Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H2O2

doi:10.1016/j.cjche.2020.01.002

Chinese Journal of Chemical Engineering ›› 2020, Vol. 28 ›› Issue (5): 1302-1310.DOI: 10.1016/j.cjche.2020.01.002

• Catalysis, Kinetics and Reaction Engineering • Previous Articles Next Articles

Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H₂O₂

Xianfeng Liu^1,2, Fu Yang^1,3, Shuying Gao¹, Bo Shao¹, Shijian Zhou¹, Yan Kong¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 College of Environment Engineering, Nanjing Institute of Technology, Nanjing 211167, China;
3 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Received:2019-03-08 Revised:2019-10-19 Online:2020-07-29 Published:2020-05-28
Contact: Fu Yang, Yan Kong
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 21476108, 21276125, 21776129, 21706121 and 21908085), Natural Science Foundation of Jiangsu Province (Nos. BK20170995 and BK20190961), General Program for University Natural Science Research of Jiangsu Province (No. 16KJB530003) and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H₂O₂

Xianfeng Liu^1,2, Fu Yang^1,3, Shuying Gao¹, Bo Shao¹, Shijian Zhou¹, Yan Kong¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 College of Environment Engineering, Nanjing Institute of Technology, Nanjing 211167, China;
3 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

通讯作者: Fu Yang, Yan Kong
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 21476108, 21276125, 21776129, 21706121 and 21908085), Natural Science Foundation of Jiangsu Province (Nos. BK20170995 and BK20190961), General Program for University Natural Science Research of Jiangsu Province (No. 16KJB530003) and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Abstract

Abstract: Design and synthesis of low cost and efficacious industrial catalyst for the oxidation of styrene has been an important research project. Herein, ZSM-5 zeolite containing tetrahedral vanadium (V) and Brønsted acid sites (V-H-ZSM-5) was prepared, and identified by characterizations such as XRD, SEM, UV-vis, NH₃-TPD, H₂-TPR N₂-adsorption/desorption and FTIR. V-H-ZSM-5 performed extremely enhanced catalytic activity for the oxidation of styrene with 30% H₂O₂ at 40℃. Moreover, in-situ FTIR spectrum was used to investigate the catalytic mechanism. The results demonstrate that Brønsted acid site could not only increase the adsorption concentration of styrene in the micropores of V-H-ZSM-5 via the π complex interaction between double bond of styrene and Brønsted acid sites, but also increase the oxidation potential of H₂O₂. The synergetic action of tetrahedral vanadium (V) and Brønsted acid enhanced the catalytic activity for the oxidation of styrene with 30% H₂O₂. Impressively, V-H-ZSM-5 performed high reusability within five runs at a low reaction temperature (40℃) for the first time.

Key words: Selective oxidation, Styrene, Brønsted acid, Bifunctional, Vanadium

摘要： Design and synthesis of low cost and efficacious industrial catalyst for the oxidation of styrene has been an important research project. Herein, ZSM-5 zeolite containing tetrahedral vanadium (V) and Brønsted acid sites (V-H-ZSM-5) was prepared, and identified by characterizations such as XRD, SEM, UV-vis, NH₃-TPD, H₂-TPR N₂-adsorption/desorption and FTIR. V-H-ZSM-5 performed extremely enhanced catalytic activity for the oxidation of styrene with 30% H₂O₂ at 40℃. Moreover, in-situ FTIR spectrum was used to investigate the catalytic mechanism. The results demonstrate that Brønsted acid site could not only increase the adsorption concentration of styrene in the micropores of V-H-ZSM-5 via the π complex interaction between double bond of styrene and Brønsted acid sites, but also increase the oxidation potential of H₂O₂. The synergetic action of tetrahedral vanadium (V) and Brønsted acid enhanced the catalytic activity for the oxidation of styrene with 30% H₂O₂. Impressively, V-H-ZSM-5 performed high reusability within five runs at a low reaction temperature (40℃) for the first time.

关键词: Selective oxidation, Styrene, Brønsted acid, Bifunctional, Vanadium

Xianfeng Liu, Fu Yang, Shuying Gao, Bo Shao, Shijian Zhou, Yan Kong. Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H₂O₂[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1302-1310.

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Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H₂O₂

Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H₂O₂

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