Cobalt-free gadolinium-doped perovskite Gdx1-xFeO3-δ as high-performance materials for oxygen separation

doi:10.1016/j.cjche.2015.08.023

Abstract

Abstract: Cobalt-free oxides Gd_x_1-xFeO_3-δ (0.01 ≤ x ≤ 0.1)were achieved by a solid state reactionmethod. It is found that Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1) exhibits the cubic perovskite structure. Among Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1), the Gd_0.025Ba_0.975FeO_3-δ (GBF2.5) membrane shows the outstanding phase structure stability and the highest oxygen permeation,which can reach 1.44ml·cm^-2·min^-1 at 950 ℃ under air/He oxygen partial pressure gradient. The GBF2.5 membranewas successfully operated formore than 100 h at 800 ℃ and the oxygen permeation flux through the membrane is 0.62 ml·cm^-2·min^-1. After 100 h oxygen permeation experiment at 800 ℃, X-ray diffraction (XRD) and energy dispersive X-ray spectrometer (EDXS) demonstrate that the GBF2.5 exhibits phase structure stability even at intermediate temperature.

Key words: Perovskite, Membranes, Permeation, BaFeO_3-&delta, , Oxygen separation

摘要： Cobalt-free oxides Gd_x_1-xFeO_3-δ (0.01 ≤ x ≤ 0.1)were achieved by a solid state reactionmethod. It is found that Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1) exhibits the cubic perovskite structure. Among Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1), the Gd_0.025Ba_0.975FeO_3-δ (GBF2.5) membrane shows the outstanding phase structure stability and the highest oxygen permeation,which can reach 1.44ml·cm^-2·min^-1 at 950 ℃ under air/He oxygen partial pressure gradient. The GBF2.5 membranewas successfully operated formore than 100 h at 800 ℃ and the oxygen permeation flux through the membrane is 0.62 ml·cm^-2·min^-1. After 100 h oxygen permeation experiment at 800 ℃, X-ray diffraction (XRD) and energy dispersive X-ray spectrometer (EDXS) demonstrate that the GBF2.5 exhibits phase structure stability even at intermediate temperature.

关键词: Perovskite, Membranes, Permeation, BaFeO_3-&delta, , Oxygen separation

Yanjie Wang, Qing Liao, Yan Chen, Libin Zhuang, Haihui Wang. Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation[J]. Chin.J.Chem.Eng., 2015, 23(11): 1763-1767.

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Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation

Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation

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