SCI和EI收录∣中国化工学会会刊

›› 2015, Vol. 23 ›› Issue (3): 572-577.DOI: 10.1016/j.cjche.2014.04.003

• Chemical Engineering Thermodynamics • Previous Articles     Next Articles

Performance analysis of a zeotropicmixture (R290/CO2) for trans-critical power cycle

Lisheng Pan1, XiaolinWei1, Weixiu Shi2   

  1. 1 State Key Laboratory of High-Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China;
    2 School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
  • Received:2014-02-11 Revised:2014-04-30 Online:2015-04-03 Published:2015-03-28
  • Supported by:
    Project 51306198 supported by the National Natural Science Foundation of China.

Performance analysis of a zeotropicmixture (R290/CO2) for trans-critical power cycle

Lisheng Pan1, XiaolinWei1, Weixiu Shi2   

  1. 1 State Key Laboratory of High-Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China;
    2 School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
  • 通讯作者: Lisheng Pan
  • 基金资助:
    Project 51306198 supported by the National Natural Science Foundation of China.

Abstract: Lowcritical temperature limits the application of CO2 trans-critical power cycle. The binary mixture of R290/CO2 has higher critical temperature. Using mixture fluid may solve the problem that subcritical CO2 is hardly condensed by conventional cooling water. In this article, theoretical analysis is executed to study the performance of the zeotropic mixture for trans-critical power cycle using low-grade liquid heat source with temperature of 200℃. The results indicated that the problem that CO2 can't be condensed in power cycle by conventional coolingwater can be solved bymixing R290 to CO2. Variation trend of outlet temperature of thermal oil in supercritical heaterwith heating pressure is determined by the composition of the mixture fluid. Gliding temperature causes the maximum outlet temperature of cooling water with the increase of mass fraction of R290. There are themaximumvalues for cycle thermal efficiency and net power outputwith the increase of supercritical heating pressure.

Key words: CO2, R290, Zeotropic mixture, Low-grade heat energy, Trans-critical power cycle

摘要: Lowcritical temperature limits the application of CO2 trans-critical power cycle. The binary mixture of R290/CO2 has higher critical temperature. Using mixture fluid may solve the problem that subcritical CO2 is hardly condensed by conventional cooling water. In this article, theoretical analysis is executed to study the performance of the zeotropic mixture for trans-critical power cycle using low-grade liquid heat source with temperature of 200℃. The results indicated that the problem that CO2 can't be condensed in power cycle by conventional coolingwater can be solved bymixing R290 to CO2. Variation trend of outlet temperature of thermal oil in supercritical heaterwith heating pressure is determined by the composition of the mixture fluid. Gliding temperature causes the maximum outlet temperature of cooling water with the increase of mass fraction of R290. There are themaximumvalues for cycle thermal efficiency and net power outputwith the increase of supercritical heating pressure.

关键词: CO2, R290, Zeotropic mixture, Low-grade heat energy, Trans-critical power cycle