nanosheets for arsenic removal

doi:10.1016/j.cjche.2024.08.001

Abstract

Abstract: Incorporating nanomaterials into membranes will enhance wastewater treatment efficiency with their unique characteristics, such as higher permeability, thermal stability, surface roughness, hydrophilicity, and fouling control. In this study, the surface-modified boron nitride with phosphoric acid 2-hydroxyethyl methacrylate ester (PA/BN) was grafted with polyethylene glycol (PEG) via conventional grafting. The PEG grafted PA/BN (PEG-g-PA/BN) melt blended with polyvinylidene fluoride (PVDF) resin by using an internal mixer at different mass percentages (100% PVDF (PVDF), 3% PEG-g-PA/BN + 97% PVDF (97:3 BN), 5% PEG-g-PA/BN + 95% PVDF (95:5 BN), 7% PEG-g-PA/BN + 93% PVDF (93:7 BN), and 7% PEG-g-PA/BNNS + 93% PVDF (93:7 BNNS). Phase inversion technique was used to cast the blended mixture into a thin membrane. The prepared membranes were analyzed with different characterization techniques to determine chemical composition, crystallinity, morphology, and thermal properties. The prepared composite membrane was evaluated in terms of water permeability, anti-fouling resistance, and solute rejection efficiency with deionized water, bovine serum albumin, and arsenic solution as well. PVDF membranes show high water flux and porosity. The water flux and porosity of the blends decrease as the percentage of PEG-g-PA/BN increases. However, the highest removal capacity for arsenic was observed at 93:7 BN. The adsorption of arsenic ions takes place via complexation with PA/BN in the PVDF matrix. This was confirmed with field emission scanning electron microscopy-energy-dispersive X-ray analysis and X-ray photoelectron spectroscopy analyses.

Key words: Adsorption, Ultrafiltration, Preparation, Membranes

摘要： Incorporating nanomaterials into membranes will enhance wastewater treatment efficiency with their unique characteristics, such as higher permeability, thermal stability, surface roughness, hydrophilicity, and fouling control. In this study, the surface-modified boron nitride with phosphoric acid 2-hydroxyethyl methacrylate ester (PA/BN) was grafted with polyethylene glycol (PEG) via conventional grafting. The PEG grafted PA/BN (PEG-g-PA/BN) melt blended with polyvinylidene fluoride (PVDF) resin by using an internal mixer at different mass percentages (100% PVDF (PVDF), 3% PEG-g-PA/BN + 97% PVDF (97:3 BN), 5% PEG-g-PA/BN + 95% PVDF (95:5 BN), 7% PEG-g-PA/BN + 93% PVDF (93:7 BN), and 7% PEG-g-PA/BNNS + 93% PVDF (93:7 BNNS). Phase inversion technique was used to cast the blended mixture into a thin membrane. The prepared membranes were analyzed with different characterization techniques to determine chemical composition, crystallinity, morphology, and thermal properties. The prepared composite membrane was evaluated in terms of water permeability, anti-fouling resistance, and solute rejection efficiency with deionized water, bovine serum albumin, and arsenic solution as well. PVDF membranes show high water flux and porosity. The water flux and porosity of the blends decrease as the percentage of PEG-g-PA/BN increases. However, the highest removal capacity for arsenic was observed at 93:7 BN. The adsorption of arsenic ions takes place via complexation with PA/BN in the PVDF matrix. This was confirmed with field emission scanning electron microscopy-energy-dispersive X-ray analysis and X-ray photoelectron spectroscopy analyses.

关键词: Adsorption, Ultrafiltration, Preparation, Membranes

S. Selambakkannu, N. L. Ishak, N. M. Fauzi, N. Ismail, Z. A. Karim. Preparation of an adsorptive membrane of polyvinylidene fluoride incorporated functionalized boron nitride nanosheets for arsenic removal[J]. Chinese Journal of Chemical Engineering, 2024, 76(12): 49-63.

References

[1] N. Abdullah, N. Yusof, W.J. Lau, J. Jaafar, A.F. Ismail, Recent trends of heavy metal removal from water/wastewater by membrane technologies, J. Ind. Eng. Chem. 76 (2019) 17-38.
[2] C.R. Fadila, M.H.D. Othman, M.R. Adam, R. Takagi, T. Yoshioka, W. Khongnakorn, M.A. Rahman, J. Jaafar, A.F. Ismail, Adsorptive membrane for heavy metal removal: Material, fabrication, and performance, Mater. Today Proc. 65 (2022) 3037-3045.
[3] T.S. Vo, M.M. Hossain, H.M. Jeong, K. Kim, Heavy metal removal applications using adsorptive membranes, Nano Converg. 7 (1) (2020) 36.
[4] L. Qalyoubi, A. Al-Othman, S. Al-Asheh, Recent progress and challenges on adsorptive membranes for the removal of pollutants from wastewater. Part I: Fundamentals and classification of membranes, Case Stud. Chem. Environ. Eng. 3 (2021) 100086.
[5] E. Salehi, P. Daraei, A. Arabi Shamsabadi, A review on chitosan-based adsorptive membranes, Carbohydr. Polym. 152 (2016) 419-432.
[6] J.Q. Meng, J. Yuan, Y.L. Kang, Y.F. Zhang, Q.Y. Du, Surface glycosylation of polysulfone membrane towards a novel complexing membrane for boron removal, J. Colloid Interface Sci. 368 (1) (2012) 197-207.
[7] E. Salehi, S.S. Madaeni, F. Heidary, Dynamic adsorption of Ni(II) and Cd(II) ions from water using 8-hydroxyquinoline ligand immobilized PVDF membrane: Isotherms, thermodynamics and kinetics, Sep. Purif. Technol. 94 (2012) 1-8.
[8] A. Nain, A. Sangili, S.R. Hu, C.H. Chen, Y.L. Chen, H.T. Chang, Recent progress in nanomaterial-functionalized membranes for removal of pollutants, iScience 25 (7) (2022) 104616.
[9] M. Khraisheh, S. Elhenawy, F. AlMomani, M. Al-Ghouti, M.K. Hassan, B.H. Hameed, Recent progress on nanomaterial-based membranes for water treatment, Membranes 11 (12) (2021) 995.
[10] A.M. Nasir, P.S. Goh, A.F. Ismail, Highly adsorptive polysulfone/hydrous iron-nickel-manganese (PSF/HINM) nanocomposite hollow fiber membrane for synergistic arsenic removal, Sep. Purif. Technol. 213 (2019) 162-175.
[11] Ihsanullah, F.A. Al-Khaldi, B. Abusharkh, M. Khaled, M. Ali Atieh, M.S. Nasser, T. Laoui, T.A. Saleh, S. Agarwal, I. Tyagi, V.K. Gupta, Adsorptive removal of cadmium(II) ions from liquid phase using acid modified carbon-based adsorbents, J. Mol. Liq. 204 (2015) 255-263.
[12] A.M. Nasir, N.A.H. Md Nordin, P.S. Goh, A.F. Ismail, Application of two-dimensional leaf-shaped zeolitic imidazolate framework (2D ZIF-L) as arsenite adsorbent: Kinetic, isotherm and mechanism, J. Mol. Liq. 250 (2018) 269-277.
[13] A. Alshameri, A. Ibrahim, A.M. Assabri, X.R. Lei, H.Q. Wang, C.J. Yan, The investigation into the ammonium removal performance of Yemeni natural zeolite: Modification, ion exchange mechanism, and thermodynamics, Powder Technol. 258 (2014) 20-31.
[14] A. Mohd Nasir, M.R. Adam, S.K. Hubadillah, Grand challenges in the development of adsorptive membrane for water and wastewater treatment, J. Appl. Membr. Sci. Technol. 27 (2) (2023) 89-101.
[15] I.U. Khan, M.H.D. Othman, A.F. Ismail, T. Matsuura, H. Hashim, N.A.H.M. Nordin, M.A. Rahman, J. Jaafar, A. Jilani, Status and improvement of dual-layer hollow fiber membranes via co-extrusion process for gas separation: A review, J. Nat. Gas Sci. Eng. 52 (2018) 215-234.
[16] Z.Q. Huang, Z.F. Cheng, Recent advances in adsorptive membranes for removal of harmful cations, J. Appl. Polym. Sci. 137 (13) (2020) e48579.
[17] Y. Chen, P. Renner, H. Liang, Dispersion of nanoparticles in lubricating oil: A critical review, Lubricants 7 (1) (2019) 7.
[18] A. Pakdel, Y. Bando, D. Golberg, Nano boron nitride flatland, Chem. Soc. Rev. 43 (3) (2014) 934-959.
[19] Z.Y. Zheng, M. Cox, B. Li, Surface modification of hexagonal boron nitride nanomaterials: A review, J. Mater. Sci. 53 (1) (2018) 66-99.
[20] L.Q. Wang, E. Magliocca, E.L. Cunningham, W.E. Mustain, S.D. Poynton, R. Escudero-Cid, M.M. Nasef, J. Ponce-Gonzalez, R. Bance-Souahli, R.C.T. Slade, D.K. Whelligan, J.R. Varcoe, An optimised synthesis of high performance radiation-grafted anion-exchange membranes, Green Chem. 19 (3) (2017) 831-843.
[21] J. Azamat, A. Khataee, S.W. Joo, Separation of a heavy metal from water through a membrane containing boron nitride nanotubes: Molecular dynamics simulations, J. Mol. Model. 20 (10) (2014) 2468.
[22] J. Azamat, A. Khataee, S.W. Joo, Molecular dynamics simulation of trihalomethanes separation from water by functionalized nanoporous graphene under induced pressure, Chem. Eng. Sci. 127 (2015) 285-292.
[23] A. Hafeez, Z.A. Karim, A.F. Ismail, A. Samavati, K.A.M. Said, S. Selambakkannu, Functionalized boron nitride composite ultrafiltration membrane for dye removal from aqueous solution, J. Membr. Sci. 612 (2020) 118473.
[24] M. Lorber, Indirect exposure assessment at the United States Environmental Protection Agency, Toxicol. Ind. Health 17 (5-10) (2001) 145-156.
[25] D.G. Ebsa, W.T. Dibaba, Assessment of drinking water treatment and disinfection by-products, S. Afr. N. J. Chem. Eng. 41 (2022) 85-92.
[26] C.O. Akinbile, M.S. Yusoff, S.H. Abu Talib, Z. Abu Hasan, W.R. Ismail, U. Sansudin, Qualitative analysis and classification of surface water in Bukit Merah Reservoir in Malaysia, Water Supply 13 (4) (2013) 1138-1145.
[27] M. Sharma, S. Remanan, G. Madras, S. Bose, Crystallization induced phase separation: Unique tool to design microfiltration membranes with high flux and sustainable antibacterial surface, Ind. Eng. Chem. Res. 56 (8) (2017) 2025-2035.
[28] B. Chen, Y. Zhang, J.L. Zhang, L.J. Zhu, H.C. Zhao, PEGylated polyvinylidene fluoride membranes via grafting from a graphene oxide additive for improving permeability and antifouling properties, RSC Adv. 9 (32) (2019) 18688-18696.
[29] N.S. Kacem, F. Delporte, Y. Muhovski, A. Djekoun, B. Watillon, In vitro screening of durum wheat against water-stress mediated through polyethylene glycol, J. Genet. Eng. Biotechnol. 15 (1) (2017) 239-247.
[30] J. Pretula, K. Kaluzynski, B. Wisniewski, R. Szymanski, T. Loontjens, S. Penczek, H₃PO₄ in a direct synthesis of oligo-poly(ethylene phosphate) from ethylene glycol, J. Polym. Sci. A Polym. Chem. 44 (7) (2006) 2358-2362.
[31] M.D. Moezzi, M. Karrabi, Y. Jahani, Thermal tensile, and dynamic mechanical properties of PVDF/FKM blends in different curing systems, Polym. Korea 41 (2) (2017) 250.
[32] A. Oucif, N. Haddadine, D. Zakia, N. Bouslah, A. Benaboura, K. Beyaz, B. Guedouar, M.S. El-Shall, Poly (hydroxyethyl methacrylate-co-hydroxyethyl acrylate) soft contact lenses for acetazolamide release, Polym. Bull. 79 (3) (2022) 1535-1554.
[33] A.R. Deshmukh, J.W. Jeong, S.J. Lee, G.U. Park, B.S. Kim, Ultrasound-assisted facile green synthesis of hexagonal boron nitride nanosheets and their applications, ACS Sustainable Chem. Eng. 7 (20) (2019) 17114-17125.
[34] T. Jager, A. Mokos, N.I. Prasianakis, S. Leyer, Pore-level multiphase simulations of realistic distillation membranes for water desalination, Membr. Basel 12 (11) (2022) 1112.
[35] K.A.R. Medeiros, E.Q. Rangel, A.R. Sant’Anna, D.R. Louzada, C.R.H. Barbosa, J.R.M. D’Almeida, Evaluation of the electromechanical behavior of polyvinylidene fluoride used as a component of risers in the offshore oil industry, Oil Gas Sci. Technol. - Rev. IFP Energies Nouvelles 73 (2018) 48.
[36] X.M. Cai, T.P. Lei, D.H. Sun, L.W. Lin, A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR, RSC Adv. 7 (25) (2017) 15382-15389.
[37] S. Yuan, C. Journet, S. Linas, V. Garnier, P. Steyer, S. Benayoun, A. Brioude, B. Toury, How to increase the h-BN crystallinity of microfilms and self-standing nanosheets: A review of the different strategies using the PDCs route, Crystals 6 (5) (2016) 55.
[38] F. Yuan, W.C. Jiao, F. Yang, W.B. Liu, J.Y. Liu, Z.H. Xu, R.G. Wang, Scalable exfoliation for large-size boron nitride nanosheets by low temperature thermal expansion-assisted ultrasonic exfoliation, J. Mater. Chem. C 5 (25) (2017) 6359-6368.
[39] T.F. Wu, B.M. Zhou, T. Zhu, J. Shi, Z.W. Xu, C.S. Hu, J.J. Wang, Facile and low-cost approach towards a PVDF ultrafiltration membrane with enhanced hydrophilicity and antifouling performance via graphene oxide/water-bath coagulation, RSC Adv. 5 (11) (2015) 7880-7889.
[40] J. Liu, X.L. Lu, C.R. Wu, Effect of preparation methods on crystallization behavior and tensile strength of poly(vinylidene fluoride) membranes, Membranes 3 (4) (2013) 389-405.
[41] P.X. Feng, M. Sajjad, Few-atomic-layer boron nitride sheets syntheses and applications for semiconductor diodes, Mater. Lett. 89 (2012) 206-208.
[42] J. Aramendia, I. Poblacion, J. Huidobro, L. Coloma, C. Garcia-Florentino, G. Arana, K. Castro, J.M. Madariaga, Can Raman spectroscopy determine the presence of ionic compounds? The use of water molecules as a indirect identification parameter, in 16th Europlanet Science Congress, Palacio de Congresos de Granada, Spain, 2022.
[43] A. Mansourizadeh, A.F. Ismail, Influence of membrane morphology on characteristics of porous hydrophobic PVDF hollow fiber contactors for CO₂ stripping from water, Desalination 287 (2012) 220-227.
[44] N.M. Mokhtar, W.J. Lau, B.C. Ng, A.F. Ismail, D. Veerasamy, Preparation and characterization of PVDF membranes incorporated with different additives for dyeing solution treatment using membrane distillation, Desalin. Water Treat. 56 (8) (2015) 1999-2012.
[45] H.Q. Liang, L.S. Wan, Z.K. Xu, Poly(vinylidene fluoride) separators with dual-asymmetric structure for high-performance lithium ion batteries, Chin. J. Polym. Sci. 34 (12) (2016) 1423-1435.
[46] A.P. Ysiwata-Rivera, E. Hernandez-Hernandez, G. Cadenas-Pliego, C.A. Avila-Orta, P. Gonzalez-Morones, J.A.V.D. Jesus, E. Cuara-Diaz, C.A. Gallardo-Vega, J.M. Mata-Padilla, Effect of modified hexagonal boron nitride nanoparticles on the emulsion stability, viscosity and electrochemical behavior of nanostructured acrylic coatings for the corrosion protection of AISI 304 stainless steel, Coatings 10 (5) (2020) 488.
[47] M.S. Rahman, M.N.I. Shiblee, K. Ahmed, A. Khosla, J. Ogawa, M. Kawakami, H. Furukawa, Flexible and conductive 3D printable polyvinylidene fluoride and poly(N, N-dimethylacrylamide) based gel polymer electrolytes, Macromol. Mater. Eng. 305 (9) (2020) 2000262.
[48] W. Li, H. Li, Y.M. Zhang, Preparation and investigation of PVDF/PMMA/TiO₂ composite film, J. Mater. Sci. 44 (11) (2009) 2977-2984.
[49] P. Kaspar, D. Sobola, K. Castkova, R. Dallaev, E. Stastna, P. Sedlak, A. Knapek, T. Trcka, V. Holcman, Case study of polyvinylidene fluoride doping by carbon nanotubes, Materials (Basel) 14 (6) (2021) 1428.
[50] L. Fu, G.X. Chen, N. Jiang, J.H. Yu, C.T. Lin, A.M. Yu, In situ growth of metal nanoparticles on boron nitride nanosheets as highly efficient catalysts, J. Mater. Chem. A 4 (48) (2016) 19107-19115.
[51] S. Abdikheibari, W.W. Lei, L.F. Dumee, A.J. Barlow, K. Baskaran, Novel thin film nanocomposite membranes decorated with few-layered boron nitride nanosheets for simultaneously enhanced water flux and organic fouling resistance, Appl. Surf. Sci. 488 (2019) 565-577.
[52] B.M. Ma, J. Yang, Q.S. Sun, W. Jakpa, X.L. Hou, Y.Q. Yang, Influence of cellulose/[Bmim]Cl solution on the properties of fabricated NIPS PVDF membranes, J. Mater. Sci. 52 (16) (2017) 9946-9957.
[53] S. Acosta, V. Perez Luna, G. Sanchez Balderas, J.M. Hernandez Meza, B. Yanez Soto, M. Quintana, Wetting properties of thin films of exfoliated hexagonal boron nitride in different solvents, Rev. Mex. Fis. 69 (4 Jul-Aug) (2023) 041607 1-6.
[54] T.N. Baroud, Tuning PVDF membrane porosity and wettability resistance via varying substrate morphology for the desalination of highly saline water, Membranes 13 (4) (2023) 395.
[55] J.A. Kharraz, A.K. An, Patterned superhydrophobic polyvinylidene fluoride (PVDF) membranes for membrane distillation: Enhanced flux with improved fouling and wetting resistance, J. Membr. Sci. 595 (2020) 117596.
[56] G. Jozefaciuk, Effect of the size of aggregates on pore characteristics of minerals measured by mercury intrusion and water-vapor desorption techniques, Clays Clay Miner. 57 (5) (2009) 586-601.
[57] F. Liu, M.M. Tao, L.X. Xue, PVDF membranes with inter-connected pores prepared via a Nat-ips process, Desalination 298 (2012) 99-105.
[58] D. da Silva Biron, P. Poletto, J. Duarte, M. Zeni, C.P. Bergmann, V. dos Santos, Preparation and characterization of PA66/alumina composite membrane, Mat. Res. 18 (4) (2015) 748-755.
[59] S. Bano, M. Pednekar, S. Rameshkumar, D. Borah, M.A. Morris, R.B. Padamati, N. Cronly, Fabrication and evaluation of filtration membranes from industrial polymer waste, Membranes 13 (4) (2023) 445.
[60] M.Z. Li, J.H. Li, X.S. Shao, J. Miao, J.B. Wang, Q.Q. Zhang, X.P. Xu, Grafting zwitterionic brush on the surface of PVDF membrane using physisorbed free radical grafting technique, J. Membr. Sci. 405 (2012) 141-148.
[61] J. Li, X. Xiao, X.W. Xu, J. Lin, Y. Huang, Y.M. Xue, P. Jin, J. Zou, C.C. Tang, Activated boron nitride as an effective adsorbent for metal ions and organic pollutants, Sci. Rep. 3 (2013) 3208.
[62] A.E.D. Mahmoud, E. Mostafa, Nanofiltration membranes for the removal of heavy metals from aqueous solutions: Preparations and applications, Membranes 13 (9) (2023) 789.
[63] Y. Ibrahim, V. Naddeo, F. Banat, S.W. Hasan, Preparation of novel polyvinylidene fluoride (PVDF)-Tin(IV) oxide (SnO₂) ion exchange mixed matrix membranes for the removal of heavy metals from aqueous solutions, Sep. Purif. Technol. 250 (2020) 117250.
[64] G.Q. Chen, Y.X. Liu, F. Liu, X. Zhang, Fabrication of three-dimensional graphene foam with high electrical conductivity and large adsorption capability, Appl. Surf. Sci. 311 (2014) 808-815.
[65] K.Y. Shin, J.Y. Hong, J. Jang, Heavy metal ion adsorption behavior in nitrogen-doped magnetic carbon nanoparticles: Isotherms and kinetic study, J. Hazard. Mater. 190 (1-3) (2011) 36-44.
[66] B. Alizadeh, M. Ghorbani, M. Ali Salehi, Application of polyrhodanine modified multi-walled carbon nanotubes for high efficiency removal of Pb(II) from aqueous solution, J. Mol. Liq. 220 (2016) 142-149.
[67] R. Dubey, J. Bajpai, A.K. Bajpai, Green synthesis of graphene sand composite (GSC) as novel adsorbent for efficient removal of Cr(VI) ions from aqueous solution, J. Water Process. Eng. 5 (2015) 83-94.
[68] S. Scorrano, L. Mergola, M.P. Di Bello, M.R. Lazzoi, G. Vasapollo, R. Del Sole, Molecularly imprinted composite membranes for selective detection of 2-deoxyadenosine in urine samples, Int. J. Mol. Sci. 16 (6) (2015) 13746-13759.
[69] M. Rjeb, A. Labzour, A. Rjeb, S. Sayouri, M. Chafik El Idrissi, S. Massey, A. Adnot, D. Roy, Contribution to the study by X-ray photoelectron spectroscopy of the natural aging of the polypropylene, Moroccan J. Condens. Matter 5 (2) (2004) 168-172.
[70] V. Vatanpour, H. Karimi, S. Imanian Ghazanlou, Y. Mansourpanah, M.R. Ganjali, A. Badiei, E. Pourbashir, M.R. Saeb, Anti-fouling polyethersulfone nanofiltration membranes aided by amine-functionalized boron nitride nanosheets with improved separation performance, J. Environ. Chem. Eng. 8 (6) (2020) 104454.
[71] Z.X. Low, J. Ji, D. Blumenstock, Y.M. Chew, D. Wolverson, D. Mattia, Fouling resistant 2D boron nitride nanosheet-PES nanofiltration membranes, J. Membr. Sci. 563 (2018) 949-956.
[72] R.X. Wang, Z.X. Low, S.S. Liu, Y.Q. Wang, S. Murthy, W. Shen, H.T. Wang, Thin-film composite polyamide membrane modified by embedding functionalized boron nitride nanosheets for reverse osmosis, J. Membr. Sci. 611 (2020) 118389.
[73] R. Das, P. Solis-Fernandez, D. Breite, A. Prager, A. Lotnyk, A. Schulze, H. Ago, High flux and adsorption based non-functionalized hexagonal boron nitride lamellar membrane for ultrafast water purification, Chem. Eng. J. 420 (2021) 127721.
[74] N. Garcia Domenech, F. Purcell-Milton, A. Sanz Arjona, M.L. Casasin Garcia, M. Ward, M.B. Cabre, A. Rafferty, K. McKelvey, P. Dunne, Y.K. Gun’ko, High-performance boron nitride-based membranes for water purification, Nanomaterials (Basel) 12 (3) (2022) 473.
[75] R.S. Bangari, A. Yadav, J. Bharadwaj, N. Sinha, Boron nitride nanosheets incorporated polyvinylidene fluoride mixed matrix membranes for removal of methylene blue from aqueous stream, J. Environ. Chem. Eng. 10 (1) (2022) 107052.
[76] A. Abdelrasoul, H. Doan, A. Lohi, C.H. Cheng, Mass transfer mechanisms and transport resistances in membrane separation process. Mass Transfer - Advancement in Process Modelling (2015), DOI: 10.5772/60866.
[77] A. Abdelrasoul, H. Doan, A. Lohi, C.H. Cheng, Mass transfer mechanisms and transport resistances in membrane separation process. Mass Transf. Adv. Process Model. (2015), DOI: 10.5772/60866.