Enthalpy of phase transition of isonicotinic acid

doi:10.1016/j.cjche.2016.08.014

Abstract

Abstract: In this work, the group contribution method of Chickos et al. was applied to estimate the fusion enthalpy of isonicotinic acid, and the obtained result (29.2 kJ·mol^-1) showed a large difference with the value (135 kJ·mol^-1) as reported from literatures and as determined by differential scanning calorimetry (DSC). The results of DSC/TG measurement showed that the phase transition of isonicotinic acid from 187.27℃ to 277.47℃ underwent a sublimation process, with a sublimation enthalpy of 128.03 kJ·mol^-1. An efficient analytical technique combining pyrolysis and gas chromatography/mass spectrometry (Py-GC/MS) was used to prove this conclusion.

Key words: Isonicotinic acid, Enthalpy of fusion, Group contribution method, Enthalpy of sublimation, Py-GC/MS

摘要： In this work, the group contribution method of Chickos et al. was applied to estimate the fusion enthalpy of isonicotinic acid, and the obtained result (29.2 kJ·mol^-1) showed a large difference with the value (135 kJ·mol^-1) as reported from literatures and as determined by differential scanning calorimetry (DSC). The results of DSC/TG measurement showed that the phase transition of isonicotinic acid from 187.27℃ to 277.47℃ underwent a sublimation process, with a sublimation enthalpy of 128.03 kJ·mol^-1. An efficient analytical technique combining pyrolysis and gas chromatography/mass spectrometry (Py-GC/MS) was used to prove this conclusion.

关键词: Isonicotinic acid, Enthalpy of fusion, Group contribution method, Enthalpy of sublimation, Py-GC/MS

Dongfang Zhao, Guanghui Liu, Jian Sun, Lisheng Wang. Enthalpy of phase transition of isonicotinic acid[J]. , 2017, 25(7): 971-975.

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