The adsorption and corrosion inhibition of 8-hydroxy-7-quinolinecarboxaldehyde derivatives on C-steel surface in hydrochloric acid

doi:10.1016/j.cjche.2016.11.018

Abstract

Abstract: The protection influence of 8-hydroxy-7-quinolinecarboxaldehyde derivatives against C-steel corrosion was studied in 2 mol·L^-1 HCl solutions at 30℃. Measurements were conducted under various experimental conditions using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. These studies have shown that 8-hydroxy-7-quinolinecarboxaldehyde derivatives are very good "green", mixed-type inhibitors. Corrosion rates obtained from both EFM and EIS methods are comparable with those recorded using Tafel extrapolation method, confirming validation of corrosion rates measured by the latter. The inhibitive action of these 8-hydroxy-7-quinolinecarboxaldehyde derivatives was discussed in terms of blocking the electrode surface by adsorption of the molecules through the active centers contained in their structures following Langmuir adsorption isotherm. Quantum chemical method was also employed to explore the relationship between the inhibitor molecular properties and its protection efficiency.

Key words: 8-Hydroxy-7-quinolinecarboxaldehyde, derivatives, C-steel, HCl, EFM

摘要： The protection influence of 8-hydroxy-7-quinolinecarboxaldehyde derivatives against C-steel corrosion was studied in 2 mol·L^-1 HCl solutions at 30℃. Measurements were conducted under various experimental conditions using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. These studies have shown that 8-hydroxy-7-quinolinecarboxaldehyde derivatives are very good "green", mixed-type inhibitors. Corrosion rates obtained from both EFM and EIS methods are comparable with those recorded using Tafel extrapolation method, confirming validation of corrosion rates measured by the latter. The inhibitive action of these 8-hydroxy-7-quinolinecarboxaldehyde derivatives was discussed in terms of blocking the electrode surface by adsorption of the molecules through the active centers contained in their structures following Langmuir adsorption isotherm. Quantum chemical method was also employed to explore the relationship between the inhibitor molecular properties and its protection efficiency.

关键词: 8-Hydroxy-7-quinolinecarboxaldehyde, derivatives, C-steel, HCl, EFM

A. M. Eldesoky, S. G. Nozha. The adsorption and corrosion inhibition of 8-hydroxy-7-quinolinecarboxaldehyde derivatives on C-steel surface in hydrochloric acid[J]. , 2017, 25(9): 1256-1265.

References

[1] M.A. Deyab, Effect of cationic surfactant and inorganic anions on the electrochemical behavior of carbon steel in formation water, Corros. Sci. 49(2007) 2315-2328.
[2] S.A. Abd El-Maksoud, A.S. Fouda, Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium, Mater. Chem. Phys. 93(2005) 84-90.
[3] K.F. Khaled, Application of electrochemical frequency modulation for monitoring corrosion and corrosion inhibition of iron by some indole derivatives in molar hydrochloric acid, Mater. Chem. Phys. 122(2008) 290-300.
[4] E. Machnikova, K.H. Whitmire, N. Hackeman, Corrosion inhibition of carbon steel in hydrochloric acid by furan derivatives, Electrochim. Acta 53(2008) 6024-6032.
[5] H. Ashassi-sorkhabi, M.R. Magidi, K. Seyyedi, Investigation of inhibition effect of some amino acids against steel corrosion in HCl solution, Appl. Surf. Sci. 225(2004) 176-185.
[6] M.A. Migahed, I.F. Nassar, Corrosion inhibition of tubing steel during acidization of oil and gas wells, Electrochim. Acta 53(2008) 2877-2882.
[7] G. Avci, Corrosion inhibition of indole-3-acetic acid on mild steel in 0.5 mol·L^-1 HCl, Colloids Surf. A 317(2008) 730-736.
[8] M. Bagherzadeh, H. Haddadi, M. Iranpour, Electrochemical evaluation and surface study of magnetite/PANI nanocomposite for carbon steel protection in 3.5% NaCl, Prog. Org. Coat. 101(2016) 149-160.
[9] M. Abdallah, E.A. Helal, A.S. Fouda, Aminopyrimidine derivatives as inhibitors for corrosion of 1018 carbon steel in nitric acid solution, Corros. Sci. 48(2006) 1639-1654.
[10] A.S. Fouda, A.A. Al-Sarawy, E.E. El-Katori, Potentiometric and thermodynamic studies of 3-methyl-1-phenyl-{p-[N-(pyrimidin-2-yl)-sulfamoyl] phenylazo}-2-pyrazolin-5-one and its metal complexes, Chem. Pap. 60(2006) 5-9.
[11] O. Benali, L. Larabi, M. Traisnel, L. Gengembre, Y. Harek, Electrochemical, theoretical and XPS studies of 2-mercapto-1-methylimidazole adsorption on carbon steel in 1 mol·L^-1 HClO₄, Appl. Surf. Sci. 253(2007) 6130-6139.
[12] C. Verma, M.A. Quraishi, E.E. Ebenso, I.B. Obot, A. El-Assyry, 3-Amino alkylated indoles as corrosion inhibitors for mild steel in 1mol·L^-1 HCl:Experimental and theoretical studies, J. Mol. Liq. 219(2016) 647-660.
[13] M.A. Khalifa, M. El-Batouti, F. Mahgoub, A.B. Aknish, Corrosion inhibition of steel in crude oil storage tanks, Mater. Corros. 54(2003) 251-258.
[14] H. Ashassi-Sorkhabi, B. Shaabani, D. Seifzadeh, Corrosion inhibition of mild steel by some Schiff base compounds in hydrochloric acid, Appl. Surf. Sci. 239(2005) 154-164.
[15] K.F. Khaled, The inhibition of benzimidazole derivatives on corrosion of iron in 1 mol·L^-1 HCl solutions, Electrochim. Acta 48(2003) 2493-2503.
[16] A. Popova, M. Christov, S. Raicheva, E. Sokolova, Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion, Corros. Sci. 46(2004) 1333-1350.
[17] R.E. Khidre, A.A. Abu-Hashem, M. El-Shazly, Synthesis and anti-microbial activity of some 1-substituted amino-4, 6-dimethyl-2-oxo-pyridine-3-carbonitrile derivatives, Eur. J. Med. Chem. 46(2011) 5057-5064.
[18] E.E. Ebenso, I.B. Obot, L.C. Murulana, Quinoline and its derivatives as effective corrosion inhibitors for mild steel in acidic medium, Int. J. Electrochem. Sci. 5(2010) 1574-1586.
[19] G. Achary, H.P. Sachin, Y.A. Naik, T.V. Venkatesha, The corrosion inhibition of mild steel by 3-formyl-8-hydroxy quinoline in hydrochloric acid medium, Mater. Chem. Phys. 107(2008) 44-50.
[20] V.R. Saliyan, A.V. Adhikari, Quinolin-5-ylmethylene-3-{[8-(trifluoromethyl) quinolin-4-yl] thio} propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution, Corros. Sci. 50(2008) 55-61.
[21] B.M. Mistry, S. Jauhari, Synthesis and evaluation of some quinoline Schiff bases as a corrosion inhibitor for mild steel in 1 mol·L^-1 HCl, Res. Chem. Intermed. 39(2013) 1049-1068.
[22] A.Z. El-Sonbati, M.A. Diab, A.A. El-Bindary, G.G. Mohamed, Sh.M. Morgan, M.I. Abou-Dobara, S.G. Nozha, Geometrical structures, thermalstability and antimicrobial activity of Schiff base supramolecular and its metal complexes, J. Mol. Liq. 215(2016) 423-442.
[23] A.Z. El-Sonbati, A.A. El-Bindary, Stereochemistry of new nitrogen containing aldehydes. V. Novel synthesis and spectroscopic studies of some quinoline Schiff bases complexes, Pol. J. Chem. 74(2000) 621-630.
[24] A.Z. El-Sonbati, A.A. El-Bindary, A.F. Shoair, R.M. Younes, Stereochemistry of new nitrogen containing heterocyclic aldehyde. VⅡ. Potentiometric, conductometric and thermodynamic studies of novel quinoline azodyes and their metal complexes with some transition metals, Chem. Pharm. Bull. 49(2001) 1308-1313.
[25] N.A. El-Ghamaz, M.A. Diab, A.A. El-Bindary, A.Z. El-Sonbati, S.G. Nozha, Thermal, dielectric characteristics and conduction mechanism of azodyes derived from quinoline and their copper complexes, Spectrochim. Acta A 143(2015) 200-212.
[26] Yu.P. Khodyrev, E.S. Batyeva, E.K. Badeeva, E.V. Platova, L. Tiwari, O.G. Sinyashin, The inhibition action of ammonium salts of O, O'-dialkyldithio-phosphoric acid on carbon dioxide corrosion of mild steel, Corros. Sci. 53(2011) 976-983.
[27] V.V. Torres, R.S. Amado, C.F. de Sá, T.L. Fernandez, C.A. Da Silva Riehl, A.G. Torres, E. D'Elia, Inhibitory action of aqueous coffee ground extracts on the corrosion of carbon steel in HCl solution, Corros. Sci. 53(2011) 2385-2392.
[28] T. Zhao, G. Mu, The adsorption and corrosion inhibition of anion surfactants on aluminium surface in hydrochloric acid, Corros. Sci. 41(1999) 1937-1944.
[29] M.J. Bahrami, S.M.A. Hosseini, P. Pilvar, Experimental and theoretical investigation of organic compounds as inhibitors for mild steel corrosion in sulfuric acid medium, J. Corros. Sci. 52(2010) 2793-2803.
[30] A. Ostovari, S.M. Hoseinieh, M. Peikari, S.R. Shadizadeh, S.J. Hashemi, Corrosion inhibition of mild steel in 1mol·L^-1 HCl solution by henna extract:A comparative study of the inhibition by henna and its constituents (lawsone, gallic acid, α-d-glucose and tannic acid), Corros. Sci. 51(2009) 1935-1949.
[31] M. Bouklah, B. Hammouti, M. Lagrenée, F. Bentiss, Thermodynamic properties of 2, 5-bis (4-methoxyphenyl)-1, 3, 4-oxadiazole as a corrosion inhibitor for mild steel in normal sulfuric acid medium, Corros. Sci. 48(2006) 2831-2842.
[32] F. Bensajjay, S. Alehyen, M. El Achouri, S. Kertit, Corrosion inhibition of steel by 1-phenyl 5-mercapto 1, 2, 3, 4-tetrazole in acidic environments (0.5 mol·L^-1 H₂SO₄ and 1/3 mol·L^-1 H₃PO₄), Anti-Corros. Methods Mater. 50(2003) 402-409.
[33] S.Z. Duan, Y.L. Tao, Interface Chem, Higher Education Press, Beijing, 1990124-126(in Chinese).
[34] S.S.A. El-Rehim, S.A.M. Refaey, F. Taha, M.B. Saleh, R.A. Ahmed, Corrosion inhibition of mild steel in acidic medium using 2-amino thiophenol and 2-cyanomethyl benzothiazole, J. Appl. Electrochem. 31(2001) 429-435.
[35] K.K. Al-Neami, A.K. Mohamed, I.M. Kenawy, A.S. Fouda, Inhibition of the corrosion of iron by oxygen and nitrogen containing compounds, Monatsh. Chem. 126(1995) 369-376.
[36] E.A. Noor, Temperature effects on the corrosion inhibition of mild steel in acidic solutions by aqueous extract of fenugreek leaves, Int. J. Electrochem. Sci. 2(2007) 996-1017.
[37] J. Marsh, Advanced Organic Chemistry, third ed. Wiley Eastern, New Delhi, 1988.
[38] S. Martinez, I. Stern, Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in the low carbon steel/mimosa tannin/sulfuric acid system, Appl. Surf. Sci. 199(2002) 83-89.
[39] H.M. Hassan, A.M. Eldesoky, R.M. Younis, W.A. Zordok, Density functional theory (DFT) studies on sulfa Dimedine azo derivatives as green inhibitors for C-steel in 0.5 mol·L^-1 H₃PO₄ solutions, Int. J. Adv. Res. 2(2014) 550-568.
[40] A.S. Fouda, A.M. Eldesoky, M.M. Muhtar, New cyanoacetamide derivatives as corrosion inhibitors for carbon steel in acidic media, J. Adv. Chem. 4(2013) 323-350.
[41] M. El Achouri, S. Kertit, H.M. Gouttaya, B. Nciri, Y. Bensouda, L. Perez, M.R. Infante, K. Elkacemi, Corrosion inhibition of iron in 1 mol·L^-1 HCl by some gemini surfactants in the series of alkanediyl-α, ω-bis-(dimethyl tetradecyl ammonium bromide), Prog. Org. Coat. 43(2001) 267-273.
[42] U. Rammelt, G. Reinhard, The influence of surface roughness on the impedance data for iron electrodes in acid solutions, Corros. Sci. 27(1987) 373-382.
[43] A. Le Mehaute, G. Grepy, Introduction to transfer and motion in fractal media:The geometry of kinetics, Solid State Ionics 9-10(1983) 17-30.
[44] C.H. Hsu, F. Mansfeld, Technical note:Concerning the conversion of the constant phase element parameter Y0 into a capacitance, Corrosion 57(2001) 747-748.
[45] M. Lebrini, M. Lagrenée, M. Traisnel, L. Gengembre, H. Vezin, F. Bentiss, Enhanced corrosion resistance of mild steel in normal sulfuric acid medium by 2,5-bis(nthienyl)-1,3,4-thiadiazoles:Electrochemical, X-ray photoelectron spectroscopy and theoretical studies, Appl. Surf. Sci. 253(2007) 9267-9276.
[46] H. Amar, A. Tounsi, A. Makayssi, A. Derja, J. Benzakour, A. Outzourhit, Corrosion inhibition of Armco iron by 2-mercaptobenzimidazole in sodium chloride 3% media, Corros. Sci. 49(2007) 2936-2945.
[47] K.F. Khaled, New synthesized guanidine derivative as a green corrosion inhibitor for mild steel in acidic solutions, Int. J. Electrochem. Sci. 3(2008) 462-475.
[48] K.F. Khaled, Molecular simulation, quantum chemical calculations and electrochemical studies for inhibition of mild steel by triazoles, Electrochim. Acta 53(2008) 3484-3492.
[49] A.S. Fouda, A.M. Eldesoky, A.Z. El-Sonbati, S.F. Salam, Prop-2-en-1-one derivatives as corrosion inhibitors for copper in 1 mol·L^-1 HNO₃, Int. J. Electrochem. Sci. 9(2014) 1867-1891.
[50] C. Lee, W. Yang, R.G. Parr, Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density, Phys. Rev. B 37(1988) 785-789.
[51] R.M. Issa, M.K. Awad, F.M. Atlam, Quantum chemical studies on the inhibition of corrosionofcoppersurfacebysubstituteduracils, Appl. Surf. Sci.255(2008)2433-2441.